INPUT=256~1923~ARCHIVE=899787~343548~PROPARC=1243335~15889~PROPIN=0~0~MOLSTATE=2225~248~VIBSTATE=2199~26~OUTPUT=1259224~3980~CELLS=2179~20~ISOD=2751~897036~ISOE=2473~278~RETCODE=1263204~70~VOUT=1263274~271565~                                              
BEGININPUT
  OPT B3LYP 6-31G* 
5-hexen-2-one
0 1
 1   3.356693062  -0.684995443   1.321513299
 6   3.368530645  -0.379534740   0.276875090
 6   2.300942242   0.170495167  -0.302974153
 1   4.296997886  -0.539394297  -0.265031368
 6   0.982457688   0.427002711   0.373489951
 1   2.362942048   0.461415144  -1.353940895
 1   0.745036077   1.498692553   0.348289114
 1   1.041745251   0.152962686   1.433057143
 6  -0.173267208  -0.337225822  -0.288330291
 6  -1.536802823  -0.038222402   0.327373181
 1   0.003057691  -1.421609615  -0.249924370
 1  -0.234802873  -0.096476958  -1.361455737
 8  -1.686655906   0.825035680   1.171095583
 6  -2.701387941  -0.880284934  -0.168984420
 1  -3.634994549  -0.513194637   0.262180057
 1  -2.556397782  -1.929009923   0.120791371
 1  -2.763977832  -0.858458976  -1.263877774
ENDCART
EMPTYVAL
    1 
    4 
    6 
    7 
    8 
   11 
   12 
   15 
   16 
   17 
ENDEMPTYVAL
PLANE
ENDPLANE
POINT
ENDPOINT
ISOTOPE
ENDISOTOPE
FROZEN
ENDFROZEN
TRANSITION
ENDTRANSITION
ATOMALIGN
ENDATOMALIGN
ATOMLABELS
"H1"
"C1"
"C2"
"H3"
"C3"
"H4"
"H2"
"H5"
"C4"
"C5"
"H7"
"H8"
"O1"
"C6"
"H9"
"H10"
"H11"
ENDATOMLABELS
MOLFONT
Helvetica
12
ENDMOLFONT
LABELTYPE
LABELATOM
ENDLABELTYPE
SEARCHCENTER
ENDSEARCHCENTER
BEGINFORMALCHARGE
ENDFORMALCHARGE
BEGINRES
ENDRES
HESSIAN
   -1   -3   -3   -1   -4   -1   -1   -1   -4   -3   -1   -1
   -3   -4   -1   -1   -1
    1    2    1
    2    3    2
    2    4    1
    5    3    1
    3    6    1
    5    7    1
    5    8    1
    5    9    1
    9   10    1
    9   11    1
    9   12    1
   10   13    2
   10   14    1
   14   15    1
   14   16    1
   14   17    1
ENDHESS
SEARCHLINK
ENDSEARCHLINK
LIGAND
ENDLIGAND
STRUCTMODEL
3 0 524288 0
ENDSTRUCTMODEL
ALIGN
  1.000000 0.000000 0.000000 0.000000
  0.000000 1.000000 0.000000 0.000000
  0.000000 0.000000 1.000000 0.000000
  0.000000 0.000000 0.000000 1.000000
ENDALIGN
BEGINPROPIN

ENDPROPIN
ENDINPUT
BEGINCELLS
ENDCELLS
BEGINVIBSTATE
ENDVIBSTATE
BEGINMOLSTATE
MODEL=3~HYDROGEN=1~LABELS=0
 -0.64570004  0.75768316  0.09479699  0.00000000  0.19108057  0.04013359  0.98075235  0.00000000
  0.73929477  0.65138841 -0.17069335  0.00000000  0.00000000  0.00000000  0.00000000  1.00000000
ENDMOLSTATE
BEGINISOENTITY
TYPE=density~PROP=potential~ISOVAL=adjustable~DMODE=1073741827~DISP=1~REZ=Medium~PDISP=1~PREFISO=0.002~SWAP=0~LABEL=Surface1~
@surface=density property=potential resolution=Medium
@volume=density resolution=Medium
@volume=potential resolution=Medium
ENDISOENTITY
BEGINISODATA
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ENDISODATA
BEGINARCHIVE
External AB INITIO PROGRAM: converted archive file
Jobname.Temp
  17 125  48 117   0   1 125   0 RB3LYP   6-31G(d)        OPT                  
GEOMETRY
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   9.8945060758D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.0394869000D+02
   1.5972822308D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.9210155000D+01
   2.0791870615D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   9.2866630000D+00
   1.7741742532D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   3.1639270000D+00
   6.1257982601D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   7.8682724000D+00
  -3.9955635160D-01   1.2960827175D+00   0.0000000000D+00   0.0000000000D+00
   1.8812885000D+00
  -1.8415523929D-01   9.9375362822D-01   0.0000000000D+00   0.0000000000D+00
   5.4424930000D-01
   5.1639037938D-01   4.9595271376D-01   0.0000000000D+00   0.0000000000D+00
   1.6871440000D-01
   1.8761787212D-01   1.5412755095D-01   0.0000000000D+00   0.0000000000D+00
   8.0000000000D-01
   0.0000000000D+00   0.0000000000D+00   1.1138249281D+00   0.0000000000D+00
   3.0475249000D+03
   5.3633438234D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   4.5736951000D+02
   9.8945060758D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.0394869000D+02
   1.5972822308D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.9210155000D+01
   2.0791870615D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   9.2866630000D+00
   1.7741742532D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   3.1639270000D+00
   6.1257982601D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   7.8682724000D+00
  -3.9955635160D-01   1.2960827175D+00   0.0000000000D+00   0.0000000000D+00
   1.8812885000D+00
  -1.8415523929D-01   9.9375362822D-01   0.0000000000D+00   0.0000000000D+00
   5.4424930000D-01
   5.1639037938D-01   4.9595271376D-01   0.0000000000D+00   0.0000000000D+00
   1.6871440000D-01
   1.8761787212D-01   1.5412755095D-01   0.0000000000D+00   0.0000000000D+00
   8.0000000000D-01
   0.0000000000D+00   0.0000000000D+00   1.1138249281D+00   0.0000000000D+00
   1.8731137000D+01
   2.1493541833D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.8253937000D+00
   3.6457112721D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   6.4012170000D-01
   4.1505142766D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6127780000D-01
   1.8138068393D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   3.0475249000D+03
   5.3633438234D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   4.5736951000D+02
   9.8945060758D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.0394869000D+02
   1.5972822308D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.9210155000D+01
   2.0791870615D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   9.2866630000D+00
   1.7741742532D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   3.1639270000D+00
   6.1257982601D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   7.8682724000D+00
  -3.9955635160D-01   1.2960827175D+00   0.0000000000D+00   0.0000000000D+00
   1.8812885000D+00
  -1.8415523929D-01   9.9375362822D-01   0.0000000000D+00   0.0000000000D+00
   5.4424930000D-01
   5.1639037938D-01   4.9595271376D-01   0.0000000000D+00   0.0000000000D+00
   1.6871440000D-01
   1.8761787212D-01   1.5412755095D-01   0.0000000000D+00   0.0000000000D+00
   8.0000000000D-01
   0.0000000000D+00   0.0000000000D+00   1.1138249281D+00   0.0000000000D+00
   1.8731137000D+01
   2.1493541833D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.8253937000D+00
   3.6457112721D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   6.4012170000D-01
   4.1505142766D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6127780000D-01
   1.8138068393D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.8731137000D+01
   2.1493541833D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.8253937000D+00
   3.6457112721D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   6.4012170000D-01
   4.1505142766D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6127780000D-01
   1.8138068393D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.8731137000D+01
   2.1493541833D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.8253937000D+00
   3.6457112721D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   6.4012170000D-01
   4.1505142766D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6127780000D-01
   1.8138068393D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   3.0475249000D+03
   5.3633438234D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   4.5736951000D+02
   9.8945060758D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.0394869000D+02
   1.5972822308D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.9210155000D+01
   2.0791870615D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   9.2866630000D+00
   1.7741742532D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   3.1639270000D+00
   6.1257982601D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   7.8682724000D+00
  -3.9955635160D-01   1.2960827175D+00   0.0000000000D+00   0.0000000000D+00
   1.8812885000D+00
  -1.8415523929D-01   9.9375362822D-01   0.0000000000D+00   0.0000000000D+00
   5.4424930000D-01
   5.1639037938D-01   4.9595271376D-01   0.0000000000D+00   0.0000000000D+00
   1.6871440000D-01
   1.8761787212D-01   1.5412755095D-01   0.0000000000D+00   0.0000000000D+00
   8.0000000000D-01
   0.0000000000D+00   0.0000000000D+00   1.1138249281D+00   0.0000000000D+00
   3.0475249000D+03
   5.3633438234D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   4.5736951000D+02
   9.8945060758D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.0394869000D+02
   1.5972822308D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.9210155000D+01
   2.0791870615D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   9.2866630000D+00
   1.7741742532D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   3.1639270000D+00
   6.1257982601D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   7.8682724000D+00
  -3.9955635160D-01   1.2960827175D+00   0.0000000000D+00   0.0000000000D+00
   1.8812885000D+00
  -1.8415523929D-01   9.9375362822D-01   0.0000000000D+00   0.0000000000D+00
   5.4424930000D-01
   5.1639037938D-01   4.9595271376D-01   0.0000000000D+00   0.0000000000D+00
   1.6871440000D-01
   1.8761787212D-01   1.5412755095D-01   0.0000000000D+00   0.0000000000D+00
   8.0000000000D-01
   0.0000000000D+00   0.0000000000D+00   1.1138249281D+00   0.0000000000D+00
   1.8731137000D+01
   2.1493541833D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.8253937000D+00
   3.6457112721D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   6.4012170000D-01
   4.1505142766D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6127780000D-01
   1.8138068393D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.8731137000D+01
   2.1493541833D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.8253937000D+00
   3.6457112721D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   6.4012170000D-01
   4.1505142766D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6127780000D-01
   1.8138068393D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   5.4846717000D+03
   8.3173520885D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   8.2523495000D+02
   1.5308074829D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.8804696000D+02
   2.4771490916D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   5.2964500000D+01
   3.2562802462D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6897570000D+01
   2.7928936336D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   5.7996353000D+00
   9.5493769626D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.5539616000D+01
  -6.1793369763D-01   3.1169455889D+00   0.0000000000D+00   0.0000000000D+00
   3.5999336000D+00
  -2.7572100882D-01   2.4014372483D+00   0.0000000000D+00   0.0000000000D+00
   1.0137618000D+00
   8.1420764273D-01   1.0543605133D+00   0.0000000000D+00   0.0000000000D+00
   2.7000580000D-01
   2.6695613886D-01   2.7743193731D-01   0.0000000000D+00   0.0000000000D+00
   8.0000000000D-01
   0.0000000000D+00   0.0000000000D+00   1.1138249281D+00   0.0000000000D+00
   3.0475249000D+03
   5.3633438234D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   4.5736951000D+02
   9.8945060758D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.0394869000D+02
   1.5972822308D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.9210155000D+01
   2.0791870615D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   9.2866630000D+00
   1.7741742532D+00   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   3.1639270000D+00
   6.1257982601D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   7.8682724000D+00
  -3.9955635160D-01   1.2960827175D+00   0.0000000000D+00   0.0000000000D+00
   1.8812885000D+00
  -1.8415523929D-01   9.9375362822D-01   0.0000000000D+00   0.0000000000D+00
   5.4424930000D-01
   5.1639037938D-01   4.9595271376D-01   0.0000000000D+00   0.0000000000D+00
   1.6871440000D-01
   1.8761787212D-01   1.5412755095D-01   0.0000000000D+00   0.0000000000D+00
   8.0000000000D-01
   0.0000000000D+00   0.0000000000D+00   1.1138249281D+00   0.0000000000D+00
   1.8731137000D+01
   2.1493541833D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.8253937000D+00
   3.6457112721D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   6.4012170000D-01
   4.1505142766D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6127780000D-01
   1.8138068393D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.8731137000D+01
   2.1493541833D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.8253937000D+00
   3.6457112721D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   6.4012170000D-01
   4.1505142766D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6127780000D-01
   1.8138068393D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.8731137000D+01
   2.1493541833D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   2.8253937000D+00
   3.6457112721D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   6.4012170000D-01
   4.1505142766D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
   1.6127780000D-01
   1.8138068393D-01   0.0000000000D+00   0.0000000000D+00   0.0000000000D+00
ENERGY
  -3.0986112208D+02   0.0000000000D+00
WAVEFUNC   6-31G(d)   QCHEM 
  -1.9139125859D+01  -1.0277583459D+01  -1.0197679734D+01  -1.0192051717D+01
  -1.0188844566D+01  -1.0187356601D+01  -1.0177248063D+01  -1.0386374302D+00
  -8.0582021490D-01  -7.6115288451D-01  -7.2461382791D-01  -6.4466149262D-01
  -5.5455331805D-01  -5.2625460611D-01  -4.8101215907D-01  -4.6618927903D-01
  -4.5383616134D-01  -4.3514963333D-01  -4.2246217838D-01  -4.0761694540D-01
  -3.8551186334D-01  -3.7179636502D-01  -3.5574555249D-01  -3.4323841741D-01
  -3.3927212355D-01  -2.5984603318D-01  -2.4164769219D-01  -1.2649031167D-02
   2.2641807507D-02   8.6302695324D-02   1.1634908614D-01   1.2410871176D-01
   1.4426845329D-01   1.5237628442D-01   1.5713855957D-01   1.6398124419D-01
   1.7688627485D-01   1.8785726229D-01   1.9895619955D-01   2.2042076100D-01
   2.3370230974D-01   2.9501357008D-01   3.1489107277D-01   3.5414852522D-01
   3.7396967616D-01   4.9367813015D-01   5.0954252429D-01   5.3768611266D-01
   5.3967422474D-01   5.5731931475D-01   5.6997549162D-01   5.8970639050D-01
   5.9966089936D-01   6.3246571475D-01   6.6695881196D-01   6.8354233936D-01
   6.9106213466D-01   7.0317379022D-01   7.2990720270D-01   7.4693096075D-01
   7.7841966031D-01   8.1881747147D-01   8.4671642690D-01   8.5873804293D-01
   8.6692592079D-01   8.7824179987D-01   8.9161078071D-01   9.0374331511D-01
   9.1515299255D-01   9.3007168642D-01   9.4038098697D-01   9.5406172996D-01
   9.6075043158D-01   9.7336272262D-01   1.0097207499D+00   1.1167888521D+00
   1.1298154285D+00   1.1526548767D+00   1.2000596827D+00   1.3136629199D+00
   1.3914226026D+00   1.4241339390D+00   1.4482177235D+00   1.4828773674D+00
   1.5560577403D+00   1.5927413738D+00   1.6368428432D+00   1.7086157677D+00
   1.7585753257D+00   1.7745205458D+00   1.7852559952D+00   1.8446623650D+00
   1.8540936971D+00   1.8885643324D+00   1.9252596298D+00   1.9468796641D+00
   1.9565686243D+00   1.9899089060D+00   2.0183743779D+00   2.0686975260D+00
   2.1144830532D+00   2.1387411247D+00   2.2203956470D+00   2.2297278448D+00
   2.2627095947D+00   2.3191766363D+00   2.3632515865D+00   2.4053817922D+00
   2.4324652082D+00   2.5279988422D+00   2.5673983478D+00   2.5830930496D+00
   2.6071456165D+00   2.7490711008D+00   2.7853646457D+00   2.9041925991D+00
   2.9650717513D+00   3.0127897929D+00   3.9586931921D+00   4.0840471592D+00
   4.1361290728D+00   4.2438251539D+00   4.3442118206D+00   4.4163589282D+00
   4.5355954383D+00
  -8.8665785162D-06  -7.8728684168D-05  -7.0439745442D-08  -6.4847120358D-07
   1.8966921046D-06   6.4314286589D-06  -4.7894353351D-06  -6.0848530870D-06
  -5.4760761234D-05  -5.4122812492D-05   1.2172495709D-04   1.2562632327D-06
  -2.3581951608D-06  -1.5705091906D-06   7.2877195178D-06  -2.6561200811D-06
   3.3543955970D-06   1.6137316446D-05   7.1900009466D-05  -1.9337230510D-05
  -1.5781952192D-05   5.6495251002D-06  -4.0399026705D-04   3.2185728821D-04
   2.5036512032D-06  -1.7296457786D-04  -7.1448627328D-07   3.8330483273D-05
   1.9926684323D-05   1.8303496877D-06   2.0216105238D-05  -7.7574403704D-06
   1.1377060736D-05   3.1557575777D-05   1.2143999341D-05   2.7171147654D-05
  -3.0541331841D-05   2.0340246699D-05   3.8994532546D-05  -3.7793652012D-04
   5.3189093974D-04   1.3212406678D-04   1.1312825753D-05   7.0875393965D-05
   5.1307992279D-06   1.3789656556D-05  -2.0265942917D-05  -4.6339445247D-05
  -1.2643989974D-05   9.6969744813D-06  -5.3598973707D-05   8.9954650715D-05
  -9.1597050228D-05   5.4563345669D-05   2.5803111258D-05  -5.0493729560D-06
   2.4572148055D-05  -3.3923677633D-05  -9.4040096869D-06  -1.5164791430D-06
  -3.8934333700D-04   1.0052762905D-03   5.7910413592D-04   3.3720355168D-04
  -4.8395344652D-05  -1.8487788504D-05  -6.8347363235D-06   1.3083485714D-05
   2.8085493659D-05   2.2559380883D-05  -1.6576769159D-05   3.8502816580D-04
  -8.6049191309D-06  -3.1479647366D-05  -2.8010393997D-05  -2.7251727041D-03
   6.4040410125D-04  -2.8825512940D-03  -2.8469133434D-03  -5.0324687671D-05
  -4.9958703588D-04  -4.7642816344D-04   8.3404589785D-05   7.4121548150D-05
  -4.8757412528D-04   1.9065426247D-05   1.1719906534D-04  -1.1401476321D-08
   8.5521178030D-05   9.9270958855D-01   2.5513928400D-02   1.3905560501D-04
  -8.0629627134D-04  -7.8876689760D-04   1.4930374232D-02   2.4402991944D-04
  -1.3522801377D-03  -1.3232940143D-03  -8.2413991628D-03  -7.9750909382D-03
  -7.9902798565D-03  -5.4698652113D-05  -6.1732145695D-05   3.5058037596D-04
   3.7609225160D-06   6.5642520773D-05   6.0237820788D-06  -5.1122254970D-06
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   1.1649530946D+00   1.1269711047D+00   5.9778896680D-02  -2.1104086173D-02
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  -3.0396698310D+00   1.7244929058D-01  -1.9039114539D-01  -2.7185155382D-01
   1.4098466357D+00   1.2016383215D+00   1.2068507798D+00   6.8304191422D-02
   1.2402324917D-02   7.7282518437D-02  -1.9893323984D-01   1.0869508519D+00
  -1.4336491914D-02  -5.6220433933D-02  -4.9498647060D-02   1.2860093933D+00
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   7.2845521022D-02   3.4683881107D-03   2.7539774755D-02  -1.3211934474D-04
   5.7444009649D-02
HESSIAN 6-31G(d)
  51
   6.7860600079D-02
   1.9623525130D-02   8.0800480705D-02
  -1.5067505459D-02  -1.4317489272D-02   3.4669365541D-02
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   2.1133811283D-03  -8.5648794934D-05   3.5661451714D-01
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  -2.1399116451D-01  -1.4135013442D-03   2.1780225549D-03   4.8357762045D-01
  -4.7234754073D-03   1.3938381311D-02   5.6697281778D-03   2.7147902481D-02
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   1.3503734775D-03   4.7349995316D-03  -1.0645140645D-01  -6.2725853343D-02
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   1.0230632358D-01
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  -4.5834146861D-02  -1.1495678174D-04   2.2999967919D-03  -1.2050576686D-02
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  -2.0325359288D-02   3.9295167709D-02
   3.5182666057D-03   5.3438675491D-04   1.2434010536D-03  -1.8114075135D-03
  -8.2745588358D-03   7.2626729840D-03  -2.0647666206D-02   2.2513378353D-02
  -5.5534023758D-03   3.5479778686D-03   1.6996398202D-03  -7.2368188378D-04
  -6.7322525732D-02   5.8768369840D-02  -2.0042948099D-03   1.8317301616D-03
   7.6863366495D-03  -2.8574382959D-03   7.3347992359D-02
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   9.0965819319D-03   4.6794239128D-02   1.1970625769D-01
GEOMETRY2
  1        6.34323312045000       -1.29445434499000        2.49729915639000
  6        6.36560292097000       -0.71721701969500        0.52321830489600
  6        4.34815244906000        0.32218932261200       -0.57253841864900
  1        8.12015239206000       -1.01930792758000       -0.50083692046400
  6        1.85657673717000        0.80691849878300        0.70579403690000
  1        4.46531510108000        0.87194857495000       -2.55857846455000
  1        1.40791474606000        2.83211959151000        0.65817132892800
  1        1.96861404611000        0.28905771674800        2.70808656016000
  6       -0.32742768361800       -0.63726474392800       -0.54486546024300
  6       -2.90413756884000       -0.07222994027150        0.61864585430200
  1        0.00577823279130       -2.68645388185000       -0.47228878066100
  1       -0.44371329192700       -0.18231508969900       -2.57277950571000
  8       -3.18731896419000        1.55909214349000        2.21305079671000
  6       -5.10488537353000       -1.66349806030000       -0.31933443864600
  1       -6.86914687226000       -0.96979769748500        0.49544873991700
  1       -4.83089357382000       -3.64530192584000        0.22826273556700
  1       -5.22316324554000       -1.62225301932000       -2.38838384289000
ENDARCHIVE
BEGINPROPARC
    Spartan Properties Archive 117
    
PROP STRING INITIAL_KEYWORDS 3 BEGIN
   "OPT"
   "B3LYP"
   "6-31G*"
END
PROP STRING CALCULATION_VERSION = " 126_04"
PROP STRING CALCULATION_TARGET = "x86/Darwin"
PROP STRING CALCULATION_CPUTARGET = "P4"
PROP STRING MACHINEHOSTNAME = "ngmac.ch.liv.ac.uk"
PROP VALUE ORIGINAL_ATOM_COUNT =       17.00000000 
PROP VALUE ORIGINAL_COORDS BYATOM  3 BEGIN
        0.0000000       0.0000000    -0.015999913      -0.0000000       0.0000000       1.0800000 
        1.1535197       0.0000000       1.7459852      -0.9491637       0.0000000       1.6280002 
        2.4794048       0.0000000       0.9804856       1.1535192       0.0000000       2.8419852 
        3.3124523       0.0000000       1.6926990       2.5374629       0.8948802       0.3503787 
        2.5605061      -1.2500562       0.1002907       3.8863909      -1.2500571      -0.6652095 
        1.7274587      -1.2500558      -0.6119228       2.5024472      -2.1449363       0.7303975 
        4.9487443      -1.2500564    -0.051859618       3.8863910      -1.2500590      -2.1962095 
        4.9197096      -1.2500594      -2.5615432       3.3697315      -0.3551793      -2.5615437 
        3.3697315      -2.1449396      -2.5615415 
END
PROP VALUE SCF_ITERS =       7.000000000 
PROP VALUE SCF_CTIME =       22.14333300 
PROP VALUE CORR_ENERGIES 1 BEGIN
     -309.8611221 
END
PROP VALUE QC0_TIME =       1074.860000 
PROP VALUE SOLV_SM54_A =      -1.887505042 
PROP VALUE SOLV_CORRECTION =      -1.887505042 
PROP VALUE BE_TIME_SE_MIN =       0.000000000 
PROP VALUE PROP_KEYWORDS =       0.000000000 
PROP VALUE PROP_ISOTOPES 0  2 BEGIN
END
PROP STRING SYM_STRING = "C1"
PROP VALUE E_KCAL =      -194440.8164 
PROP STRING DO_QSAR = "STARTED"
PROP VALUE ATOMIC_CPK_VOLUME BYATOM BEGIN
        1.5342652      20.8246366      14.8237282       1.5256009      15.2930087       1.5550644 
        1.5863016       1.5757678      15.2332000      13.7963932       1.5935917       1.6057381 
        7.6023195      20.9573239       1.5532365       1.5845414       1.5804788 
END
PROP VALUE ATOMIC_CPK_AREA BYATOM BEGIN
        5.3705722      22.4423114      12.4213266       5.3532583       9.5521035       5.4120043 
        5.4738904       5.4530658       9.3344880       9.8516147       5.4882760       5.5121976 
       14.3492693      18.9447348       5.4083705       5.4704138       5.4623847 
END
PROP VALUE CPKVOLUME =       124.2251965 
PROP VALUE CPKAREA =       151.3002823 
PROP VALUE OVALITY =       1.256654299 
PROP VALUE WEIGHT =       98.14500000 
PROP VALUE HOMO_N =       27.00000000 
PROP VALUE E_HOMO =     -0.2416476922 
PROP VALUE E_LUMO =    -0.01264903117 
PROP VALUE TOT_ELECTRONEG =      0.1271483617 
PROP VALUE TOT_HARDNESS =      0.1144993305 
PROP VALUE EST_POLARIZ =       49.97719424 
PROP VALUE LogP_GC =       1.420900000 
PROP VALUE MO_ENERGY 125 BEGIN
      -19.1391259     -10.2775835     -10.1976797     -10.1920517     -10.1888446     -10.1873566 
      -10.1772481      -1.0386374      -0.8058202      -0.7611529      -0.7246138      -0.6446615 
       -0.5545533      -0.5262546      -0.4810122      -0.4661893      -0.4538362      -0.4351496 
       -0.4224622      -0.4076169      -0.3855119      -0.3717964      -0.3557456      -0.3432384 
       -0.3392721      -0.2598460      -0.2416477    -0.012649031     0.022641808     0.086302695 
        0.1163491       0.1241087       0.1442685       0.1523763       0.1571386       0.1639812 
        0.1768863       0.1878573       0.1989562       0.2204208       0.2337023       0.2950136 
        0.3148911       0.3541485       0.3739697       0.4936781       0.5095425       0.5376861 
        0.5396742       0.5573193       0.5699755       0.5897064       0.5996609       0.6324657 
        0.6669588       0.6835423       0.6910621       0.7031738       0.7299072       0.7469310 
        0.7784197       0.8188175       0.8467164       0.8587380       0.8669259       0.8782418 
        0.8916108       0.9037433       0.9151530       0.9300717       0.9403810       0.9540617 
        0.9607504       0.9733627       1.0097207       1.1167889       1.1298154       1.1526549 
        1.2000597       1.3136629       1.3914226       1.4241339       1.4482177       1.4828774 
        1.5560577       1.5927414       1.6368428       1.7086158       1.7585753       1.7745205 
        1.7852560       1.8446624       1.8540937       1.8885643       1.9252596       1.9468797 
        1.9565686       1.9899089       2.0183744       2.0686975       2.1144831       2.1387411 
        2.2203956       2.2297278       2.2627096       2.3191766       2.3632516       2.4053818 
        2.4324652       2.5279988       2.5673983       2.5830930       2.6071456       2.7490711 
        2.7853646       2.9041926       2.9650718       3.0127898       3.9586932       4.0840472 
        4.1361291       4.2438252       4.3442118       4.4163589       4.5355954 
END
DIPOLE
        0.034863684      -1.8058030      -1.8763285
PROP VALUE DIPOLE_VEC 3 BEGIN
      0.034863684      -1.8058030      -1.8763285 
END
PROP VALUE DIPOLE_MAG =       2.604371004 
PROP VALUE Q_MINUS_MUL =     -0.5284175979 
PROP VALUE Q_PLUS_MUL =      0.1804673794 
MULLIKEN
         0.13625529     -0.34094121    -0.047643013      0.13833377     -0.29474239      0.12184802
         0.16444975      0.15219295     -0.35897493      0.45506994      0.16171603      0.15903013
        -0.43479270     -0.52841760      0.18046738      0.17102885      0.16511972
PROP VALUE MULCHARGES BYATOM BEGIN
        0.1362553      -0.3409412    -0.047643013       0.1383338      -0.2947424       0.1218480 
        0.1644497       0.1521929      -0.3589749       0.4550699       0.1617160       0.1590301 
       -0.4347927      -0.5284176       0.1804674       0.1710288       0.1651197 
END
PROP VALUE Q_MINUS_NAO =     -0.7681186254 
PROP VALUE Q_PLUS_NAO =      0.2558207835 
NPA
         0.21051279     -0.43284203     -0.21418431      0.21829914     -0.48713185      0.21808042
         0.25563689      0.24432094     -0.54522755      0.59251494      0.25057808      0.24987679
        -0.54388576     -0.76811863      0.25582078      0.25015919      0.24559014
PROP VALUE NATCHARGES BYATOM BEGIN
        0.2105128      -0.4328420      -0.2141843       0.2182991      -0.4871319       0.2180804 
        0.2556369       0.2443209      -0.5452275       0.5925149       0.2505781       0.2498768 
       -0.5438858      -0.7681186       0.2558208       0.2501592       0.2455901 
END
PROP VALUE CHELP_INFO =       1025.501000 
PROP VALUE Q1_POINTS =       80.00000000 
PROP VALUE Q1_COORDS 80  3 BEGIN
        6.3432331      -1.2944543       2.4972992       6.4656029      -0.7172170       0.5232183 
        6.2656029      -0.7172170       0.5232183       6.3656029      -0.6172170       0.5232183 
        6.3656029      -0.8172170       0.5232183       6.3656029      -0.7172170       0.6232183 
        6.3656029      -0.7172170       0.4232183       6.3078679      -0.7749520       0.4654833 
        6.4233379      -0.6594820       0.4654833       6.4233379      -0.7749520       0.5809533 
        6.3078679      -0.6594820       0.5809533       4.4481524       0.3221893      -0.5725384 
        4.2481524       0.3221893      -0.5725384       4.3481524       0.4221893      -0.5725384 
        4.3481524       0.2221893      -0.5725384       4.3481524       0.3221893      -0.4725384 
        4.3481524       0.3221893      -0.6725384       4.2904174       0.2644543      -0.6302734 
        4.4058874       0.3799243      -0.6302734       4.4058874       0.2644543      -0.5148034 
        4.2904174       0.3799243      -0.5148034       8.1201524      -1.0193079      -0.5008369 
        1.9565767       0.8069185       0.7057940       1.7565767       0.8069185       0.7057940 
        1.8565767       0.9069185       0.7057940       1.8565767       0.7069185       0.7057940 
        1.8565767       0.8069185       0.8057940       1.8565767       0.8069185       0.6057940 
        1.7988417       0.7491835       0.6480590       1.9143117       0.8646535       0.6480590 
        1.9143117       0.7491835       0.7635290       1.7988417       0.8646535       0.7635290 
        4.4653151       0.8719486      -2.5585785       1.4079147       2.8321196       0.6581713 
        1.9686140       0.2890577       2.7080866      -0.2274277      -0.6372647      -0.5448655 
       -0.4274277      -0.6372647      -0.5448655      -0.3274277      -0.5372647      -0.5448655 
       -0.3274277      -0.7372647      -0.5448655      -0.3274277      -0.6372647      -0.4448655 
       -0.3274277      -0.6372647      -0.6448655      -0.3851627      -0.6949997      -0.6026005 
       -0.2696927      -0.5795297      -0.6026005      -0.2696927      -0.6949997      -0.4871305 
       -0.3851627      -0.5795297      -0.4871305      -2.8041376    -0.072229900       0.6186459 
       -3.0041376    -0.072229900       0.6186459      -2.9041376     0.027770100       0.6186459 
       -2.9041376      -0.1722299       0.6186459      -2.9041376    -0.072229900       0.7186459 
       -2.9041376    -0.072229900       0.5186459      -2.9618726      -0.1299649       0.5609109 
       -2.8464026    -0.014494874       0.5609109      -2.8464026      -0.1299649       0.6763809 
       -2.9618726    -0.014494874       0.6763809    0.0057782000      -2.6864539      -0.4722888 
       -0.4437133      -0.1823151      -2.5727795      -3.0873190       1.5590921       2.2130508 
       -3.2873190       1.5590921       2.2130508      -3.1873190       1.6590921       2.2130508 
       -3.1873190       1.4590921       2.2130508      -3.1873190       1.5590921       2.3130508 
       -3.1873190       1.5590921       2.1130508      -3.2450540       1.5013571       2.1553158 
       -3.1295840       1.6168271       2.1553158      -3.1295840       1.5013571       2.2707858 
       -3.2450540       1.6168271       2.2707858      -5.0048854      -1.6634981      -0.3193344 
       -5.2048854      -1.6634981      -0.3193344      -5.1048854      -1.5634981      -0.3193344 
       -5.1048854      -1.7634981      -0.3193344      -5.1048854      -1.6634981      -0.2193344 
       -5.1048854      -1.6634981      -0.4193344      -5.1626204      -1.7212331      -0.3770694 
       -5.0471504      -1.6057631      -0.3770694      -5.0471504      -1.7212331      -0.2615994 
       -5.1626204      -1.6057631      -0.2615994      -6.8691469      -0.9697977       0.4954487 
       -4.8308936      -3.6453019       0.2282627      -5.2231632      -1.6222530      -2.3883838 
END
PROP VALUE Q1_CHARGES 80 BEGIN
        0.1950015      -0.6291983      -0.8697581      -1.1068677    -0.010080005      -0.3847691 
        2.6068539      -1.7240251      -0.3228139       0.6905133       1.1721329       1.8179471 
       -0.9094887      -3.1576876      -3.4831569       3.8566415       1.9511824       0.5224975 
       -2.5769311       0.7915632       1.1492430       0.1843601       0.3609420       0.5874953 
       -2.0420389      -1.3059842       0.2953204       2.0731825       1.0590110     0.089080194 
      0.031743059      -1.3481904       0.1869301       0.1710159       0.1605207      -0.5430832 
       -0.5965430      -0.6419634      -0.5232041       1.9868184    -0.036469202      -0.4327578 
        1.3553262      -0.8310414      -0.2787703       0.2576092     0.060227230       0.1618997 
       -1.6210297      -0.1070956       1.6982756       0.5263053      -1.8027517       1.6316692 
       -0.1188997       0.1814945       0.1653871     -10.8778406      -6.9367421       6.2366212 
        0.9395274       1.1257543       9.1951879      -2.7274673      -4.0730309       7.4343557 
       -0.7643941      -1.4044673      -0.7504080       0.7410240       2.8922283    -0.020594921 
       -1.8290207      -1.0230277       2.1248751      -1.1983044      -0.2756559       0.2177219 
        0.1943197       0.2057478 
END
PROP VALUE Q1_RMS =       1.771852392 
PROP VALUE Q1_PRMS =       1.099581893 
PROP VALUE Q1_ATOMIC_MM BYATOM  10 BEGIN
        0.1950015       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
       -0.5780122       0.1960605   -0.0024739668      -0.1866562    -0.055178498    -0.039766548 
        0.0949450    -0.052575405    -0.025320620    -0.012366821 
     -0.038189674       0.1858919      -0.3195678       1.0704387     0.035636801      -0.2689360 
        0.2332992    -0.053728648     0.036871493     0.046491769 
        0.1843601       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
       -0.1994391    0.0025824741      -0.5318378      -0.8134214     0.038682235      -0.1346563 
        0.0959741     0.033143523     0.031601364   -0.0055137843 
        0.1869301       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
        0.1710159       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
        0.1605207       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
       -0.5416879       0.1949094       0.3132056       0.2159861    -0.041211016    -0.042241473 
      0.083452489     0.027331784    -0.031473484    -0.016619417 
        0.6862095    -0.034716745      -0.1454771    -0.049560244    0.0067728025    -0.064918014 
      0.058145212    -0.037509839     0.054863486    0.0077796035 
        0.1814945       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
        0.1653871       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
       -0.4480285    0.0039620255    -0.054211277    -0.074273097      -0.7144507       0.2937878 
        0.4206629      -0.1811530       0.1283535      -0.0921628 
       -0.7433515       0.1602799     0.050554685     0.081648643    -0.081944885       0.1515742 
     -0.069629337     0.034639891    -0.054741449    -0.029925590 
        0.2177219       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
        0.1943197       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
        0.2057478       0.0000000       0.0000000       0.0000000       0.0000000       0.0000000 
        0.0000000       0.0000000       0.0000000       0.0000000 
END
CHELP
         0.19379738     -0.49989638    -0.050939486      0.18701773    -0.065126628      0.11573583
        0.078676733     0.092965599     -0.39571770      0.76280427      0.13396195      0.12381456
        -0.49895062     -0.79536194      0.21937428      0.20146116      0.19638325
PROP VALUE ESPCHARGES BYATOM BEGIN
        0.1937974      -0.4998964    -0.050939486       0.1870177    -0.065126628       0.1157358 
      0.078676733       0.0929656      -0.3957177       0.7628043       0.1339620       0.1238146 
       -0.4989506      -0.7953619       0.2193743       0.2014612       0.1963833 
END
PROP VALUE CHELP_RMS =       2.144517879 
PROP VALUE CHELP_PRMS =       2.144517879 
PROP VALUE MOMENT_I_cm 3 BEGIN
        0.2473678     0.037201357     0.034182337 
END
PROP VALUE MOMENT_I 3 BEGIN
       68.1481253     453.1461578     493.1685054 
END
PROP VALUE TOTAL_MASS =       98.07316500 
PROP VALUE TOTAL_WALL_TIME =       20.7607
ENDPROPARC
BEGINOUTPUT

MacSPARTAN '04 MECHANICS PROGRAM: MAC/P4             build 126   
  (Job run on ngmac.ch.liv.ac.uk)


 Reading coordinates from previous archive
  Adjusted 5 (out of 51) low frequency modes

  Reason for exit: Successful completion
  Mechanics CPU Time :   0:00:00.0
  Mechanics Wall Time:   0:00:00.1

MacSPARTAN '04 Quantum Mechanics Program:  (x86/Darwin)     build  126v3

Job type: Geometry optimization.
Method: RB3LYP
Basis set: 6-31G(D)
Number of shells: 48
Number of basis functions: 125

SCF model:
 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization


Optimization:
         Step      Energy          Max Grad.      Max Dist. 
            1    -309.8512088       0.020754       0.117090
            2    -309.8549009       0.007623       0.113666
            3    -309.8554334       0.003808       0.145480
            4    -309.8559199       0.002341       0.139865
            5    -309.8564152       0.003082       0.105789   1
            6    -309.8569512       0.002969       0.035983   1
            7    -309.8571679       0.002846       0.037415   1
            8    -309.8573958       0.002694       0.037799   1
            9    -309.8576302       0.002554       0.039667   1
           10    -309.8578705       0.002402       0.040129   1
           11    -309.8581118       0.002260       0.034311   1
           12    -309.8579457       0.003655       0.133928
           13    -309.8588135       0.002254       0.128555
           14    -309.8594916       0.002145       0.107468
           15    -309.8593108       0.007383       0.131781
           16    -309.8602357       0.004248       0.133532
           17    -309.8607117       0.001713       0.137568
           18    -309.8608574       0.002213       0.148193
           19    -309.8609189       0.002790       0.038662
           20    -309.8610216       0.000837       0.024563
           21    -309.8610569       0.001124       0.038695
           22    -309.8610816       0.000677       0.034227
           23    -309.8610951       0.000237       0.044104
           24    -309.8611065       0.000539       0.070132
           25    -309.8611122       0.000840       0.023518
           26    -309.8611194       0.000397       0.023856
           27    -309.8611214       0.000231       0.008604
           28    -309.8611221       0.000088       0.004922

  Program Wall Time:    0:20:40.0
  Reason for exit: Successful completion 
  Quantum Mechanics Program CPU Time :   0:17:55.0
  Quantum Mechanics Program Wall Time:   0:20:40.5


MacSPARTAN '04 Semi-Empirical Program:  (x86/Darwin)          build  126       
   Job run on machine : ngmac.ch.liv.ac.uk                      
    Semi-empirical Property Calculation 

  5-HEXEN-2-ONE                                                              

  Guess from Archive
    
  Energy Due to Solvation
   Solvation Energy SM5.4/A         -7.897
  Memory Used:         631.08 Kb
  Reason for exit: Successful completion
  Semi-Empirical Program CPU Time :   0:00:00.0
  Semi-Empirical Program Wall Time:   0:00:00.3


SPARTAN PROPERTIES PACKAGE: MAC/P4             build 126                       
   
   

  Reason for exit: Successful completion
  Properties CPU Time :   0:00:00.5
  Properties Wall Time:   0:00:00.6

SPARTAN GRAPHICS PROGRAM:  MAC/P4             build 126   

Graphics requests:
   volume=density resolution=Medium pending
   volume=potential resolution=Medium pending

Surface    Type        Property    S.mo P.mo Resolution  Value   Size   Time

    1     Density                               0.500    0.002  2.000    0.16
    2      Elpot                                0.500   -5.000  3.000    3.25

  Reason for exit: Successful completion
  Graphics Program CPU Time :   0:00:03.4
  Graphics Program Wall Time:   0:00:03.6

molecule 5-hexen-2-one terminated normally



End-   molecule "5-hexen-2-one" Wed Oct  3 12:39:54 2007
ENDOUTPUT
BEGINRETCODE
    0 0 165 sp_graphics
Successful completion
ENDRETCODE
BEGINVOUTPUT
               MacSPARTAN '04 
          build 126 (Nov 13 2006)

 Wavefunction Developers: 
    B.J. Deppmeier, A.J. Driessen, T.S. Hehre, W.J. Hehre, 
    J.A. Johnson, P.E. Klunzinger, J.M. Leonard, I.N. Pham 
    W.J. Pietro, Jianguo Yu 
 
 Q-Chem Developers:  
 Y. Shao, L. Fusti-Molnar, Y. Jung, J. Kussmann, C. Ochsenfeld,
 S. T. Brown, A. T. B. Gilbert, L. V. Slipchenko,S. V. Levchenko,
 D. P. O'Neill, R. A. DiStasio Jr., R. C. Lochan, T. Wang,
 G. J. O. Beran, N. A. Besley, J. M., Herbert, C. Y. Lin,
 T. Van Voorhis, S. H. Chien, A. Sodt, R. P. Steele, 
 V. A. Rassolov, P. E. Maslen, P. P. Korambath, R. D. Adamson,
 B. Austin, J. Baker, E. F. C. Byrd, H. Dachsel, R. J. Doerksen,
 A. Dreuw, B. D. Dunietz, A. D. Dutoi, T. R. Furlani,
 S. R. Gwaltney, A. Heyden, S. Hirata, C.-P. Hsu, G. Kedziora,
 R. Z. Khalliulin, P. Klunzinger, A. M. Lee, M. S. Lee, W. Liang,
 I. Lotan, N. Nair, B. Peters, E. I. Proynov, P. A. Pieniazek, 
 Y. M. Rhee, J. Ritchie, E. Rosta, C. D. Sherrill, 
 A. C. Simmonett, J. E. Subotnik, H. L. Woodcock III,
 W. Zhang, A. T. Bell, A. K. Chakraborty, D. M. Chipman,
 F. J. Keil, A. Warshel, W. J. Hehre, H. F. Schaefer III,
 J. Kong, A. I. Krylov, P. M. W. Gill, M. Head-Gordon,
 
 Wavefunction Inc.           Sales:   sales@wavefun.com  
 Irvine CA                   Support: support@wavefun.com  
                             Web:     www.wavefun.com   
 
Copyright © 1995 - 2006 
----------------------------------------------------

Job run on "ngmac.ch.liv.ac.uk" (MacPro 3.00 Ghz[quad processor] Intel Core 2)

           Spartan 'O6 Quantum Mechanics Module    126v3

     Scratch files written to /Users/ngreeves/Desktop/231Molecules/5-hexen-2-one.slst/5-hexen-2-one.smol_Fld//scratch//

 Macintosh (OS-X)
Processing $rem in system registry
  ... MEM_TOTAL 2000 # MB 

Processing $rem in /Applications/Spartan04/1.1.1/Spartan 04111.app/Contents/MacOS/../SharedSupport//P4//../auxdir/config/preferences.
   (Site specific preferences)
  ... THRESH             9
  ... SCF_CONVERGENCE    7
  ... SMALL_PROD_XCMAT   9
  ... BASIS_LIN_DEP_THRESH     5
  ... SCF_ALGORITHM	DIIS_GDM
  ... MAXSCF		100
  ... MAXDIIS          50
  ... THRESHDIIS	 -1  (i.e. don't switch on delta-E)
  ... ONEEXE_SPAR     TRUE
  ... GUI              GUI_SPARTAN
  ... TERSE_OUTPUT     TRUE
Processing $rem in input file
  ... JOBTYPE    OPT
  ... TIDY_SYM   TRUE
  ... EXCHANGE     	B3LYP
  ... CORRELATION  	none  (built-in)
  ... INCDFT       	TRUE
  ... VARTHRESH    	2
  ... BASIS        	6-31G(d)
  ... GEOM_OPT_HESSIAN      READ
  ... EXTERNAL_HESSIAN      TRUE
  ... GUI          	 GUI_SPARTAN
  ... TERSE_OUTPUT 	 TRUE
 Writing REM_CC_EA            0
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.230451    -1.655998     0.227674
    2      C       2.850318    -0.785076    -0.014140
    3      C       2.330441     0.439768     0.046107
    4      H       3.897963    -0.922005    -0.305528
    5      C       0.866988     0.631045     0.453146
    6      H       2.950309     1.310690    -0.195708
    7      H       0.622334     1.699363     0.445633
    8      H       0.712281     0.227900     1.460497
    9      C      -0.038598    -0.106859    -0.536486
   10      C      -1.502051     0.084417    -0.129448
   11      H       0.206056    -1.175178    -0.528973
   12      H       0.116109     0.296285    -1.543838
   13      O      -1.980841     1.212457    -0.073962
   14      C      -2.367944    -1.132173     0.208340
   15      H      -3.377684    -0.799341     0.474540
   16      H      -1.926219    -1.671501     1.054047
   17      H      -2.419795    -1.796599    -0.661755
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   284.8187282747 hartrees
 There are       27 alpha and       27 beta electrons
 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions

Total Memory Limit   2000 MB
Mega-Array Size        61 MB
MEM_STATIC part        62 MB

 MacSPARTAN '04 Quantum Mechanics Program:  (x86/Darwin)     build  126v3 (3.0.0)
-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:19:09 2007  -
-------------------------------------------------

 Standard Electronic Orientation quadrupole field applied
 Nucleus-field energy     =     0.0000000966 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:19:09 2007  -
-------------------------------------------------

 A cutoff of  1.0D-09 yielded   1014 shell pairs
 There are   7094 function pairs
 Smallest overlap matrix eigenvalue = 3.40E-03
 Multipole matrices computed through 2nd order
 Guess from superposition of atomic densities
 Warning:  Energy on first SCF cycle will be non-variational

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:19:09 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -310.8748693974      6.76E-02
    2    -309.6731240107      9.77E-03
    3    -309.4820044104      1.51E-02
    4    -309.8257401118      3.84E-03
    5    -309.8508505756      4.67E-04
    6    -309.8511574905      1.64E-04
    7    -309.8512061709      3.81E-05
    8    -309.8512085214      1.19E-05
    9    -309.8512087398      4.80E-06
   10    -309.8512087806      1.41E-06
   11    -309.8512087711      3.20E-07
   12    -309.8512087730      4.59E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 41.69 s  wall 42.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:19:52 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.133086
      2 C                    -0.325935
      3 C                    -0.070331
      4 H                     0.139576
      5 C                    -0.305299
      6 H                     0.135485
      7 H                     0.167359
      8 H                     0.153906
      9 C                    -0.328296
     10 C                     0.445472
     11 H                     0.139804
     12 H                     0.174263
     13 O                    -0.445189
     14 C                    -0.528878
     15 H                     0.180810
     16 H                     0.165681
     17 H                     0.168486
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       1.1000      Y      -2.1723      Z      -0.0803
       Tot       2.4362
    Quadrupole Moments (Debye-Ang)
        XX     -45.2245     XY       6.0977     YY     -44.1712
        XZ      -0.6933     YZ      -0.3269     ZZ     -43.0615
    Octapole Moments (Debye-Ang^2)
       XXX       0.4807    XXY      -8.0031    XYY       5.3309
       YYY       1.0837    XXZ      -3.5975    XYZ      -0.9514
       YYZ       0.0709    XZZ      -7.6816    YZZ       1.5976
       ZZZ      -0.7241
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1038.0445   XXXY      17.4382   XXYY    -224.5406
      XYYY       2.4586   YYYY    -240.1876   XXXZ     -18.5202
      XXYZ       1.0129   XYYZ       0.6084   YYYZ       0.2866
      XXZZ    -202.4821   XYZZ      -0.0761   YYZZ     -54.3540
      XZZZ       1.0799   YZZZ      -2.3620   ZZZZ     -87.8522
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:19:52 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0083649  -0.0099519   0.0060572   0.0067919  -0.0177016   0.0050075
    2  -0.0012781  -0.0020756   0.0028688   0.0051215  -0.0076365   0.0025020
    3   0.0015038   0.0021744  -0.0065397  -0.0020820   0.0085485  -0.0013538
            7           8           9          10          11          12
    1   0.0036451   0.0007098   0.0135673   0.0148753  -0.0007803   0.0015862
    2   0.0027393  -0.0031953   0.0055335  -0.0149817  -0.0012616   0.0016649
    3  -0.0033623  -0.0015402  -0.0072816   0.0037250   0.0041434   0.0003029
           13          14          15          16          17
    1  -0.0068321  -0.0045454  -0.0030427   0.0000147  -0.0010361
    2   0.0109389  -0.0082229   0.0001829   0.0037910   0.0033089
    3   0.0000675   0.0013636   0.0006918   0.0012336  -0.0015949
 Max gradient component =       1.770E-02
 RMS gradient           =       6.133E-03
 Gradient time:  CPU 12.56 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:20:04 2007  -
-------------------------------------------------


 Cartesian Hessian read from HESS file


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:   1

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.230451   -1.655998    0.227674
    2  C           2.850318   -0.785076   -0.014140
    3  C           2.330441    0.439768    0.046107
    4  H           3.897963   -0.922005   -0.305528
    5  C           0.866988    0.631045    0.453146
    6  H           2.950309    1.310690   -0.195708
    7  H           0.622334    1.699363    0.445633
    8  H           0.712281    0.227900    1.460497
    9  C          -0.038598   -0.106859   -0.536486
   10  C          -1.502051    0.084417   -0.129448
   11  H           0.206056   -1.175178   -0.528973
   12  H           0.116109    0.296285   -1.543838
   13  O          -1.980841    1.212457   -0.073962
   14  C          -2.367944   -1.132173    0.208340
   15  H          -3.377684   -0.799341    0.474540
   16  H          -1.926219   -1.671501    1.054047
   17  H          -2.419795   -1.796599   -0.661755
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.851208773


 Attempting to Generate Delocalized Internal Coordinates

 Transforming Cartesian Hessian to Internal Coordinates
 Hessian Transformation does not Include Derivative of B-matrix
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.001121    0.001953    0.004063    0.005072    0.019196    0.029864
     0.040055    0.041451    0.042146    0.043619    0.047097    0.053665
     0.055808    0.057131    0.077307    0.082582    0.105394    0.121261
     0.126789    0.128185    0.132673    0.138126    0.150047    0.153718
     0.189654    0.202185    0.207198    0.213076    0.235750    0.261702
     0.292254    0.301185    0.301465    0.301859    0.301997    0.302082
     0.302631    0.304429    0.307391    0.308854    0.311175    0.323388
     0.424526    0.642673    0.827606

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00688371
 Step Taken.  Stepsize is  0.241896

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.020754      0.000300      NO
         Displacement       0.117090      0.001200      NO
         Energy change     *********      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.405911
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.364704    -1.681395     0.209187
    2      C       2.921545    -0.775555    -0.016143
    3      C       2.332865     0.416944     0.058260
    4      H       3.960752    -0.903194    -0.301657
    5      C       0.881807     0.616723     0.440787
    6      H       2.909956     1.309502    -0.178440
    7      H       0.610752     1.676075     0.447160
    8      H       0.722868     0.247937     1.461870
    9      C      -0.077340    -0.123993    -0.516821
   10      C      -1.538717     0.107366    -0.131423
   11      H       0.172408    -1.189970    -0.528457
   12      H       0.067210     0.260972    -1.533067
   13      O      -1.988649     1.235836    -0.076634
   14      C      -2.389266    -1.104433     0.200804
   15      H      -3.396013    -0.777199     0.463034
   16      H      -1.953014    -1.667533     1.036636
   17      H      -2.431753    -1.790889    -0.654952
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   284.1551872113 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:20:05 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000987 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:20:05 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded   1006 shell pairs
 There are   7050 function pairs
 Smallest overlap matrix eigenvalue = 3.49E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:20:05 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8774173266      1.68E-03
    2    -309.8546266779      3.62E-04
    3    -309.8545539009      4.46E-04
    4    -309.8548742473      1.27E-04
    5    -309.8548998817      2.52E-05
    6    -309.8549006582      1.12E-05
    7    -309.8549009011      3.16E-06
    8    -309.8549009434      1.04E-06
    9    -309.8549009331      1.79E-07
   10    -309.8549009451      5.54E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 34.03 s  wall 34.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:20:39 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.132269
      2 C                    -0.330864
      3 C                    -0.066492
      4 H                     0.143432
      5 C                    -0.307083
      6 H                     0.133787
      7 H                     0.168202
      8 H                     0.152929
      9 C                    -0.334549
     10 C                     0.453058
     11 H                     0.140524
     12 H                     0.171958
     13 O                    -0.441147
     14 C                    -0.533276
     15 H                     0.179532
     16 H                     0.168360
     17 H                     0.169360
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.9825      Y      -2.2232      Z      -0.0664
       Tot       2.4315
    Quadrupole Moments (Debye-Ang)
        XX     -45.0420     XY       5.8487     YY     -44.0827
        XZ      -0.6547     YZ      -0.1984     ZZ     -43.1064
    Octapole Moments (Debye-Ang^2)
       XXX       0.6822    XXY      -9.3380    XYY       5.5053
       YYY      -0.2117    XXZ      -3.4859    XYZ      -0.7628
       YYZ       0.1662    XZZ      -7.6563    YZZ       1.5354
       ZZZ      -0.7548
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1062.6513   XXXY      16.8482   XXYY    -227.5008
      XYYY       6.4809   YYYY    -237.2191   XXXZ     -19.8825
      XXYZ       1.0324   XYYZ      -0.0372   YYYZ      -0.1184
      XXZZ    -206.8760   XYZZ       1.0499   YYZZ     -53.7656
      XZZZ      -0.2692   YZZZ      -2.5089   ZZZZ     -86.7507
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:20:39 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0013292   0.0002824  -0.0006115  -0.0006985   0.0000294  -0.0002105
    2   0.0023511   0.0008601  -0.0020746  -0.0007197   0.0000761  -0.0007341
    3  -0.0005414  -0.0003940   0.0006634   0.0001257   0.0007494   0.0000332
            7           8           9          10          11          12
    1  -0.0007484   0.0008116   0.0012902  -0.0018437   0.0017576   0.0000912
    2  -0.0002795   0.0000651   0.0008761   0.0008184   0.0004600   0.0000885
    3   0.0001935  -0.0011393  -0.0016100  -0.0004915   0.0010023   0.0007591
           13          14          15          16          17
    1   0.0008317  -0.0002911   0.0011620  -0.0004455  -0.0000778
    2  -0.0019160  -0.0000359   0.0006621  -0.0004838  -0.0000139
    3  -0.0000888   0.0008364  -0.0003038   0.0002839  -0.0000781
 Max gradient component =       2.351E-03
 RMS gradient           =       8.888E-04
 Gradient time:  CPU 12.13 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:20:51 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:   2

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.364704   -1.681395    0.209187
    2  C           2.921545   -0.775555   -0.016143
    3  C           2.332865    0.416944    0.058260
    4  H           3.960752   -0.903194   -0.301657
    5  C           0.881807    0.616723    0.440787
    6  H           2.909956    1.309502   -0.178440
    7  H           0.610752    1.676075    0.447160
    8  H           0.722868    0.247937    1.461870
    9  C          -0.077340   -0.123993   -0.516821
   10  C          -1.538717    0.107366   -0.131423
   11  H           0.172408   -1.189970   -0.528457
   12  H           0.067210    0.260972   -1.533067
   13  O          -1.988649    1.235836   -0.076634
   14  C          -2.389266   -1.104433    0.200804
   15  H          -3.396013   -0.777199    0.463034
   16  H          -1.953014   -1.667533    1.036636
   17  H          -2.431753   -1.790889   -0.654952
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.854900945

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.001120    0.001957    0.004065    0.005072    0.019264    0.030038
     0.041143    0.041589    0.042147    0.043561    0.047161    0.053560
     0.055139    0.057309    0.078020    0.082580    0.105151    0.120609
     0.126602    0.129832    0.135482    0.142197    0.150128    0.159785
     0.189648    0.199496    0.202979    0.211623    0.235918    0.261582
     0.292478    0.299760    0.301467    0.301621    0.301962    0.302478
     0.302910    0.303345    0.307675    0.309915    0.312537    0.317834
     0.387055    0.630639    0.838197

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00069296
 Step Taken.  Stepsize is  0.232182

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.007623      0.000300      NO
         Displacement       0.113666      0.001200      NO
         Energy change     -0.003692      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.453659
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.440053    -1.686334     0.283810
    2      C       2.957779    -0.768589     0.011495
    3      C       2.338545     0.412136     0.027674
    4      H       4.000253    -0.874852    -0.273727
    5      C       0.890926     0.610657     0.420368
    6      H       2.894040     1.306644    -0.252700
    7      H       0.627948     1.672270     0.416227
    8      H       0.738171     0.262925     1.452316
    9      C      -0.094942    -0.137304    -0.507422
   10      C      -1.544644     0.113282    -0.090976
   11      H       0.144338    -1.206273    -0.519624
   12      H       0.027055     0.236043    -1.531949
   13      O      -1.965144     1.246728     0.041568
   14      C      -2.416352    -1.098702     0.175902
   15      H      -3.425787    -0.780100     0.442434
   16      H      -1.989085    -1.699265     0.990203
   17      H      -2.453038    -1.752071    -0.705453
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   283.6933613760 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:20:51 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000001001 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:20:51 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded   1005 shell pairs
 There are   7046 function pairs
 Smallest overlap matrix eigenvalue = 3.53E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:20:51 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8429344780      2.47E-03
    2    -309.8553029512      1.71E-04
    3    -309.8554009303      1.29E-04
    4    -309.8554258840      6.76E-05
    5    -309.8554316120      3.28E-05
    6    -309.8554332618      6.19E-06
    7    -309.8554333279      1.68E-06
    8    -309.8554333315      7.68E-07
    9    -309.8554333475      2.40E-07
   10    -309.8554333521      6.42E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 33.25 s  wall 34.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:21:25 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.132468
      2 C                    -0.330427
      3 C                    -0.068223
      4 H                     0.142644
      5 C                    -0.305357
      6 H                     0.133749
      7 H                     0.168278
      8 H                     0.152348
      9 C                    -0.337044
     10 C                     0.455720
     11 H                     0.141769
     12 H                     0.171834
     13 O                    -0.441659
     14 C                    -0.533244
     15 H                     0.179114
     16 H                     0.169297
     17 H                     0.168732
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.8970      Y      -2.2433      Z      -0.2420
       Tot       2.4281
    Quadrupole Moments (Debye-Ang)
        XX     -44.8546     XY       5.7783     YY     -44.1275
        XZ      -0.2549     YZ      -0.6532     ZZ     -43.0986
    Octapole Moments (Debye-Ang^2)
       XXX      -0.7702    XXY      -9.3556    XYY       5.4330
       YYY      -0.4656    XXZ      -4.7667    XYZ      -0.4569
       YYZ      -0.6730    XZZ      -7.7594    YZZ       1.5110
       ZZZ      -2.3719
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1075.2898   XXXY      15.4942   XXYY    -229.7859
      XYYY       6.0603   YYYY    -236.9953   XXXZ     -15.5265
      XXYZ      -2.1316   XYYZ       1.7569   YYYZ      -3.2068
      XXZZ    -209.1545   XYZZ       1.0344   YYZZ     -53.2893
      XZZZ       2.4937   YZZZ      -4.1873   ZZZZ     -84.9526
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:21:25 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0004459  -0.0003520  -0.0003806  -0.0003395   0.0013084  -0.0003516
    2   0.0005966   0.0003966  -0.0003428  -0.0006377   0.0000011   0.0001232
    3  -0.0006413   0.0001119  -0.0002307   0.0003605  -0.0007078   0.0004944
            7           8           9          10          11          12
    1   0.0000641  -0.0000805  -0.0008462  -0.0010829   0.0016161   0.0000155
    2   0.0000676   0.0001658  -0.0010312   0.0014149   0.0000927   0.0002774
    3   0.0004195   0.0004268  -0.0014714  -0.0007056   0.0004218   0.0007033
           13          14          15          16          17
    1   0.0003819   0.0003067   0.0002814  -0.0000092  -0.0000858
    2  -0.0013916   0.0007130   0.0002704  -0.0004590  -0.0002568
    3   0.0000912   0.0008563  -0.0002640  -0.0000567   0.0001917
 Max gradient component =       1.616E-03
 RMS gradient           =       6.291E-04
 Gradient time:  CPU 12.15 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:21:37 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:   3

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.440053   -1.686334    0.283810
    2  C           2.957779   -0.768589    0.011495
    3  C           2.338545    0.412136    0.027674
    4  H           4.000253   -0.874852   -0.273727
    5  C           0.890926    0.610657    0.420368
    6  H           2.894040    1.306644   -0.252700
    7  H           0.627948    1.672270    0.416227
    8  H           0.738171    0.262925    1.452316
    9  C          -0.094942   -0.137304   -0.507422
   10  C          -1.544644    0.113282   -0.090976
   11  H           0.144338   -1.206273   -0.519624
   12  H           0.027055    0.236043   -1.531949
   13  O          -1.965144    1.246728    0.041568
   14  C          -2.416352   -1.098702    0.175902
   15  H          -3.425787   -0.780100    0.442434
   16  H          -1.989085   -1.699265    0.990203
   17  H          -2.453038   -1.752071   -0.705453
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.855433352

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.001024    0.001921    0.002785    0.005204    0.019797    0.029191
     0.039693    0.041566    0.042307    0.044881    0.047210    0.049847
     0.054331    0.056838    0.077851    0.080152    0.107421    0.121552
     0.126684    0.131647    0.132227    0.142894    0.150844    0.156188
     0.184301    0.191780    0.203127    0.213631    0.238274    0.261291
     0.292349    0.300405    0.301450    0.301626    0.302021    0.302443
     0.302870    0.304031    0.307984    0.310457    0.311437    0.321561
     0.358466    0.629810    0.831720

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00084015
 Calculated Step too Large.  Step scaled by  0.685317
 Step Taken.  Stepsize is  0.300000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.003808      0.000300      NO
         Displacement       0.145480      0.001200      NO
         Energy change     -0.000532      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.622475
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.545817    -1.668779     0.401294
    2      C       3.009081    -0.749434     0.044906
    3      C       2.343384     0.405723    -0.011589
    4      H       4.047339    -0.828397    -0.266039
    5      C       0.902127     0.597866     0.409729
    6      H       2.860612     1.292131    -0.379251
    7      H       0.639065     1.659097     0.401266
    8      H       0.770513     0.260778     1.448658
    9      C      -0.109997    -0.157188    -0.481721
   10      C      -1.548862     0.116011    -0.041861
   11      H       0.109848    -1.230855    -0.485944
   12      H      -0.009517     0.191688    -1.518864
   13      O      -1.933505     1.251437     0.165978
   14      C      -2.455252    -1.086669     0.137630
   15      H      -3.461430    -0.768884     0.419633
   16      H      -2.044147    -1.741854     0.917447
   17      H      -2.494958    -1.685476    -0.781126
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   283.1827652550 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:21:37 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000001011 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:21:37 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded   1004 shell pairs
 There are   7042 function pairs
 Smallest overlap matrix eigenvalue = 3.53E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:21:38 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8386256336      2.78E-03
    2    -309.8556824253      2.46E-04
    3    -309.8557988576      2.54E-04
    4    -309.8559015637      1.09E-04
    5    -309.8559173720      3.80E-05
    6    -309.8559197905      7.27E-06
    7    -309.8559198932      2.26E-06
    8    -309.8559199028      5.50E-07
    9    -309.8559199102      3.13E-07
   10    -309.8559199207      1.13E-07
   11    -309.8559198511      2.53E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 35.94 s  wall 36.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:22:14 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.132437
      2 C                    -0.329541
      3 C                    -0.069850
      4 H                     0.141897
      5 C                    -0.303704
      6 H                     0.133080
      7 H                     0.168833
      8 H                     0.151736
      9 C                    -0.339331
     10 C                     0.457438
     11 H                     0.142874
     12 H                     0.171461
     13 O                    -0.441996
     14 C                    -0.532869
     15 H                     0.178926
     16 H                     0.169603
     17 H                     0.169005
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.7778      Y      -2.2628      Z      -0.4368
       Tot       2.4322
    Quadrupole Moments (Debye-Ang)
        XX     -44.6392     XY       5.6363     YY     -44.2190
        XZ       0.0791     YZ      -1.1725     ZZ     -43.0686
    Octapole Moments (Debye-Ang^2)
       XXX      -2.8877    XXY      -9.4167    XYY       4.9747
       YYY      -0.5113    XXZ      -6.4171    XYZ      -0.3679
       YYZ      -1.6179    XZZ      -7.6540    YZZ       1.3523
       ZZZ      -4.3499
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1093.9034   XXXY      12.6526   XXYY    -232.8229
      XYYY       4.8418   YYYY    -234.1940   XXXZ     -13.2275
      XXYZ      -5.7586   XYYZ       3.4640   YYYZ      -6.7931
      XXZZ    -211.9703   XYZZ       0.9586   YYZZ     -52.5617
      XZZZ       4.8619   YZZZ      -6.0595   ZZZZ     -84.2601
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:22:14 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0000009  -0.0000799  -0.0001198   0.0000747   0.0005104  -0.0001629
    2  -0.0004561  -0.0001022   0.0002580  -0.0001882   0.0006355   0.0003730
    3  -0.0006652   0.0003053  -0.0004421   0.0003803  -0.0014385   0.0006618
            7           8           9          10          11          12
    1   0.0004400  -0.0005249  -0.0013674  -0.0001101   0.0008132   0.0000825
    2   0.0000028   0.0001894  -0.0013838   0.0006521  -0.0002038   0.0002122
    3   0.0002838   0.0009088  -0.0004450   0.0003166  -0.0001386   0.0001821
           13          14          15          16          17
    1   0.0001710   0.0002053  -0.0002264   0.0003406  -0.0000472
    2  -0.0000866   0.0005602  -0.0001572   0.0000466  -0.0003519
    3  -0.0001781  -0.0002075   0.0002381  -0.0000804   0.0003187
 Max gradient component =       1.439E-03
 RMS gradient           =       4.901E-04
 Gradient time:  CPU 12.24 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:22:26 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:   4

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.545817   -1.668779    0.401294
    2  C           3.009081   -0.749434    0.044906
    3  C           2.343384    0.405723   -0.011589
    4  H           4.047339   -0.828397   -0.266039
    5  C           0.902127    0.597866    0.409729
    6  H           2.860612    1.292131   -0.379251
    7  H           0.639065    1.659097    0.401266
    8  H           0.770513    0.260778    1.448658
    9  C          -0.109997   -0.157188   -0.481721
   10  C          -1.548862    0.116011   -0.041861
   11  H           0.109848   -1.230855   -0.485944
   12  H          -0.009517    0.191688   -1.518864
   13  O          -1.933505    1.251437    0.165978
   14  C          -2.455252   -1.086669    0.137630
   15  H          -3.461430   -0.768884    0.419633
   16  H          -2.044147   -1.741854    0.917447
   17  H          -2.494958   -1.685476   -0.781126
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.855919851

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000470    0.001501    0.002567    0.005183    0.019559    0.029399
     0.039232    0.041581    0.042293    0.044233    0.046990    0.048733
     0.054862    0.056809    0.077913    0.080142    0.107150    0.121441
     0.126360    0.129260    0.133157    0.142980    0.149859    0.164198
     0.188178    0.196569    0.204327    0.215806    0.235705    0.261576
     0.292341    0.301206    0.301473    0.301709    0.302117    0.302554
     0.302852    0.307299    0.308075    0.311209    0.316798    0.327505
     0.470763    0.669264    0.845587

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00117301
 Calculated Step too Large.  Step scaled by  0.388340
 Step Taken.  Stepsize is  0.300000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002341      0.000300      NO
         Displacement       0.139865      0.001200      NO
         Energy change     -0.000486      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.589393
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.641353    -1.632094     0.527202
    2      C       3.053480    -0.727837     0.078855
    3      C       2.344632     0.395979    -0.050704
    4      H       4.082687    -0.791868    -0.265042
    5      C       0.912663     0.582811     0.403399
    6      H       2.819896     1.261949    -0.512569
    7      H       0.648875     1.643716     0.399401
    8      H       0.803492     0.246537     1.445145
    9      C      -0.121758    -0.171088    -0.460976
   10      C      -1.551253     0.115057     0.001916
   11      H       0.083771    -1.247847    -0.466400
   12      H      -0.042420     0.166405    -1.504908
   13      O      -1.906545     1.244861     0.281938
   14      C      -2.486473    -1.074540     0.104015
   15      H      -3.492057    -0.754651     0.387112
   16      H      -2.098961    -1.774911     0.856081
   17      H      -2.521263    -1.625284    -0.844319
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.8285488288 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:22:26 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000001011 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:22:26 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded   1002 shell pairs
 There are   7037 function pairs
 Smallest overlap matrix eigenvalue = 3.51E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:22:27 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8414369693      2.65E-03
    2    -309.8561859051      2.39E-04
    3    -309.8563177282      2.23E-04
    4    -309.8564026857      8.90E-05
    5    -309.8564120992      4.35E-05
    6    -309.8564150938      7.39E-06
    7    -309.8564151990      2.25E-06
    8    -309.8564152221      6.44E-07
    9    -309.8564152127      3.99E-07
   10    -309.8564152254      9.47E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 33.64 s  wall 33.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:23:01 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.132586
      2 C                    -0.329154
      3 C                    -0.069826
      4 H                     0.141249
      5 C                    -0.302787
      6 H                     0.132344
      7 H                     0.169170
      8 H                     0.151006
      9 C                    -0.341439
     10 C                     0.458305
     11 H                     0.144267
     12 H                     0.170825
     13 O                    -0.441929
     14 C                    -0.532412
     15 H                     0.178879
     16 H                     0.170306
     17 H                     0.168610
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.6793      Y      -2.2642      Z      -0.6192
       Tot       2.4436
    Quadrupole Moments (Debye-Ang)
        XX     -44.4796     XY       5.4460     YY     -44.2953
        XZ       0.3744     YZ      -1.6707     ZZ     -43.0451
    Octapole Moments (Debye-Ang^2)
       XXX      -4.8261    XXY      -9.4718    XYY       4.3140
       YYY      -0.2524    XXZ      -7.9336    XYZ      -0.3139
       YYZ      -2.4678    XZZ      -7.2511    YZZ       1.1698
       ZZZ      -6.2067
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1110.0610   XXXY       9.1792   XXYY    -235.1422
      XYYY       3.5021   YYYY    -229.6968   XXXZ     -11.3885
      XXYZ      -9.1203   XYYZ       4.8494   YYYZ      -9.8570
      XXZZ    -214.3195   XYZZ       0.9034   YYZZ     -51.9227
      XZZZ       6.8132   YZZZ      -7.8069   ZZZZ     -85.6240
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:23:01 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0000785   0.0001765   0.0002124   0.0002276  -0.0001671   0.0000800
    2  -0.0013025  -0.0003820   0.0008002   0.0002630   0.0008505   0.0004727
    3  -0.0006764   0.0005287  -0.0006235   0.0003083  -0.0018343   0.0007565
            7           8           9          10          11          12
    1   0.0005748  -0.0007443  -0.0011221   0.0001695   0.0002789   0.0000701
    2  -0.0001227   0.0003209  -0.0016540   0.0000893  -0.0003304   0.0002200
    3   0.0000533   0.0011474   0.0003074   0.0004381  -0.0004843  -0.0000741
           13          14          15          16          17
    1   0.0000827   0.0003471  -0.0005770   0.0005192  -0.0000500
    2   0.0007069   0.0004995  -0.0004085   0.0002533  -0.0002763
    3  -0.0001070  -0.0001676   0.0002563  -0.0001346   0.0003060
 Max gradient component =       1.834E-03
 RMS gradient           =       5.933E-04
 Gradient time:  CPU 12.38 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:23:13 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:   5

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.641353   -1.632094    0.527202
    2  C           3.053480   -0.727837    0.078855
    3  C           2.344632    0.395979   -0.050704
    4  H           4.082687   -0.791868   -0.265042
    5  C           0.912663    0.582811    0.403399
    6  H           2.819896    1.261949   -0.512569
    7  H           0.648875    1.643716    0.399401
    8  H           0.803492    0.246537    1.445145
    9  C          -0.121758   -0.171088   -0.460976
   10  C          -1.551253    0.115057    0.001916
   11  H           0.083771   -1.247847   -0.466400
   12  H          -0.042420    0.166405   -1.504908
   13  O          -1.906545    1.244861    0.281938
   14  C          -2.486473   -1.074540    0.104015
   15  H          -3.492057   -0.754651    0.387112
   16  H          -2.098961   -1.774911    0.856081
   17  H          -2.521263   -1.625284   -0.844319
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.856415225

 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
    -0.001711    0.001044    0.002384    0.005143    0.018871    0.028148
     0.035813    0.040979    0.042117    0.042278    0.046198    0.047229
     0.054405    0.056385    0.075090    0.078165    0.105657    0.120947
     0.121368    0.127463    0.132108    0.141794    0.148832    0.159676
     0.186250    0.196542    0.203663    0.213906    0.231012    0.261557
     0.291719    0.300422    0.301471    0.301551    0.301947    0.302320
     0.302763    0.303904    0.307935    0.310145    0.316788    0.321223
     0.411448    0.643449    0.831279
**WARNING** Hessian does not have the Desired Local Structure

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00305437
 Calculated Step too Large.  Step scaled by  0.164997
 Step Taken.  Stepsize is  0.240000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.003082      0.000300      NO
         Displacement       0.105789      0.001200      NO
         Energy change     -0.000495      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.449430
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.718058    -1.585430     0.635537
    2      C       3.086253    -0.707632     0.105181
    3      C       2.340862     0.383924    -0.080477
    4      H       4.105036    -0.769611    -0.268977
    5      C       0.919771     0.565514     0.404661
    6      H       2.775410     1.226402    -0.619833
    7      H       0.655932     1.626548     0.416591
    8      H       0.829687     0.217111     1.443988
    9      C      -0.129501    -0.177786    -0.450345
   10      C      -1.553026     0.114056     0.025796
   11      H       0.068943    -1.256014    -0.464584
   12      H      -0.061424     0.162628    -1.494668
   13      O      -1.892569     1.237998     0.345711
   14      C      -2.506512    -1.064160     0.081583
   15      H      -3.508098    -0.739182     0.373006
   16      H      -2.133783    -1.795193     0.811826
   17      H      -2.544920    -1.581980    -0.884850
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.6383929029 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:23:13 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000001006 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:23:13 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    999 shell pairs
 There are   7031 function pairs
 Smallest overlap matrix eigenvalue = 3.48E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:23:13 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8501223642      1.79E-03
    2    -309.8568338244      1.60E-04
    3    -309.8569093069      1.44E-04
    4    -309.8569457246      5.66E-05
    5    -309.8569493738      3.27E-05
    6    -309.8569510530      5.91E-06
    7    -309.8569511035      2.90E-06
    8    -309.8569511421      6.64E-07
    9    -309.8569511564      2.12E-07
   10    -309.8569511813      5.24E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 33.48 s  wall 34.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:23:47 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.132812
      2 C                    -0.329589
      3 C                    -0.068168
      4 H                     0.140986
      5 C                    -0.302852
      6 H                     0.131678
      7 H                     0.169465
      8 H                     0.149952
      9 C                    -0.342480
     10 C                     0.458716
     11 H                     0.145362
     12 H                     0.170300
     13 O                    -0.441756
     14 C                    -0.532256
     15 H                     0.178881
     16 H                     0.170360
     17 H                     0.168589
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.6264      Y      -2.2592      Z      -0.7227
       Tot       2.4533
    Quadrupole Moments (Debye-Ang)
        XX     -44.4128     XY       5.2820     YY     -44.3879
        XZ       0.5399     YZ      -1.9705     ZZ     -42.9790
    Octapole Moments (Debye-Ang^2)
       XXX      -5.9612    XXY      -9.6940    XYY       3.7501
       YYY       0.0484    XXZ      -8.7263    XYZ      -0.4136
       YYZ      -2.9022    XZZ      -6.7726    YZZ       1.0417
       ZZZ      -7.2511
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1122.2288   XXXY       6.3864   XXYY    -236.7626
      XYYY       3.0719   YYYY    -225.2066   XXXZ     -11.0811
      XXYZ     -11.1168   XYYZ       5.4738   YYYZ     -11.2510
      XXZZ    -215.5664   XYZZ       0.8914   YYZZ     -51.3550
      XZZZ       7.3563   YZZZ      -8.6858   ZZZZ     -87.7214
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:23:47 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0003159  -0.0001991   0.0001665   0.0002469  -0.0002790   0.0002339
    2  -0.0010519  -0.0003902   0.0003248   0.0002058   0.0009346   0.0006363
    3  -0.0006657   0.0003114  -0.0006159   0.0003471  -0.0019347   0.0009967
            7           8           9          10          11          12
    1   0.0005452  -0.0007096  -0.0011904   0.0004764   0.0001540   0.0000014
    2  -0.0001495   0.0004899  -0.0017428   0.0002133  -0.0004271   0.0002288
    3  -0.0000601   0.0012165   0.0005401   0.0008140  -0.0006016  -0.0001298
           13          14          15          16          17
    1  -0.0000302   0.0003452  -0.0005303   0.0004688  -0.0000155
    2   0.0006688   0.0005724  -0.0004466   0.0002480  -0.0003143
    3  -0.0002933  -0.0006888   0.0004589  -0.0000190   0.0003242
 Max gradient component =       1.935E-03
 RMS gradient           =       6.312E-04
 Gradient time:  CPU 12.22 s  wall 13.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:24:00 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:   6

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.718058   -1.585430    0.635537
    2  C           3.086253   -0.707632    0.105181
    3  C           2.340862    0.383924   -0.080477
    4  H           4.105036   -0.769611   -0.268977
    5  C           0.919771    0.565514    0.404661
    6  H           2.775410    1.226402   -0.619833
    7  H           0.655932    1.626548    0.416591
    8  H           0.829687    0.217111    1.443988
    9  C          -0.129501   -0.177786   -0.450345
   10  C          -1.553026    0.114056    0.025796
   11  H           0.068943   -1.256014   -0.464584
   12  H          -0.061424    0.162628   -1.494668
   13  O          -1.892569    1.237998    0.345711
   14  C          -2.506512   -1.064160    0.081583
   15  H          -3.508098   -0.739182    0.373006
   16  H          -2.133783   -1.795193    0.811826
   17  H          -2.544920   -1.581980   -0.884850
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.856951181

 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
    -0.001278    0.001029    0.002061    0.005130    0.018942    0.026356
     0.035799    0.040836    0.042251    0.042297    0.045829    0.047149
     0.053495    0.056433    0.074602    0.078162    0.104907    0.121018
     0.121319    0.127469    0.132160    0.141889    0.148793    0.160032
     0.185142    0.194452    0.203714    0.214037    0.230951    0.261347
     0.291843    0.299854    0.301451    0.301586    0.301980    0.302326
     0.302713    0.303898    0.307497    0.309867    0.313644    0.321803
     0.412197    0.644827    0.831517
**WARNING** Hessian does not have the Desired Local Structure

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00301239
 Calculated Step too Large.  Step scaled by  0.071005
 Step Taken.  Stepsize is  0.090000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002969      0.000300      NO
         Displacement       0.035983      0.001200      NO
         Energy change     -0.000536      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.158173
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.742881    -1.565815     0.674961
    2      C       3.096963    -0.700312     0.115398
    3      C       2.339155     0.378939    -0.090672
    4      H       4.111522    -0.763733    -0.269833
    5      C       0.922150     0.559181     0.405188
    6      H       2.758451     1.210441    -0.658483
    7      H       0.658851     1.620365     0.423986
    8      H       0.838244     0.204751     1.442853
    9      C      -0.132021    -0.178491    -0.448599
   10      C      -1.553652     0.113487     0.033134
   11      H       0.064819    -1.256903    -0.468142
   12      H      -0.067502     0.165888    -1.491949
   13      O      -1.888010     1.234570     0.368203
   14      C      -2.512437    -1.061079     0.075011
   15      H      -3.513048    -0.734124     0.367485
   16      H      -2.144708    -1.801324     0.798433
   17      H      -2.551541    -1.568647    -0.896829
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.5825579649 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:24:00 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000001003 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:24:00 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    998 shell pairs
 There are   7030 function pairs
 Smallest overlap matrix eigenvalue = 3.47E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:24:00 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8563578666      6.52E-04
    2    -309.8571546871      4.83E-05
    3    -309.8571657275      3.18E-05
    4    -309.8571670867      2.02E-05
    5    -309.8571677321      8.15E-06
    6    -309.8571678408      2.56E-06
    7    -309.8571678464      1.07E-06
    8    -309.8571678611      1.81E-07
    9    -309.8571678834      4.64E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 29.36 s  wall 29.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:24:30 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.132865
      2 C                    -0.329789
      3 C                    -0.067335
      4 H                     0.140898
      5 C                    -0.302856
      6 H                     0.131425
      7 H                     0.169554
      8 H                     0.149501
      9 C                    -0.342890
     10 C                     0.458766
     11 H                     0.145743
     12 H                     0.170067
     13 O                    -0.441654
     14 C                    -0.532178
     15 H                     0.178913
     16 H                     0.170520
     17 H                     0.168447
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.6088      Y      -2.2557      Z      -0.7610
       Tot       2.4572
    Quadrupole Moments (Debye-Ang)
        XX     -44.3944     XY       5.2203     YY     -44.4235
        XZ       0.5975     YZ      -2.0748     ZZ     -42.9547
    Octapole Moments (Debye-Ang^2)
       XXX      -6.3702    XXY      -9.7719    XYY       3.5162
       YYY       0.1802    XXZ      -9.0080    XYZ      -0.4339
       YYZ      -3.0535    XZZ      -6.5657    YZZ       0.9978
       ZZZ      -7.6190
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1126.0505   XXXY       5.3520   XXYY    -237.2868
      XYYY       2.9430   YYYY    -223.4996   XXXZ     -10.9506
      XXYZ     -11.7667   XYYZ       5.6531   YYYZ     -11.6521
      XXZZ    -215.9311   XYZZ       0.8795   YYZZ     -51.1740
      XZZZ       7.4924   YZZZ      -8.9878   ZZZZ     -88.7190
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:24:30 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0002970  -0.0002075   0.0002093   0.0002433  -0.0003029   0.0002670
    2  -0.0010818  -0.0003908   0.0003021   0.0002282   0.0008943   0.0006860
    3  -0.0005692   0.0002213  -0.0006119   0.0003087  -0.0018783   0.0010361
            7           8           9          10          11          12
    1   0.0005109  -0.0006761  -0.0011442   0.0004331   0.0001474  -0.0000029
    2  -0.0001573   0.0005169  -0.0017721   0.0001913  -0.0003891   0.0002516
    3  -0.0001385   0.0012095   0.0005377   0.0006881  -0.0005865  -0.0001030
           13          14          15          16          17
    1  -0.0000359   0.0003603  -0.0005240   0.0004581  -0.0000329
    2   0.0006819   0.0005367  -0.0004236   0.0002216  -0.0002959
    3  -0.0002560  -0.0005252   0.0003953  -0.0000336   0.0003056
 Max gradient component =       1.878E-03
 RMS gradient           =       6.164E-04
 Gradient time:  CPU 12.08 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:24:42 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:   7

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.742881   -1.565815    0.674961
    2  C           3.096963   -0.700312    0.115398
    3  C           2.339155    0.378939   -0.090672
    4  H           4.111522   -0.763733   -0.269833
    5  C           0.922150    0.559181    0.405188
    6  H           2.758451    1.210441   -0.658483
    7  H           0.658851    1.620365    0.423986
    8  H           0.838244    0.204751    1.442853
    9  C          -0.132021   -0.178491   -0.448599
   10  C          -1.553652    0.113487    0.033134
   11  H           0.064819   -1.256903   -0.468142
   12  H          -0.067502    0.165888   -1.491949
   13  O          -1.888010    1.234570    0.368203
   14  C          -2.512437   -1.061079    0.075011
   15  H          -3.513048   -0.734124    0.367485
   16  H          -2.144708   -1.801324    0.798433
   17  H          -2.551541   -1.568647   -0.896829
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.857167883

 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
    -0.000802    0.000968    0.002111    0.005092    0.018979    0.026557
     0.035442    0.040756    0.042222    0.042323    0.045828    0.046926
     0.052631    0.056441    0.074510    0.078139    0.104809    0.121101
     0.121358    0.127502    0.132207    0.141906    0.148786    0.160293
     0.185243    0.193980    0.203789    0.214291    0.230758    0.261356
     0.291656    0.299574    0.301443    0.301634    0.302020    0.302336
     0.302605    0.303999    0.307180    0.309809    0.313235    0.321898
     0.420305    0.647242    0.831990
**WARNING** Hessian does not have the Desired Local Structure

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00284569
 Calculated Step too Large.  Step scaled by  0.079137
 Step Taken.  Stepsize is  0.090000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002846      0.000300      NO
         Displacement       0.037415      0.001200      NO
         Energy change     -0.000217      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.161536
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.768545    -1.544170     0.714384
    2      C       3.107809    -0.692497     0.125321
    3      C       2.337182     0.373524    -0.100714
    4      H       4.117821    -0.758054    -0.271293
    5      C       0.924667     0.552789     0.406269
    6      H       2.740575     1.192817    -0.697209
    7      H       0.661902     1.614139     0.431412
    8      H       0.847318     0.192900     1.442338
    9      C      -0.134354    -0.179414    -0.446038
   10      C      -1.554193     0.112720     0.040628
   11      H       0.060578    -1.258075    -0.470551
   12      H      -0.073192     0.168374    -1.488583
   13      O      -1.883791     1.230939     0.389591
   14      C      -2.518500    -1.057830     0.067865
   15      H      -3.517581    -0.729021     0.363348
   16      H      -2.155411    -1.808116     0.783231
   17      H      -2.559257    -1.553830    -0.909853
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.5320476578 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:24:42 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000001000 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:24:42 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    998 shell pairs
 There are   7030 function pairs
 Smallest overlap matrix eigenvalue = 3.45E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:24:42 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8567426205      6.41E-04
    2    -309.8573824622      4.84E-05
    3    -309.8573934926      3.26E-05
    4    -309.8573949268      2.06E-05
    5    -309.8573956199      7.91E-06
    6    -309.8573957176      2.56E-06
    7    -309.8573957294      1.11E-06
    8    -309.8573957471      1.72E-07
    9    -309.8573957566      4.90E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 29.50 s  wall 30.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:25:12 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.132928
      2 C                    -0.330044
      3 C                    -0.066414
      4 H                     0.140815
      5 C                    -0.302859
      6 H                     0.131134
      7 H                     0.169650
      8 H                     0.149069
      9 C                    -0.343300
     10 C                     0.458805
     11 H                     0.146100
     12 H                     0.169852
     13 O                    -0.441547
     14 C                    -0.532106
     15 H                     0.178946
     16 H                     0.170576
     17 H                     0.168395
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.5916      Y      -2.2520      Z      -0.7974
       Tot       2.4612
    Quadrupole Moments (Debye-Ang)
        XX     -44.3805     XY       5.1574     YY     -44.4643
        XZ       0.6537     YZ      -2.1701     ZZ     -42.9240
    Octapole Moments (Debye-Ang^2)
       XXX      -6.7650    XXY      -9.8634    XYY       3.2706
       YYY       0.3232    XXZ      -9.2644    XYZ      -0.4561
       YYZ      -3.2028    XZZ      -6.3478    YZZ       0.9546
       ZZZ      -7.9839
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1130.0320   XXXY       4.2756   XXYY    -237.8429
      XYYY       2.8139   YYYY    -221.7145   XXXZ     -10.8807
      XXYZ     -12.3789   XYYZ       5.8039   YYYZ     -12.0414
      XXZZ    -216.2510   XYZZ       0.8584   YYZZ     -50.9910
      XZZZ       7.5777   YZZZ      -9.3054   ZZZZ     -89.7350
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:25:12 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0003012  -0.0002460   0.0001980   0.0002337  -0.0003094   0.0003093
    2  -0.0010230  -0.0004138   0.0002303   0.0002213   0.0008012   0.0007344
    3  -0.0005093   0.0001210  -0.0005631   0.0002796  -0.0017518   0.0010708
            7           8           9          10          11          12
    1   0.0004547  -0.0006116  -0.0010878   0.0004544   0.0001234  -0.0000087
    2  -0.0001513   0.0005652  -0.0016991   0.0001585  -0.0003650   0.0002561
    3  -0.0002225   0.0011618   0.0005318   0.0007233  -0.0005798  -0.0000992
           13          14          15          16          17
    1  -0.0000550   0.0003294  -0.0004885   0.0004338  -0.0000308
    2   0.0006431   0.0005237  -0.0004093   0.0002134  -0.0002857
    3  -0.0002999  -0.0005514   0.0004090  -0.0000118   0.0002915
 Max gradient component =       1.752E-03
 RMS gradient           =       5.938E-04
 Gradient time:  CPU 12.15 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:25:24 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:   8

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.768545   -1.544170    0.714384
    2  C           3.107809   -0.692497    0.125321
    3  C           2.337182    0.373524   -0.100714
    4  H           4.117821   -0.758054   -0.271293
    5  C           0.924667    0.552789    0.406269
    6  H           2.740575    1.192817   -0.697209
    7  H           0.661902    1.614139    0.431412
    8  H           0.847318    0.192900    1.442338
    9  C          -0.134354   -0.179414   -0.446038
   10  C          -1.554193    0.112720    0.040628
   11  H           0.060578   -1.258075   -0.470551
   12  H          -0.073192    0.168374   -1.488583
   13  O          -1.883791    1.230939    0.389591
   14  C          -2.518500   -1.057830    0.067865
   15  H          -3.517581   -0.729021    0.363348
   16  H          -2.155411   -1.808116    0.783231
   17  H          -2.559257   -1.553830   -0.909853
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.857395757

 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
    -0.000767    0.001003    0.002066    0.005072    0.019002    0.026083
     0.035695    0.040784    0.042144    0.042306    0.045791    0.046970
     0.052644    0.056497    0.074474    0.078136    0.104879    0.121191
     0.121463    0.127522    0.132116    0.142036    0.148842    0.161237
     0.185103    0.194165    0.203722    0.214531    0.230873    0.261394
     0.291612    0.299572    0.301443    0.301671    0.302031    0.302357
     0.302595    0.304154    0.307271    0.309735    0.313749    0.322940
     0.432098    0.650686    0.832146
**WARNING** Hessian does not have the Desired Local Structure

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00292185
 Calculated Step too Large.  Step scaled by  0.079387
 Step Taken.  Stepsize is  0.090000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002694      0.000300      NO
         Displacement       0.037799      0.001200      NO
         Energy change     -0.000228      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.162817
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.794180    -1.521077     0.752951
    2      C       3.118706    -0.684276     0.135026
    3      C       2.335191     0.367825    -0.110741
    4      H       4.124120    -0.752374    -0.272629
    5      C       0.927246     0.546486     0.407161
    6      H       2.722488     1.173873    -0.735419
    7      H       0.665137     1.608012     0.438123
    8      H       0.856372     0.181681     1.441761
    9      C      -0.136621    -0.180587    -0.443326
   10      C      -1.554665     0.111631     0.048491
   11      H       0.056546    -1.259431    -0.472671
   12      H      -0.078918     0.170671    -1.485005
   13      O      -1.879051     1.226538     0.412567
   14      C      -2.524690    -1.054538     0.060698
   15      H      -3.522473    -0.723514     0.357937
   16      H      -2.167025    -1.814887     0.768066
   17      H      -2.566426    -1.538841    -0.922843
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.4835754808 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:25:24 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000996 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:25:24 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    999 shell pairs
 There are   7031 function pairs
 Smallest overlap matrix eigenvalue = 3.44E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:25:25 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8569320704      6.63E-04
    2    -309.8576164978      4.94E-05
    3    -309.8576278905      3.32E-05
    4    -309.8576293663      2.10E-05
    5    -309.8576300772      8.14E-06
    6    -309.8576301782      2.65E-06
    7    -309.8576301925      1.12E-06
    8    -309.8576302063      1.84E-07
    9    -309.8576302158      5.03E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 29.42 s  wall 29.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:25:54 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.132993
      2 C                    -0.330346
      3 C                    -0.065432
      4 H                     0.140724
      5 C                    -0.302825
      6 H                     0.130814
      7 H                     0.169746
      8 H                     0.148649
      9 C                    -0.343801
     10 C                     0.458832
     11 H                     0.146486
     12 H                     0.169631
     13 O                    -0.441416
     14 C                    -0.532023
     15 H                     0.178985
     16 H                     0.170705
     17 H                     0.168278
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.5729      Y      -2.2473      Z      -0.8359
       Tot       2.4652
    Quadrupole Moments (Debye-Ang)
        XX     -44.3631     XY       5.0909     YY     -44.5034
        XZ       0.7167     YZ      -2.2658     ZZ     -42.8968
    Octapole Moments (Debye-Ang^2)
       XXX      -7.1832    XXY      -9.9388    XYY       3.0012
       YYY       0.4862    XXZ      -9.5232    XYZ      -0.4600
       YYZ      -3.3625    XZZ      -6.1149    YZZ       0.9115
       ZZZ      -8.3715
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1133.9442   XXXY       3.1085   XXYY    -238.3922
      XYYY       2.6290   YYYY    -219.8122   XXXZ     -10.6823
      XXYZ     -12.9947   XYYZ       5.9587   YYYZ     -12.4697
      XXZZ    -216.5935   XYZZ       0.8214   YYZZ     -50.8213
      XZZZ       7.7155   YZZZ      -9.6836   ZZZZ     -90.8347
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:25:54 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0002620  -0.0002536   0.0002047   0.0002206  -0.0003086   0.0003410
    2  -0.0009896  -0.0004339   0.0001906   0.0002214   0.0007147   0.0007758
    3  -0.0004334   0.0000256  -0.0005298   0.0002445  -0.0016170   0.0010945
            7           8           9          10          11          12
    1   0.0003961  -0.0005509  -0.0010101   0.0004082   0.0001193  -0.0000074
    2  -0.0001453   0.0005998  -0.0016781   0.0001374  -0.0003293   0.0002829
    3  -0.0003034   0.0011157   0.0004987   0.0006463  -0.0005605  -0.0000706
           13          14          15          16          17
    1  -0.0000588   0.0003234  -0.0004607   0.0004143  -0.0000396
    2   0.0006294   0.0004754  -0.0003791   0.0001900  -0.0002620
    3  -0.0002959  -0.0004307   0.0003643  -0.0000163   0.0002680
 Max gradient component =       1.678E-03
 RMS gradient           =       5.666E-04
 Gradient time:  CPU 12.06 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:26:07 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:   9

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.794180   -1.521077    0.752951
    2  C           3.118706   -0.684276    0.135026
    3  C           2.335191    0.367825   -0.110741
    4  H           4.124120   -0.752374   -0.272629
    5  C           0.927246    0.546486    0.407161
    6  H           2.722488    1.173873   -0.735419
    7  H           0.665137    1.608012    0.438123
    8  H           0.856372    0.181681    1.441761
    9  C          -0.136621   -0.180587   -0.443326
   10  C          -1.554665    0.111631    0.048491
   11  H           0.056546   -1.259431   -0.472671
   12  H          -0.078918    0.170671   -1.485005
   13  O          -1.879051    1.226538    0.412567
   14  C          -2.524690   -1.054538    0.060698
   15  H          -3.522473   -0.723514    0.357937
   16  H          -2.167025   -1.814887    0.768066
   17  H          -2.566426   -1.538841   -0.922843
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.857630216

 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
    -0.000661    0.001007    0.002118    0.005053    0.019034    0.026349
     0.035916    0.040731    0.041955    0.042260    0.045787    0.046985
     0.052393    0.056497    0.074380    0.078126    0.104770    0.121206
     0.121662    0.127516    0.132048    0.142214    0.148884    0.161584
     0.185368    0.193394    0.203700    0.214644    0.230973    0.261371
     0.291576    0.299485    0.301443    0.301670    0.302021    0.302374
     0.302583    0.304322    0.307136    0.309751    0.313505    0.322916
     0.436877    0.652327    0.832729
**WARNING** Hessian does not have the Desired Local Structure

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00295388
 Calculated Step too Large.  Step scaled by  0.080783
 Step Taken.  Stepsize is  0.090000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002554      0.000300      NO
         Displacement       0.039667      0.001200      NO
         Energy change     -0.000234      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.168293
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.821792    -1.496155     0.790822
    2      C       3.130331    -0.675264     0.144219
    3      C       2.333147     0.361723    -0.120702
    4      H       4.130947    -0.745758    -0.274627
    5      C       0.930001     0.539938     0.408355
    6      H       2.703680     1.153536    -0.773305
    7      H       0.668492     1.601632     0.444262
    8      H       0.865936     0.171221     1.441779
    9      C      -0.138855    -0.182649    -0.439401
   10      C      -1.555117     0.110237     0.056954
   11      H       0.052062    -1.261782    -0.472736
   12      H      -0.084611     0.170920    -1.480620
   13      O      -1.874088     1.221738     0.435832
   14      C      -2.531551    -1.050719     0.052743
   15      H      -3.527776    -0.717340     0.352428
   16      H      -2.179847    -1.821992     0.751165
   17      H      -2.574426    -1.522089    -0.937022
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.4316695025 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:26:07 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000993 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:26:07 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    998 shell pairs
 There are   7030 function pairs
 Smallest overlap matrix eigenvalue = 3.43E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:26:07 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8572080408      6.71E-04
    2    -309.8578563440      5.04E-05
    3    -309.8578679039      3.55E-05
    4    -309.8578695904      2.22E-05
    5    -309.8578703851      8.27E-06
    6    -309.8578704881      2.77E-06
    7    -309.8578704990      1.18E-06
    8    -309.8578705139      1.86E-07
    9    -309.8578705252      5.56E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 29.52 s  wall 30.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:26:37 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.133084
      2 C                    -0.330701
      3 C                    -0.064431
      4 H                     0.140624
      5 C                    -0.302750
      6 H                     0.130461
      7 H                     0.169851
      8 H                     0.148262
      9 C                    -0.344357
     10 C                     0.458866
     11 H                     0.146880
     12 H                     0.169420
     13 O                    -0.441278
     14 C                    -0.531941
     15 H                     0.179024
     16 H                     0.170783
     17 H                     0.168205
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.5531      Y      -2.2425      Z      -0.8739
       Tot       2.4695
    Quadrupole Moments (Debye-Ang)
        XX     -44.3435     XY       5.0222     YY     -44.5453
        XZ       0.7834     YZ      -2.3559     ZZ     -42.8679
    Octapole Moments (Debye-Ang^2)
       XXX      -7.6101    XXY     -10.0125    XYY       2.7138
       YYY       0.6649    XXZ      -9.7647    XYZ      -0.4577
       YYZ      -3.5284    XZZ      -5.8717    YZZ       0.8680
       ZZZ      -8.7749
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1138.1866   XXXY       1.8769   XXYY    -238.9988
      XYYY       2.4093   YYYY    -217.7561   XXXZ     -10.4554
      XXYZ     -13.6054   XYYZ       6.1011   YYYZ     -12.9363
      XXZZ    -216.9672   XYZZ       0.7693   YYZZ     -50.6508
      XZZZ       7.8530   YZZZ     -10.1171   ZZZZ     -91.9544
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:26:37 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0002500  -0.0002820   0.0001937   0.0002077  -0.0003019   0.0003793
    2  -0.0009207  -0.0004651   0.0001405   0.0002078   0.0006097   0.0008176
    3  -0.0003716  -0.0000677  -0.0004717   0.0002152  -0.0014649   0.0011062
            7           8           9          10          11          12
    1   0.0003335  -0.0004859  -0.0009373   0.0004011   0.0000956  -0.0000077
    2  -0.0001427   0.0006386  -0.0016090   0.0001004  -0.0003013   0.0002993
    3  -0.0003822   0.0010550   0.0004949   0.0006554  -0.0005618  -0.0000606
           13          14          15          16          17
    1  -0.0000725   0.0003019  -0.0004271   0.0003894  -0.0000379
    2   0.0005993   0.0004494  -0.0003603   0.0001789  -0.0002422
    3  -0.0003369  -0.0004124   0.0003602  -0.0000043   0.0002473
 Max gradient component =       1.609E-03
 RMS gradient           =       5.414E-04
 Gradient time:  CPU 12.17 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:26:49 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  10

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.821792   -1.496155    0.790822
    2  C           3.130331   -0.675264    0.144219
    3  C           2.333147    0.361723   -0.120702
    4  H           4.130947   -0.745758   -0.274627
    5  C           0.930001    0.539938    0.408355
    6  H           2.703680    1.153536   -0.773305
    7  H           0.668492    1.601632    0.444262
    8  H           0.865936    0.171221    1.441779
    9  C          -0.138855   -0.182649   -0.439401
   10  C          -1.555117    0.110237    0.056954
   11  H           0.052062   -1.261782   -0.472736
   12  H          -0.084611    0.170920   -1.480620
   13  O          -1.874088    1.221738    0.435832
   14  C          -2.531551   -1.050719    0.052743
   15  H          -3.527776   -0.717340    0.352428
   16  H          -2.179847   -1.821992    0.751165
   17  H          -2.574426   -1.522089   -0.937022
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.857870525

 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
    -0.000482    0.000963    0.002114    0.005031    0.018763    0.025523
     0.035207    0.040163    0.041509    0.042269    0.045766    0.047035
     0.052492    0.056463    0.074369    0.078091    0.104764    0.121213
     0.121531    0.127433    0.131692    0.142017    0.148903    0.161881
     0.185479    0.192605    0.203460    0.214243    0.230964    0.261357
     0.291119    0.299484    0.301433    0.301663    0.301954    0.302389
     0.302573    0.304377    0.307208    0.309557    0.313516    0.322238
     0.433478    0.650361    0.832103
**WARNING** Hessian does not have the Desired Local Structure

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00287648
 Calculated Step too Large.  Step scaled by  0.083726
 Step Taken.  Stepsize is  0.090000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002402      0.000300      NO
         Displacement       0.040129      0.001200      NO
         Energy change     -0.000240      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.169879
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.849742    -1.469970     0.827267
    2      C       3.142161    -0.665710     0.153023
    3      C       2.331076     0.355341    -0.130605
    4      H       4.138013    -0.738616    -0.276563
    5      C       0.932785     0.533404     0.409375
    6      H       2.684658     1.132116    -0.810298
    7      H       0.671990     1.595293     0.449744
    8      H       0.875489     0.161405     1.441826
    9      C      -0.141038    -0.185262    -0.435124
   10      C      -1.555483     0.108497     0.065803
   11      H       0.047725    -1.264672    -0.471794
   12      H      -0.090311     0.170149    -1.476005
   13      O      -1.868534     1.216154     0.460477
   14      C      -2.538704    -1.046641     0.044580
   15      H      -3.533497    -0.710463     0.345739
   16      H      -2.193836    -1.828925     0.734025
   17      H      -2.582120    -1.504905    -0.951324
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.3811333381 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:26:49 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000989 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:26:49 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    996 shell pairs
 There are   6993 function pairs
 Smallest overlap matrix eigenvalue = 3.41E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:26:49 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8574203676      6.92E-04
    2    -309.8580972456      5.12E-05
    3    -309.8581090244      3.65E-05
    4    -309.8581107739      2.30E-05
    5    -309.8581116144      8.43E-06
    6    -309.8581117139      2.87E-06
    7    -309.8581117271      1.19E-06
    8    -309.8581117403      1.96E-07
    9    -309.8581117534      5.81E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 29.70 s  wall 30.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:27:19 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.133186
      2 C                    -0.331110
      3 C                    -0.063409
      4 H                     0.140518
      5 C                    -0.302625
      6 H                     0.130083
      7 H                     0.169956
      8 H                     0.147891
      9 C                    -0.344999
     10 C                     0.458896
     11 H                     0.147310
     12 H                     0.169208
     13 O                    -0.441114
     14 C                    -0.531855
     15 H                     0.179067
     16 H                     0.170912
     17 H                     0.168084
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.5316      Y      -2.2367      Z      -0.9134
       Tot       2.4738
    Quadrupole Moments (Debye-Ang)
        XX     -44.3195     XY       4.9502     YY     -44.5845
        XZ       0.8565     YZ      -2.4442     ZZ     -42.8438
    Octapole Moments (Debye-Ang^2)
       XXX      -8.0554    XXY     -10.0662    XYY       2.4045
       YYY       0.8629    XXZ     -10.0000    XYZ      -0.4386
       YYZ      -3.7023    XZZ      -5.6177    YZZ       0.8253
       ZZZ      -9.1989
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1142.4128   XXXY       0.5648   XXYY    -239.6029
      XYYY       2.1291   YYYY    -215.5573   XXXZ     -10.1073
      XXYZ     -14.2147   XYYZ       6.2433   YYYZ     -13.4442
      XXZZ    -217.3801   XYZZ       0.7012   YYZZ     -50.4944
      XZZZ       8.0382   YZZZ     -10.6131   ZZZZ     -93.1439
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:27:19 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0002254  -0.0002881   0.0001784   0.0001918  -0.0002845   0.0003999
    2  -0.0008581  -0.0004925   0.0000959   0.0001984   0.0005262   0.0008520
    3  -0.0003088  -0.0001379  -0.0004260   0.0001875  -0.0013367   0.0011012
            7           8           9          10          11          12
    1   0.0002769  -0.0004279  -0.0008631   0.0003552   0.0000900  -0.0000031
    2  -0.0001361   0.0006607  -0.0015845   0.0000872  -0.0002729   0.0003303
    3  -0.0004395   0.0010072   0.0004580   0.0005920  -0.0005508  -0.0000301
           13          14          15          16          17
    1  -0.0000738   0.0002963  -0.0003982   0.0003684  -0.0000436
    2   0.0005831   0.0004008  -0.0003300   0.0001570  -0.0002175
    3  -0.0003429  -0.0003040   0.0003190  -0.0000109   0.0002226
 Max gradient component =       1.584E-03
 RMS gradient           =       5.165E-04
 Gradient time:  CPU 12.02 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:27:32 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  11

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.849742   -1.469970    0.827267
    2  C           3.142161   -0.665710    0.153023
    3  C           2.331076    0.355341   -0.130605
    4  H           4.138013   -0.738616   -0.276563
    5  C           0.932785    0.533404    0.409375
    6  H           2.684658    1.132116   -0.810298
    7  H           0.671990    1.595293    0.449744
    8  H           0.875489    0.161405    1.441826
    9  C          -0.141038   -0.185262   -0.435124
   10  C          -1.555483    0.108497    0.065803
   11  H           0.047725   -1.264672   -0.471794
   12  H          -0.090311    0.170149   -1.476005
   13  O          -1.868534    1.216154    0.460477
   14  C          -2.538704   -1.046641    0.044580
   15  H          -3.533497   -0.710463    0.345739
   16  H          -2.193836   -1.828925    0.734025
   17  H          -2.582120   -1.504905   -0.951324
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.858111753

 Hessian Updated using BFGS Update
**WARNING** Hereditary positive definiteness endangered
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
    -0.412608    0.000005    0.001296    0.002494    0.005355    0.019684
     0.026174    0.037375    0.041308    0.042199    0.045763    0.046262
     0.050094    0.055797    0.070101    0.077906    0.085259    0.107086
     0.121227    0.123319    0.128202    0.135274    0.144805    0.149205
     0.176395    0.185914    0.201290    0.206310    0.230316    0.235995
     0.262334    0.292450    0.299532    0.301435    0.301758    0.302206
     0.302498    0.302624    0.304836    0.307588    0.309711    0.315547
     0.351446    0.614217    0.827109
**WARNING** Magnitude of eigenvalue   2 too small.  Replaced by     0.000100
**WARNING** Hessian does not have the Desired Local Structure

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.41264379
 Calculated Step too Large.  Step scaled by  0.000838
 Step Taken.  Stepsize is  0.090000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002260      0.000300      NO
         Displacement       0.034311      0.001200      NO
         Energy change     -0.000241      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.283524
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.813110    -1.437304     0.845730
    2      C       3.120267    -0.671143     0.137294
    3      C       2.326475     0.358452    -0.142499
    4      H       4.102661    -0.785145    -0.312547
    5      C       0.948272     0.548636     0.432112
    6      H       2.674574     1.118575    -0.841979
    7      H       0.671913     1.609312     0.463360
    8      H       0.918089     0.188588     1.462135
    9      C      -0.123211    -0.173647    -0.411185
   10      C      -1.554221     0.094132     0.067453
   11      H       0.077323    -1.247449    -0.447418
   12      H      -0.067762     0.191978    -1.445976
   13      O      -1.885535     1.197871     0.457228
   14      C      -2.537666    -1.062706     0.036931
   15      H      -3.528568    -0.707199     0.316842
   16      H      -2.218725    -1.854823     0.727575
   17      H      -2.566878    -1.510934    -0.964911
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.6303507934 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:27:32 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000986 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:27:32 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    998 shell pairs
 There are   6990 function pairs
 Smallest overlap matrix eigenvalue = 3.38E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:27:32 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8626131793      9.24E-04
    2    -309.8578942725      1.37E-04
    3    -309.8578782668      2.02E-04
    4    -309.8579417756      4.86E-05
    5    -309.8579452115      1.67E-05
    6    -309.8579456815      3.55E-06
    7    -309.8579457001      2.03E-06
    8    -309.8579457295      4.92E-07
    9    -309.8579457435      1.25E-07
   10    -309.8579457256      3.46E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 33.12 s  wall 33.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:28:06 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.132311
      2 C                    -0.330999
      3 C                    -0.060880
      4 H                     0.140935
      5 C                    -0.303265
      6 H                     0.129948
      7 H                     0.168529
      8 H                     0.149627
      9 C                    -0.344345
     10 C                     0.455352
     11 H                     0.147044
     12 H                     0.169159
     13 O                    -0.440154
     14 C                    -0.531614
     15 H                     0.180301
     16 H                     0.171100
     17 H                     0.166951
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.5859      Y      -2.2106      Z      -0.8993
       Tot       2.4574
    Quadrupole Moments (Debye-Ang)
        XX     -44.4430     XY       4.9228     YY     -44.5733
        XZ       0.8283     YZ      -2.4341     ZZ     -42.7245
    Octapole Moments (Debye-Ang^2)
       XXX      -7.8640    XXY     -10.1864    XYY       2.1936
       YYY       1.3650    XXZ     -10.3169    XYZ      -0.2885
       YYZ      -3.6779    XZZ      -5.1860    YZZ       0.9754
       ZZZ      -9.1238
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1141.2201   XXXY      -1.8837   XXYY    -239.0678
      XYYY       0.8126   YYYY    -216.1659   XXXZ     -10.2268
      XXYZ     -13.9052   XYYZ       5.9835   YYYZ     -13.7600
      XXZZ    -215.5561   XYZZ       0.1934   YYZZ     -50.5050
      XZZZ       9.0062   YZZZ     -10.9326   ZZZZ     -92.9461
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:28:06 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0009784  -0.0026127   0.0000347   0.0000320   0.0034623   0.0008962
    2   0.0014954   0.0020902  -0.0042580   0.0002052  -0.0043649   0.0003285
    3  -0.0003789  -0.0018545   0.0003498   0.0000423   0.0038747   0.0017970
            7           8           9          10          11          12
    1  -0.0016828   0.0010797   0.0031944  -0.0023045  -0.0003197  -0.0001705
    2   0.0006297   0.0028179   0.0000844  -0.0007954   0.0020063   0.0008515
    3  -0.0009859  -0.0027951  -0.0013681  -0.0024144   0.0005661   0.0014863
           13          14          15          16          17
    1   0.0001738  -0.0026572   0.0016619  -0.0002738   0.0004646
    2  -0.0009992   0.0002062   0.0000355  -0.0006524   0.0003191
    3  -0.0004257   0.0027869  -0.0003589  -0.0000137  -0.0003079
 Max gradient component =       4.365E-03
 RMS gradient           =       1.764E-03
 Gradient time:  CPU 12.69 s  wall 13.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:28:19 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  12

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.813110   -1.437304    0.845730
    2  C           3.120267   -0.671143    0.137294
    3  C           2.326475    0.358452   -0.142499
    4  H           4.102661   -0.785145   -0.312547
    5  C           0.948272    0.548636    0.432112
    6  H           2.674574    1.118575   -0.841979
    7  H           0.671913    1.609312    0.463360
    8  H           0.918089    0.188588    1.462135
    9  C          -0.123211   -0.173647   -0.411185
   10  C          -1.554221    0.094132    0.067453
   11  H           0.077323   -1.247449   -0.447418
   12  H          -0.067762    0.191978   -1.445976
   13  O          -1.885535    1.197871    0.457228
   14  C          -2.537666   -1.062706    0.036931
   15  H          -3.528568   -0.707199    0.316842
   16  H          -2.218725   -1.854823    0.727575
   17  H          -2.566878   -1.510934   -0.964911
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.857945726

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000005    0.001296    0.002494    0.005352    0.019446    0.026007
     0.037170    0.041010    0.041987    0.045302    0.046041    0.050062
     0.055792    0.063966    0.073788    0.078406    0.105363    0.119897
     0.121909    0.127631    0.129894    0.136739    0.146029    0.149839
     0.180333    0.188894    0.201318    0.207931    0.230419    0.260042
     0.268937    0.292553    0.300058    0.301503    0.301902    0.302492
     0.302547    0.304019    0.305157    0.308520    0.312018    0.323841
     0.352275    0.651545    0.830014
**WARNING** Magnitude of eigenvalue   1 too small.  Replaced by     0.000100

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00276847
 Calculated Step too Large.  Step scaled by  0.335367
 Step Taken.  Stepsize is  0.300000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.003655      0.000300      NO
         Displacement       0.133928      0.001200      NO
         Energy change      0.000166      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.579071
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       2.929116    -1.347271     0.951672
    2      C       3.170162    -0.633242     0.166914
    3      C       2.319978     0.334815    -0.168780
    4      H       4.138823    -0.743835    -0.312771
    5      C       0.952568     0.520194     0.432015
    6      H       2.607263     1.042360    -0.947740
    7      H       0.682471     1.581757     0.476408
    8      H       0.937640     0.148257     1.460169
    9      C      -0.135491    -0.190902    -0.398555
   10      C      -1.556161     0.091571     0.096813
   11      H       0.052058    -1.268143    -0.442012
   12      H      -0.090985     0.172450    -1.436076
   13      O      -1.862937     1.184093     0.535303
   14      C      -2.563503    -1.041298     0.009352
   15      H      -3.550423    -0.680058     0.299785
   16      H      -2.263463    -1.866990     0.667979
   17      H      -2.596998    -1.446564    -1.010330
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.3517338295 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:28:19 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000973 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:28:19 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    991 shell pairs
 There are   6972 function pairs
 Smallest overlap matrix eigenvalue = 3.33E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:28:19 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8455418275      2.34E-03
    2    -309.8585790919      2.53E-04
    3    -309.8586772289      2.60E-04
    4    -309.8588042518      7.51E-05
    5    -309.8588100226      4.63E-05
    6    -309.8588133625      8.24E-06
    7    -309.8588134568      4.18E-06
    8    -309.8588135036      1.08E-06
    9    -309.8588135255      2.98E-07
   10    -309.8588135329      7.69E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 33.74 s  wall 34.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:28:53 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.133038
      2 C                    -0.332807
      3 C                    -0.058425
      4 H                     0.140429
      5 C                    -0.301872
      6 H                     0.128691
      7 H                     0.169296
      8 H                     0.147921
      9 C                    -0.346982
     10 C                     0.456663
     11 H                     0.148555
     12 H                     0.168480
     13 O                    -0.439933
     14 C                    -0.531462
     15 H                     0.180019
     16 H                     0.171365
     17 H                     0.167025
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.4966      Y      -2.2015      Z      -1.0252
       Tot       2.4787
    Quadrupole Moments (Debye-Ang)
        XX     -44.3349     XY       4.6891     YY     -44.7276
        XZ       1.0881     YZ      -2.6662     ZZ     -42.6712
    Octapole Moments (Debye-Ang^2)
       XXX      -9.3900    XXY     -10.3452    XYY       1.1633
       YYY       1.8927    XXZ     -10.8456    XYZ      -0.2013
       YYZ      -4.2636    XZZ      -4.4142    YZZ       0.7996
       ZZZ     -10.5685
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1157.2895   XXXY      -5.5970   XXYY    -241.5412
      XYYY       0.3572   YYYY    -207.8959   XXXZ      -8.9108
      XXYZ     -15.7379   XYYZ       6.3078   YYYZ     -15.3669
      XXZZ    -217.6248   XYZZ       0.0602   YYZZ     -50.0443
      XZZZ       9.1104   YZZZ     -12.7018   ZZZZ     -97.0374
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:28:53 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0006245  -0.0017580   0.0001015  -0.0000303   0.0021760   0.0008820
    2   0.0010866   0.0006512  -0.0023598   0.0000560  -0.0031590   0.0006414
    3  -0.0001775  -0.0016483   0.0004358  -0.0000481   0.0029662   0.0013594
            7           8           9          10          11          12
    1  -0.0012111   0.0007235   0.0019665  -0.0014023  -0.0002370  -0.0000999
    2   0.0003437   0.0020421  -0.0001014  -0.0005563   0.0012463   0.0007577
    3  -0.0011350  -0.0016434  -0.0006492  -0.0013867   0.0001481   0.0009255
           13          14          15          16          17
    1  -0.0000099  -0.0015647   0.0010194  -0.0001845   0.0002533
    2  -0.0005145  -0.0001039   0.0000744  -0.0003817   0.0002772
    3  -0.0006115   0.0019435  -0.0002159  -0.0000408  -0.0002220
 Max gradient component =       3.159E-03
 RMS gradient           =       1.174E-03
 Gradient time:  CPU 12.22 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:29:06 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  13

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           2.929116   -1.347271    0.951672
    2  C           3.170162   -0.633242    0.166914
    3  C           2.319978    0.334815   -0.168780
    4  H           4.138823   -0.743835   -0.312771
    5  C           0.952568    0.520194    0.432015
    6  H           2.607263    1.042360   -0.947740
    7  H           0.682471    1.581757    0.476408
    8  H           0.937640    0.148257    1.460169
    9  C          -0.135491   -0.190902   -0.398555
   10  C          -1.556161    0.091571    0.096813
   11  H           0.052058   -1.268143   -0.442012
   12  H          -0.090985    0.172450   -1.436076
   13  O          -1.862937    1.184093    0.535303
   14  C          -2.563503   -1.041298    0.009352
   15  H          -3.550423   -0.680058    0.299785
   16  H          -2.263463   -1.866990    0.667979
   17  H          -2.596998   -1.446564   -1.010330
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.858813533

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000027    0.001279    0.002540    0.005351    0.019661    0.026616
     0.037146    0.040817    0.041866    0.044008    0.045948    0.047300
     0.051463    0.055828    0.071525    0.077924    0.096905    0.109086
     0.121204    0.123266    0.128273    0.135783    0.145439    0.149158
     0.177235    0.186859    0.201045    0.206990    0.230691    0.247428
     0.263238    0.292301    0.299801    0.301465    0.301881    0.302341
     0.302531    0.303093    0.304799    0.307484    0.309550    0.316423
     0.349811    0.623643    0.827862
**WARNING** Magnitude of eigenvalue   1 too small.  Replaced by     0.000100

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00206236
 Calculated Step too Large.  Step scaled by  0.355557
 Step Taken.  Stepsize is  0.300000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002254      0.000300      NO
         Displacement       0.128555      0.001200      NO
         Energy change     -0.000868      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.562657
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.031569    -1.243362     1.046330
    2      C       3.214723    -0.592177     0.193934
    3      C       2.312659     0.307827    -0.194362
    4      H       4.170997    -0.705151    -0.309544
    5      C       0.957763     0.492108     0.430426
    6      H       2.542312     0.954246    -1.043018
    7      H       0.694283     1.554783     0.490085
    8      H       0.957479     0.108497     1.455400
    9      C      -0.145685    -0.206694    -0.389429
   10      C      -1.557068     0.085750     0.124314
   11      H       0.032197    -1.285964    -0.439671
   12      H      -0.111806     0.158552    -1.427255
   13      O      -1.838879     1.161819     0.616988
   14      C      -2.587832    -1.020449    -0.016058
   15      H      -3.570112    -0.650345     0.280441
   16      H      -2.310005    -1.876751     0.612272
   17      H      -2.622480    -1.385494    -1.050706
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   282.1756731717 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:29:06 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000956 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:29:06 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    988 shell pairs
 There are   6963 function pairs
 Smallest overlap matrix eigenvalue = 3.28E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:29:06 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8475966751      2.41E-03
    2    -309.8592720243      2.40E-04
    3    -309.8593834486      2.29E-04
    4    -309.8594844026      6.35E-05
    5    -309.8594882175      4.51E-05
    6    -309.8594913722      8.96E-06
    7    -309.8594914792      4.42E-06
    8    -309.8594915283      1.06E-06
    9    -309.8594915495      2.86E-07
   10    -309.8594915649      7.30E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 33.56 s  wall 34.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:29:40 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.133626
      2 C                    -0.335017
      3 C                    -0.055008
      4 H                     0.139942
      5 C                    -0.300630
      6 H                     0.127267
      7 H                     0.169972
      8 H                     0.146596
      9 C                    -0.349989
     10 C                     0.457374
     11 H                     0.150166
     12 H                     0.167781
     13 O                    -0.439381
     14 C                    -0.531197
     15 H                     0.179948
     16 H                     0.171916
     17 H                     0.166636
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.4089      Y      -2.1795      Z      -1.1493
       Tot       2.4977
    Quadrupole Moments (Debye-Ang)
        XX     -44.1989     XY       4.4502     YY     -44.8478
        XZ       1.3758     YZ      -2.8500     ZZ     -42.6586
    Octapole Moments (Debye-Ang^2)
       XXX     -10.7760    XXY     -10.2789    XYY      -0.0177
       YYY       2.6158    XXZ     -11.2011    XYZ       0.0281
       YYZ      -4.8216    XZZ      -3.5703    YZZ       0.6654
       ZZZ     -11.9955
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1170.6182   XXXY      -9.6226   XXYY    -243.6514
      XYYY      -0.6157   YYYY    -198.7640   XXXZ      -6.8706
      XXYZ     -17.2085   XYYZ       6.4708   YYYZ     -16.9015
      XXZZ    -219.6010   XYZZ      -0.2297   YYZZ     -49.7439
      XZZZ       9.4943   YZZZ     -14.6661   ZZZZ    -101.8194
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:29:40 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0004718  -0.0013013  -0.0001909  -0.0001011   0.0019726   0.0006457
    2   0.0009186   0.0000166  -0.0014369  -0.0000683  -0.0024634   0.0007767
    3  -0.0000355  -0.0013949   0.0005200  -0.0001490   0.0023347   0.0011196
            7           8           9          10          11          12
    1  -0.0009647   0.0005443   0.0013259  -0.0011428   0.0000519  -0.0000511
    2   0.0002223   0.0015378  -0.0005538  -0.0001902   0.0009285   0.0007820
    3  -0.0010141  -0.0011200  -0.0007844  -0.0013106   0.0001471   0.0008061
           13          14          15          16          17
    1  -0.0000476  -0.0010318   0.0007452  -0.0001155   0.0001328
    2  -0.0002134  -0.0004028   0.0001545  -0.0002977   0.0002894
    3  -0.0004293   0.0019406  -0.0003122  -0.0001376  -0.0001805
 Max gradient component =       2.463E-03
 RMS gradient           =       9.369E-04
 Gradient time:  CPU 12.16 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:29:52 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  14

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.031569   -1.243362    1.046330
    2  C           3.214723   -0.592177    0.193934
    3  C           2.312659    0.307827   -0.194362
    4  H           4.170997   -0.705151   -0.309544
    5  C           0.957763    0.492108    0.430426
    6  H           2.542312    0.954246   -1.043018
    7  H           0.694283    1.554783    0.490085
    8  H           0.957479    0.108497    1.455400
    9  C          -0.145685   -0.206694   -0.389429
   10  C          -1.557068    0.085750    0.124314
   11  H           0.032197   -1.285964   -0.439671
   12  H          -0.111806    0.158552   -1.427255
   13  O          -1.838879    1.161819    0.616988
   14  C          -2.587832   -1.020449   -0.016058
   15  H          -3.570112   -0.650345    0.280441
   16  H          -2.310005   -1.876751    0.612272
   17  H          -2.622480   -1.385494   -1.050706
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.859491565

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000201    0.001212    0.002063    0.005316    0.013825    0.019718
     0.026736    0.037836    0.041274    0.042086    0.045799    0.046108
     0.050576    0.055821    0.070557    0.077803    0.093695    0.108235
     0.121740    0.123178    0.128239    0.135800    0.145342    0.149033
     0.178031    0.186900    0.200960    0.206482    0.231405    0.239278
     0.262777    0.292451    0.299470    0.301482    0.301853    0.302324
     0.302560    0.302784    0.304930    0.307395    0.309486    0.315763
     0.349847    0.616242    0.827970

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00202517
 Calculated Step too Large.  Step scaled by  0.532984
 Step Taken.  Stepsize is  0.300000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002145      0.000300      NO
         Displacement       0.107468      0.001200      NO
         Energy change     -0.000678      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.620487
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.165017    -1.196747     1.095486
    2      C       3.277250    -0.546372     0.226667
    3      C       2.319062     0.288008    -0.199410
    4      H       4.234667    -0.607075    -0.285351
    5      C       0.943091     0.459739     0.400771
    6      H       2.516365     0.902360    -1.081770
    7      H       0.700475     1.524243     0.461030
    8      H       0.930236     0.073560     1.437039
    9      C      -0.175341    -0.249033    -0.386245
   10      C      -1.554291     0.088604     0.164874
   11      H      -0.025449    -1.339442    -0.418411
   12      H      -0.162881     0.073626    -1.442691
   13      O      -1.789964     1.149028     0.713311
   14      C      -2.612732    -0.977342    -0.042623
   15      H      -3.599374    -0.624084     0.277764
   16      H      -2.339387    -1.860662     0.548979
   17      H      -2.656627    -1.301217    -1.089273
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.6920794598 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:29:52 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000943 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:29:52 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    989 shell pairs
 There are   6969 function pairs
 Smallest overlap matrix eigenvalue = 3.30E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:29:52 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8378037520      2.73E-03
    2    -309.8590030034      3.27E-04
    3    -309.8589541007      4.50E-04
    4    -309.8592859839      1.26E-04
    5    -309.8593079225      3.94E-05
    6    -309.8593105861      8.41E-06
    7    -309.8593107089      4.07E-06
    8    -309.8593107421      1.30E-06
    9    -309.8593107696      4.25E-07
   10    -309.8593107631      8.69E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 33.44 s  wall 34.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:30:27 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.135449
      2 C                    -0.335906
      3 C                    -0.057974
      4 H                     0.139109
      5 C                    -0.298831
      6 H                     0.125958
      7 H                     0.172278
      8 H                     0.144136
      9 C                    -0.352876
     10 C                     0.462211
     11 H                     0.152355
     12 H                     0.167344
     13 O                    -0.439827
     14 C                    -0.531311
     15 H                     0.178136
     16 H                     0.171636
     17 H                     0.168112
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.2559      Y      -2.1807      Z      -1.2911
       Tot       2.5471
    Quadrupole Moments (Debye-Ang)
        XX     -43.9079     XY       4.2439     YY     -44.8837
        XZ       1.6932     YZ      -3.0353     ZZ     -42.8720
    Octapole Moments (Debye-Ang^2)
       XXX     -12.3102    XXY      -9.8397    XYY      -0.9833
       YYY       2.9815    XXZ     -11.3221    XYZ       0.0019
       YYZ      -5.5100    XZZ      -3.3316    YZZ       0.2700
       ZZZ     -13.9488
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1184.4100   XXXY     -11.8069   XXYY    -246.0747
      XYYY      -1.8656   YYYY    -189.5554   XXXZ      -4.4086
      XXYZ     -19.3445   XYYZ       6.9849   YYYZ     -18.9287
      XXZZ    -223.6567   XYZZ      -0.3367   YYZZ     -49.6822
      XZZZ       9.5929   YZZZ     -16.9136   ZZZZ    -106.6133
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:30:27 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0021519   0.0033169  -0.0001504   0.0001616  -0.0060388  -0.0005570
    2  -0.0022470  -0.0038039   0.0048640  -0.0001220   0.0056962   0.0012542
    3   0.0009477   0.0015655  -0.0007189  -0.0000475  -0.0063903  -0.0001574
            7           8           9          10          11          12
    1   0.0017363  -0.0008997  -0.0049547   0.0036545  -0.0002849   0.0004197
    2  -0.0008536  -0.0022848  -0.0017638  -0.0000645  -0.0029613  -0.0001340
    3  -0.0005247   0.0046079   0.0025073   0.0042078  -0.0017573  -0.0016287
           13          14          15          16          17
    1  -0.0002915   0.0043109  -0.0025560   0.0008135  -0.0008321
    2   0.0021365   0.0001141  -0.0002518   0.0009186  -0.0004971
    3  -0.0005191  -0.0033972   0.0007288   0.0001132   0.0004629
 Max gradient component =       6.390E-03
 RMS gradient           =       2.545E-03
 Gradient time:  CPU 11.97 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:30:39 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  15

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.165017   -1.196747    1.095486
    2  C           3.277250   -0.546372    0.226667
    3  C           2.319062    0.288008   -0.199410
    4  H           4.234667   -0.607075   -0.285351
    5  C           0.943091    0.459739    0.400771
    6  H           2.516365    0.902360   -1.081770
    7  H           0.700475    1.524243    0.461030
    8  H           0.930236    0.073560    1.437039
    9  C          -0.175341   -0.249033   -0.386245
   10  C          -1.554291    0.088604    0.164874
   11  H          -0.025449   -1.339442   -0.418411
   12  H          -0.162881    0.073626   -1.442691
   13  O          -1.789964    1.149028    0.713311
   14  C          -2.612732   -0.977342   -0.042623
   15  H          -3.599374   -0.624084    0.277764
   16  H          -2.339387   -1.860662    0.548979
   17  H          -2.656627   -1.301217   -1.089273
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.859310763

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000116    0.001285    0.002443    0.005394    0.019694    0.026733
     0.037658    0.041155    0.042005    0.045449    0.045986    0.050104
     0.055733    0.062798    0.074942    0.078404    0.104878    0.118930
     0.122350    0.127482    0.130536    0.137770    0.148031    0.149930
     0.182489    0.189439    0.201036    0.207784    0.231353    0.260917
     0.279880    0.292543    0.300247    0.301503    0.301904    0.302462
     0.302570    0.304232    0.305194    0.308658    0.311628    0.323967
     0.349810    0.659928    0.830362

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00265918
 Calculated Step too Large.  Step scaled by  0.438896
 Step Taken.  Stepsize is  0.300000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.007383      0.000300      NO
         Displacement       0.131781      0.001200      NO
         Energy change      0.000181      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.578491
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.239872    -1.054891     1.176725
    2      C       3.308940    -0.501766     0.240124
    3      C       2.309912     0.254941    -0.226518
    4      H       4.250116    -0.588865    -0.297031
    5      C       0.957272     0.433252     0.413014
    6      H       2.451174     0.785592    -1.171526
    7      H       0.714599     1.498805     0.485418
    8      H       0.969252     0.040989     1.442409
    9      C      -0.175307    -0.258001    -0.367818
   10      C      -1.556253     0.072964     0.188575
   11      H      -0.030734    -1.346737    -0.412072
   12      H      -0.169379     0.077910    -1.419307
   13      O      -1.779159     1.110534     0.783693
   14      C      -2.636100    -0.961552    -0.068958
   15      H      -3.613634    -0.589865     0.252537
   16      H      -2.396574    -1.875535     0.489914
   17      H      -2.673881    -1.240582    -1.129032
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.6255765931 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:30:39 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000922 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:30:39 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    986 shell pairs
 There are   6963 function pairs
 Smallest overlap matrix eigenvalue = 3.23E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:30:39 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8530894179      2.27E-03
    2    -309.8600421876      2.12E-04
    3    -309.8601693271      1.79E-04
    4    -309.8602292367      5.47E-05
    5    -309.8602330577      3.60E-05
    6    -309.8602356040      7.91E-06
    7    -309.8602356842      4.07E-06
    8    -309.8602357208      1.01E-06
    9    -309.8602357231      2.60E-07
   10    -309.8602357337      7.49E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 33.02 s  wall 33.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:31:13 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.135481
      2 C                    -0.338295
      3 C                    -0.052743
      4 H                     0.138915
      5 C                    -0.297809
      6 H                     0.124418
      7 H                     0.172131
      8 H                     0.144636
      9 C                    -0.355513
     10 C                     0.460440
     11 H                     0.153468
     12 H                     0.166415
     13 O                    -0.438848
     14 C                    -0.530753
     15 H                     0.178954
     16 H                     0.172007
     17 H                     0.167093
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.2122      Y      -2.1343      Z      -1.3831
       Tot       2.5521
    Quadrupole Moments (Debye-Ang)
        XX     -43.7949     XY       4.0416     YY     -44.9887
        XZ       1.9648     YZ      -3.0715     ZZ     -42.8385
    Octapole Moments (Debye-Ang^2)
       XXX     -13.1114    XXY      -9.5481    XYY      -2.3266
       YYY       4.1137    XXZ     -11.4901    XYZ       0.4764
       YYZ      -5.9525    XZZ      -2.2500    YZZ       0.3167
       ZZZ     -15.2056
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1195.9576   XXXY     -15.9717   XXYY    -248.1463
      XYYY      -3.5321   YYYY    -179.6037   XXXZ      -2.2098
      XXYZ     -19.6858   XYYZ       6.5871   YYYZ     -20.1564
      XXZZ    -224.9541   XYZZ      -0.9198   YYZZ     -49.5677
      XZZZ      10.4535   YZZZ     -18.9313   ZZZZ    -111.9426
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:31:13 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0014115   0.0019231  -0.0001275   0.0000169  -0.0030927  -0.0003456
    2  -0.0008643  -0.0024841   0.0030395  -0.0001996   0.0027449   0.0008184
    3   0.0008381   0.0007600  -0.0001333  -0.0001976  -0.0030985  -0.0001606
            7           8           9          10          11          12
    1   0.0007613  -0.0003664  -0.0026544   0.0019072  -0.0003407   0.0001880
    2  -0.0005148  -0.0013149  -0.0011203  -0.0003278  -0.0014626   0.0001262
    3  -0.0006617   0.0024943   0.0013588   0.0024462  -0.0011762  -0.0009491
           13          14          15          16          17
    1  -0.0002434   0.0023913  -0.0014716   0.0005173  -0.0004744
    2   0.0014018  -0.0000112  -0.0001465   0.0005468  -0.0002315
    3  -0.0004667  -0.0017226   0.0003979   0.0000751   0.0001959
 Max gradient component =       3.098E-03
 RMS gradient           =       1.392E-03
 Gradient time:  CPU 12.43 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:31:25 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  16

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.239872   -1.054891    1.176725
    2  C           3.308940   -0.501766    0.240124
    3  C           2.309912    0.254941   -0.226518
    4  H           4.250116   -0.588865   -0.297031
    5  C           0.957272    0.433252    0.413014
    6  H           2.451174    0.785592   -1.171526
    7  H           0.714599    1.498805    0.485418
    8  H           0.969252    0.040989    1.442409
    9  C          -0.175307   -0.258001   -0.367818
   10  C          -1.556253    0.072964    0.188575
   11  H          -0.030734   -1.346737   -0.412072
   12  H          -0.169379    0.077910   -1.419307
   13  O          -1.779159    1.110534    0.783693
   14  C          -2.636100   -0.961552   -0.068958
   15  H          -3.613634   -0.589865    0.252537
   16  H          -2.396574   -1.875535    0.489914
   17  H          -2.673881   -1.240582   -1.129032
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.860235734

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000314    0.001264    0.002431    0.005399    0.019693    0.026718
     0.037806    0.041214    0.041974    0.045639    0.046038    0.050400
     0.055797    0.061808    0.072005    0.078826    0.102875    0.112916
     0.121884    0.123548    0.128334    0.135693    0.145287    0.149391
     0.178756    0.188212    0.201116    0.207413    0.231370    0.256329
     0.263830    0.293067    0.300168    0.301509    0.301899    0.302463
     0.302581    0.303246    0.305319    0.307978    0.310047    0.316922
     0.349823    0.630189    0.828519

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00095859
 Calculated Step too Large.  Step scaled by  0.670948
 Step Taken.  Stepsize is  0.300000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.004248      0.000300      NO
         Displacement       0.133532      0.001200      NO
         Energy change     -0.000925      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.596376
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.307435    -0.918567     1.228382
    2      C       3.340520    -0.452204     0.244764
    3      C       2.303026     0.225348    -0.252322
    4      H       4.272071    -0.552584    -0.306047
    5      C       0.969297     0.407828     0.418305
    6      H       2.398918     0.684047    -1.239333
    7      H       0.723685     1.474458     0.489154
    8      H       1.006448     0.024158     1.446743
    9      C      -0.175388    -0.283460    -0.343627
   10      C      -1.554611     0.047748     0.221681
   11      H      -0.031137    -1.371331    -0.378042
   12      H      -0.179529     0.048011    -1.395271
   13      O      -1.754105     1.048838     0.883837
   14      C      -2.663712    -0.937824    -0.100488
   15      H      -3.631345    -0.532096     0.204585
   16      H      -2.479867    -1.881401     0.429514
   17      H      -2.681588    -1.173774    -1.171688
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.5940419622 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:31:26 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000895 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:31:26 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    985 shell pairs
 There are   6965 function pairs
 Smallest overlap matrix eigenvalue = 3.15E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:31:26 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8507991245      2.68E-03
    2    -309.8604974810      2.33E-04
    3    -309.8606426250      1.86E-04
    4    -309.8607075075      4.39E-05
    5    -309.8607093208      3.51E-05
    6    -309.8607115378      1.01E-05
    7    -309.8607117045      3.65E-06
    8    -309.8607117300      1.11E-06
    9    -309.8607117375      3.55E-07
   10    -309.8607117475      8.90E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 34.13 s  wall 34.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:32:00 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.135376
      2 C                    -0.340351
      3 C                    -0.049118
      4 H                     0.138695
      5 C                    -0.296650
      6 H                     0.123078
      7 H                     0.171366
      8 H                     0.145852
      9 C                    -0.358383
     10 C                     0.458656
     11 H                     0.155571
     12 H                     0.165184
     13 O                    -0.437546
     14 C                    -0.529871
     15 H                     0.179700
     16 H                     0.173146
     17 H                     0.165295
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.1402      Y      -2.0606      Z      -1.5046
       Tot       2.5553
    Quadrupole Moments (Debye-Ang)
        XX     -43.5780     XY       3.7980     YY     -44.9181
        XZ       2.2921     YZ      -3.1132     ZZ     -43.0125
    Octapole Moments (Debye-Ang^2)
       XXX     -14.1369    XXY      -8.5871    XYY      -3.8720
       YYY       5.6921    XXZ     -11.7817    XYZ       1.0361
       YYZ      -6.4464    XZZ      -1.2012    YZZ       0.4419
       ZZZ     -16.9766
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1205.5269   XXXY     -20.9802   XXYY    -249.1791
      XYYY      -6.8995   YYYY    -167.7539   XXXZ       1.2840
      XXYZ     -20.0043   XYYZ       6.2969   YYYZ     -21.8592
      XXZZ    -227.5451   XYZZ      -1.7133   YYZZ     -49.6274
      XZZZ      12.5891   YZZZ     -21.3880   ZZZZ    -118.7880
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:32:00 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0006052   0.0009426  -0.0003238  -0.0000955  -0.0007278  -0.0000912
    2   0.0001899  -0.0015289   0.0014966  -0.0001945   0.0002978   0.0006008
    3   0.0005696  -0.0000257   0.0002895  -0.0001857  -0.0004824   0.0000712
            7           8           9          10          11          12
    1   0.0000372   0.0000737  -0.0013925   0.0002493   0.0000890   0.0000928
    2  -0.0000755  -0.0005378  -0.0013719   0.0001100  -0.0003548   0.0006388
    3  -0.0007509   0.0008623  -0.0004525   0.0002582  -0.0001923  -0.0000722
           13          14          15          16          17
    1  -0.0000380   0.0010097  -0.0005398   0.0003817  -0.0002727
    2   0.0009176  -0.0006865   0.0002342   0.0001347   0.0001293
    3   0.0000552   0.0004859  -0.0002974  -0.0001450   0.0000122
 Max gradient component =       1.529E-03
 RMS gradient           =       5.831E-04
 Gradient time:  CPU 12.66 s  wall 13.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:32:13 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  17

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.307435   -0.918567    1.228382
    2  C           3.340520   -0.452204    0.244764
    3  C           2.303026    0.225348   -0.252322
    4  H           4.272071   -0.552584   -0.306047
    5  C           0.969297    0.407828    0.418305
    6  H           2.398918    0.684047   -1.239333
    7  H           0.723685    1.474458    0.489154
    8  H           1.006448    0.024158    1.446743
    9  C          -0.175388   -0.283460   -0.343627
   10  C          -1.554611    0.047748    0.221681
   11  H          -0.031137   -1.371331   -0.378042
   12  H          -0.179529    0.048011   -1.395271
   13  O          -1.754105    1.048838    0.883837
   14  C          -2.663712   -0.937824   -0.100488
   15  H          -3.631345   -0.532096    0.204585
   16  H          -2.479867   -1.881401    0.429514
   17  H          -2.681588   -1.173774   -1.171688
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.860711748

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000282    0.001284    0.002324    0.005404    0.019673    0.027097
     0.037992    0.041149    0.042113    0.045609    0.046080    0.050409
     0.055501    0.067607    0.076980    0.081919    0.101487    0.108438
     0.121368    0.123963    0.128216    0.135303    0.144202    0.149863
     0.175428    0.187784    0.201784    0.207850    0.231560    0.252430
     0.262432    0.293116    0.300241    0.301511    0.301906    0.302500
     0.302579    0.303523    0.305703    0.308011    0.310182    0.317162
     0.350705    0.622635    0.827279

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00052367
 Calculated Step too Large.  Step scaled by  0.447841
 Step Taken.  Stepsize is  0.300000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.001713      0.000300      NO
         Displacement       0.137568      0.001200      NO
         Energy change     -0.000476      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.606886
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.392648    -0.776130     1.275309
    2      C       3.378652    -0.394920     0.255259
    3      C       2.298479     0.189774    -0.268695
    4      H       4.300229    -0.499374    -0.311467
    5      C       0.974876     0.375540     0.419752
    6      H       2.348983     0.564543    -1.294106
    7      H       0.735135     1.443711     0.493493
    8      H       1.025731    -0.005768     1.448626
    9      C      -0.182077    -0.311629    -0.323632
   10      C      -1.553199     0.028025     0.253785
   11      H      -0.049111    -1.401685    -0.354654
   12      H      -0.197658     0.009191    -1.378915
   13      O      -1.730180     0.995895     0.969415
   14      C      -2.687310    -0.905467    -0.131391
   15      H      -3.646765    -0.485024     0.180325
   16      H      -2.541986    -1.876803     0.359089
   17      H      -2.696330    -1.092684    -1.212046
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.4581809291 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:32:14 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000870 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:32:14 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    985 shell pairs
 There are   6962 function pairs
 Smallest overlap matrix eigenvalue = 3.10E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:32:14 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8488286622      2.59E-03
    2    -309.8606368402      2.39E-04
    3    -309.8607641292      2.14E-04
    4    -309.8608507762      6.05E-05
    5    -309.8608541109      4.52E-05
    6    -309.8608571795      9.87E-06
    7    -309.8608573302      3.57E-06
    8    -309.8608573690      1.15E-06
    9    -309.8608573842      3.66E-07
   10    -309.8608573937      8.19E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 34.43 s  wall 34.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:32:49 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.135816
      2 C                    -0.341998
      3 C                    -0.047228
      4 H                     0.138418
      5 C                    -0.295343
      6 H                     0.121721
      7 H                     0.171675
      8 H                     0.146702
      9 C                    -0.360717
     10 C                     0.458232
     11 H                     0.157326
     12 H                     0.163988
     13 O                    -0.436967
     14 C                    -0.529509
     15 H                     0.179856
     16 H                     0.173222
     17 H                     0.164805
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0730      Y      -2.0029      Z      -1.6088
       Tot       2.5700
    Quadrupole Moments (Debye-Ang)
        XX     -43.3801     XY       3.6051     YY     -44.8957
        XZ       2.5897     YZ      -3.0482     ZZ     -43.1804
    Octapole Moments (Debye-Ang^2)
       XXX     -14.8856    XXY      -7.7004    XYY      -5.2327
       YYY       7.0019    XXZ     -11.8122    XYZ       1.5279
       YYZ      -6.8974    XZZ      -0.3388    YZZ       0.5143
       ZZZ     -18.7389
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1216.0408   XXXY     -24.2414   XXYY    -250.8372
      XYYY      -9.6910   YYYY    -156.2888   XXXZ       3.9302
      XXYZ     -19.8337   XYYZ       5.7925   YYYZ     -23.1780
      XXZZ    -230.2146   XYZZ      -2.3954   YYZZ     -49.6689
      XZZZ      13.7034   YZZZ     -23.4833   ZZZZ    -125.6147
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:32:49 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0008340   0.0012221  -0.0007283  -0.0000908  -0.0007896  -0.0003618
    2   0.0003489  -0.0014854   0.0018369  -0.0002781   0.0004608   0.0003311
    3   0.0006024   0.0002976   0.0004472  -0.0002059  -0.0009143  -0.0001832
            7           8           9          10          11          12
    1   0.0001850  -0.0000061  -0.0013117   0.0005893  -0.0000807   0.0000366
    2  -0.0001403  -0.0008783  -0.0010192  -0.0001547  -0.0004541   0.0004268
    3  -0.0006048   0.0009054  -0.0000682   0.0007785  -0.0003819  -0.0003435
           13          14          15          16          17
    1  -0.0001491   0.0011972  -0.0006688   0.0003657  -0.0002432
    2   0.0009487  -0.0003716   0.0001540   0.0002069   0.0000675
    3  -0.0000193  -0.0002262  -0.0001186   0.0000082   0.0000267
 Max gradient component =       1.837E-03
 RMS gradient           =       6.391E-04
 Gradient time:  CPU 12.25 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:33:01 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  18

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.392648   -0.776130    1.275309
    2  C           3.378652   -0.394920    0.255259
    3  C           2.298479    0.189774   -0.268695
    4  H           4.300229   -0.499374   -0.311467
    5  C           0.974876    0.375540    0.419752
    6  H           2.348983    0.564543   -1.294106
    7  H           0.735135    1.443711    0.493493
    8  H           1.025731   -0.005768    1.448626
    9  C          -0.182077   -0.311629   -0.323632
   10  C          -1.553199    0.028025    0.253785
   11  H          -0.049111   -1.401685   -0.354654
   12  H          -0.197658    0.009191   -1.378915
   13  O          -1.730180    0.995895    0.969415
   14  C          -2.687310   -0.905467   -0.131391
   15  H          -3.646765   -0.485024    0.180325
   16  H          -2.541986   -1.876803    0.359089
   17  H          -2.696330   -1.092684   -1.212046
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.860857394

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000840    0.002015    0.002351    0.005396    0.019502    0.027859
     0.038112    0.040955    0.041903    0.045475    0.046137    0.050799
     0.053948    0.066600    0.076768    0.079410    0.085248    0.106146
     0.121059    0.123620    0.128095    0.134708    0.143460    0.149869
     0.171632    0.187779    0.201561    0.207854    0.230358    0.244741
     0.262160    0.293130    0.300220    0.301521    0.301907    0.302490
     0.302591    0.303412    0.305702    0.307779    0.309968    0.316536
     0.351405    0.610386    0.825559

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00052067
 Calculated Step too Large.  Step scaled by  0.663322
 Step Taken.  Stepsize is  0.300000

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002213      0.000300      NO
         Displacement       0.148193      0.001200      NO
         Energy change     -0.000146      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.544330
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.404305    -0.708651     1.271454
    2      C       3.386210    -0.370407     0.237830
    3      C       2.296291     0.183318    -0.290243
    4      H       4.305929    -0.484418    -0.329609
    5      C       0.988699     0.377650     0.424168
    6      H       2.333517     0.532421    -1.324245
    7      H       0.729503     1.444750     0.463627
    8      H       1.070966     0.043702     1.461369
    9      C      -0.171096    -0.344372    -0.277403
   10      C      -1.550249    -0.012338     0.291113
   11      H      -0.028595    -1.431837    -0.263966
   12      H      -0.198657    -0.066768    -1.342607
   13      O      -1.720095     0.909778     1.066144
   14      C      -2.707958    -0.884465    -0.168464
   15      H      -3.651332    -0.426853     0.132246
   16      H      -2.631118    -1.881520     0.285018
   17      H      -2.686201    -1.022797    -1.256286
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.4314928474 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:33:01 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000844 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:33:01 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    983 shell pairs
 There are   6954 function pairs
 Smallest overlap matrix eigenvalue = 3.05E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:33:01 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8552204999      2.25E-03
    2    -309.8607611404      2.16E-04
    3    -309.8608411363      2.00E-04
    4    -309.8609158973      4.07E-05
    5    -309.8609166402      3.77E-05
    6    -309.8609187555      8.17E-06
    7    -309.8609188769      1.53E-06
    8    -309.8609188912      6.59E-07
    9    -309.8609189020      3.45E-07
   10    -309.8609189174      7.44E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 33.46 s  wall 34.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:33:35 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.135539
      2 C                    -0.341904
      3 C                    -0.046024
      4 H                     0.138453
      5 C                    -0.295048
      6 H                     0.121837
      7 H                     0.168356
      8 H                     0.149695
      9 C                    -0.360476
     10 C                     0.454796
     11 H                     0.159685
     12 H                     0.161540
     13 O                    -0.435608
     14 C                    -0.528682
     15 H                     0.181160
     16 H                     0.173739
     17 H                     0.162942
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0662      Y      -1.9070      Z      -1.7115
       Tot       2.5633
    Quadrupole Moments (Debye-Ang)
        XX     -43.1952     XY       3.3971     YY     -44.6107
        XZ       2.8361     YZ      -3.0293     ZZ     -43.5242
    Octapole Moments (Debye-Ang^2)
       XXX     -15.2254    XXY      -6.6194    XYY      -6.3122
       YYY       8.8370    XXZ     -12.4175    XYZ       1.8437
       YYZ      -7.1730    XZZ       0.5367    YZZ       0.8800
       ZZZ     -20.6898
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1220.6411   XXXY     -28.6802   XXYY    -249.6897
      XYYY     -14.0413   YYYY    -147.7108   XXXZ       7.0419
      XXYZ     -19.7579   XYYZ       5.9080   YYYZ     -24.0598
      XXZZ    -233.1003   XYZZ      -3.3152   YYZZ     -49.9786
      XZZZ      17.3928   YZZZ     -24.8801   ZZZZ    -132.5223
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:33:35 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0002348  -0.0015261   0.0006605  -0.0001032   0.0020930   0.0006857
    2   0.0013355  -0.0002646  -0.0007960  -0.0000847  -0.0032643   0.0004608
    3  -0.0001473  -0.0013103   0.0009600  -0.0001450   0.0028823   0.0004233
            7           8           9          10          11          12
    1  -0.0010671   0.0003790   0.0017033  -0.0011313  -0.0003364  -0.0002859
    2   0.0001581   0.0011398   0.0001427  -0.0006043   0.0012179   0.0006180
    3  -0.0005795  -0.0019305  -0.0006231  -0.0012936   0.0004083   0.0007658
           13          14          15          16          17
    1  -0.0002802  -0.0015495   0.0008237  -0.0002718   0.0004411
    2  -0.0000607  -0.0002290   0.0000134  -0.0002454   0.0004629
    3  -0.0002622   0.0011410  -0.0001814   0.0000273  -0.0001349
 Max gradient component =       3.264E-03
 RMS gradient           =       1.024E-03
 Gradient time:  CPU 12.37 s  wall 13.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:33:48 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  19

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.404305   -0.708651    1.271454
    2  C           3.386210   -0.370407    0.237830
    3  C           2.296291    0.183318   -0.290243
    4  H           4.305929   -0.484418   -0.329609
    5  C           0.988699    0.377650    0.424168
    6  H           2.333517    0.532421   -1.324245
    7  H           0.729503    1.444750    0.463627
    8  H           1.070966    0.043702    1.461369
    9  C          -0.171096   -0.344372   -0.277403
   10  C          -1.550249   -0.012338    0.291113
   11  H          -0.028595   -1.431837   -0.263966
   12  H          -0.198657   -0.066768   -1.342607
   13  O          -1.720095    0.909778    1.066144
   14  C          -2.707958   -0.884465   -0.168464
   15  H          -3.651332   -0.426853    0.132246
   16  H          -2.631118   -1.881520    0.285018
   17  H          -2.686201   -1.022797   -1.256286
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.860918917

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.001157    0.002299    0.002679    0.005379    0.019737    0.027537
     0.038366    0.040564    0.042099    0.045762    0.046214    0.049830
     0.054340    0.063099    0.077694    0.078975    0.105927    0.119797
     0.122060    0.123455    0.128352    0.137267    0.143325    0.153717
     0.172163    0.191207    0.202912    0.208539    0.232481    0.255060
     0.262740    0.294308    0.300345    0.301527    0.301912    0.302487
     0.302593    0.304052    0.305993    0.308622    0.312577    0.325524
     0.366916    0.640573    0.825829

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00019395
 Step Taken.  Stepsize is  0.103791

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.002790      0.000300      NO
         Displacement       0.038662      0.001200      NO
         Energy change     -0.000062      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.161012
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.393892    -0.710448     1.285382
    2      C       3.386221    -0.366316     0.252718
    3      C       2.298447     0.180388    -0.291246
    4      H       4.311516    -0.480124    -0.305532
    5      C       0.983118     0.378688     0.409572
    6      H       2.340307     0.519590    -1.328613
    7      H       0.736692     1.447638     0.460219
    8      H       1.052609     0.031637     1.447088
    9      C      -0.176523    -0.336111    -0.301134
   10      C      -1.546063    -0.009430     0.289435
   11      H      -0.029183    -1.424525    -0.301561
   12      H      -0.207821    -0.045797    -1.363086
   13      O      -1.703775     0.899301     1.082682
   14      C      -2.705225    -0.885294    -0.158201
   15      H      -3.649876    -0.427701     0.142143
   16      H      -2.621601    -1.877349     0.304510
   17      H      -2.692617    -1.036953    -1.244228
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.4974283656 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:33:48 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000836 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:33:48 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    984 shell pairs
 There are   6958 function pairs
 Smallest overlap matrix eigenvalue = 3.06E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:33:48 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8579789550      7.62E-04
    2    -309.8610068613      6.57E-05
    3    -309.8610112256      7.47E-05
    4    -309.8610206254      2.40E-05
    5    -309.8610213930      1.11E-05
    6    -309.8610215963      3.03E-06
    7    -309.8610216124      1.70E-06
    8    -309.8610216181      2.14E-07
    9    -309.8610216095      8.24E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 30.33 s  wall 31.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:34:19 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.135735
      2 C                    -0.342038
      3 C                    -0.046383
      4 H                     0.138387
      5 C                    -0.295039
      6 H                     0.121633
      7 H                     0.168885
      8 H                     0.149044
      9 C                    -0.361503
     10 C                     0.456046
     11 H                     0.160089
     12 H                     0.161766
     13 O                    -0.435522
     14 C                    -0.528896
     15 H                     0.180699
     16 H                     0.174552
     17 H                     0.162547
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0326      Y      -1.8953      Z      -1.7428
       Tot       2.5749
    Quadrupole Moments (Debye-Ang)
        XX     -43.1586     XY       3.3115     YY     -44.5392
        XZ       2.8443     YZ      -3.0366     ZZ     -43.6140
    Octapole Moments (Debye-Ang^2)
       XXX     -15.7173    XXY      -6.4725    XYY      -6.5055
       YYY       8.8741    XXZ     -12.3806    XYZ       1.7944
       YYZ      -7.1541    XZZ       0.5179    YZZ       0.7917
       ZZZ     -20.8832
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1217.5972   XXXY     -29.7660   XXYY    -248.8706
      XYYY     -14.7701   YYYY    -146.6235   XXXZ       7.2409
      XXYZ     -19.6712   XYYZ       5.8963   YYYZ     -23.7298
      XXZZ    -233.2839   XYZZ      -3.5065   YYZZ     -50.0132
      XZZZ      17.5178   YZZZ     -24.8295   ZZZZ    -134.3248
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:34:19 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0001206   0.0001608   0.0001191  -0.0001406   0.0003740  -0.0000214
    2   0.0004067  -0.0002001   0.0000677  -0.0000459  -0.0007196   0.0001624
    3   0.0002026  -0.0002922   0.0000588  -0.0000762   0.0005186   0.0001312
            7           8           9          10          11          12
    1  -0.0002758   0.0002390  -0.0002041  -0.0004958   0.0001964   0.0001106
    2   0.0000950   0.0000534  -0.0009428   0.0009341   0.0002354   0.0004680
    3  -0.0001249  -0.0000490  -0.0009210  -0.0012108   0.0002189   0.0004975
           13          14          15          16          17
    1   0.0000534  -0.0002156   0.0002772  -0.0000633   0.0000067
    2  -0.0000287  -0.0009168   0.0003893  -0.0001753   0.0002173
    3   0.0003917   0.0013380  -0.0003927  -0.0002522  -0.0000383
 Max gradient component =       1.338E-03
 RMS gradient           =       4.407E-04
 Gradient time:  CPU 11.67 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:34:31 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  20

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.393892   -0.710448    1.285382
    2  C           3.386221   -0.366316    0.252718
    3  C           2.298447    0.180388   -0.291246
    4  H           4.311516   -0.480124   -0.305532
    5  C           0.983118    0.378688    0.409572
    6  H           2.340307    0.519590   -1.328613
    7  H           0.736692    1.447638    0.460219
    8  H           1.052609    0.031637    1.447088
    9  C          -0.176523   -0.336111   -0.301134
   10  C          -1.546063   -0.009430    0.289435
   11  H          -0.029183   -1.424525   -0.301561
   12  H          -0.207821   -0.045797   -1.363086
   13  O          -1.703775    0.899301    1.082682
   14  C          -2.705225   -0.885294   -0.158201
   15  H          -3.649876   -0.427701    0.142143
   16  H          -2.621601   -1.877349    0.304510
   17  H          -2.692617   -1.036953   -1.244228
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.861021609

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.001176    0.002299    0.003167    0.005329    0.019696    0.029241
     0.037951    0.040498    0.042267    0.045556    0.046094    0.049148
     0.054844    0.059412    0.076630    0.078254    0.103194    0.110113
     0.121811    0.123848    0.128048    0.132944    0.143309    0.149641
     0.173388    0.195572    0.200293    0.208158    0.235519    0.257545
     0.263309    0.295707    0.300246    0.301574    0.301908    0.302479
     0.302513    0.303997    0.305181    0.308496    0.313191    0.330839
     0.345158    0.636803    0.826315

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00005757
 Step Taken.  Stepsize is  0.065142

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.000837      0.000300      NO
         Displacement       0.024563      0.001200      NO
         Energy change     -0.000103      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.093951
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.389297    -0.724746     1.283351
    2      C       3.383052    -0.372156     0.253672
    3      C       2.299599     0.184513    -0.289962
    4      H       4.308441    -0.488548    -0.304279
    5      C       0.982104     0.387753     0.405711
    6      H       2.346556     0.526055    -1.326571
    7      H       0.736614     1.456995     0.446688
    8      H       1.048731     0.048698     1.446483
    9      C      -0.176467    -0.335071    -0.297607
   10      C      -1.545098    -0.011137     0.294255
   11      H      -0.027571    -1.423829    -0.289958
   12      H      -0.212191    -0.057571    -1.363467
   13      O      -1.704896     0.896876     1.087718
   14      C      -2.702778    -0.884728    -0.161090
   15      H      -3.649481    -0.440902     0.154517
   16      H      -2.609167    -1.881666     0.289359
   17      H      -2.696628    -1.023343    -1.248675
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.5001713385 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:34:31 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000836 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:34:31 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    984 shell pairs
 There are   6958 function pairs
 Smallest overlap matrix eigenvalue = 3.06E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:34:31 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8604322837      2.74E-04
    2    -309.8610545214      2.44E-05
    3    -309.8610562318      1.95E-05
    4    -309.8610568010      1.00E-05
    5    -309.8610569066      4.30E-06
    6    -309.8610569446      7.49E-07
    7    -309.8610569425      1.65E-07
    8    -309.8610569434      7.00E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 25.90 s  wall 26.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:34:57 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.135877
      2 C                    -0.341689
      3 C                    -0.046978
      4 H                     0.138372
      5 C                    -0.294962
      6 H                     0.121724
      7 H                     0.168508
      8 H                     0.149266
      9 C                    -0.360973
     10 C                     0.456314
     11 H                     0.160048
     12 H                     0.161526
     13 O                    -0.435681
     14 C                    -0.528956
     15 H                     0.180601
     16 H                     0.173806
     17 H                     0.163196
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0391      Y      -1.8980      Z      -1.7496
       Tot       2.5817
    Quadrupole Moments (Debye-Ang)
        XX     -43.1810     XY       3.2958     YY     -44.5233
        XZ       2.8541     YZ      -3.0429     ZZ     -43.6324
    Octapole Moments (Debye-Ang^2)
       XXX     -15.6950    XXY      -6.5976    XYY      -6.4058
       YYY       8.8744    XXZ     -12.4664    XYZ       1.7403
       YYZ      -7.1956    XZZ       0.4871    YZZ       0.7446
       ZZZ     -21.0647
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1216.7078   XXXY     -29.9351   XXYY    -248.6440
      XYYY     -14.8808   YYYY    -147.1150   XXXZ       7.2752
      XXYZ     -19.7397   XYYZ       6.0313   YYYZ     -23.7492
      XXZZ    -233.1322   XYZZ      -3.4962   YYZZ     -50.1708
      XZZZ      17.7867   YZZZ     -24.8461   ZZZZ    -134.5105
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:34:57 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0001468   0.0003214  -0.0000567  -0.0000133  -0.0000227  -0.0000675
    2   0.0001806  -0.0003062   0.0005389  -0.0000714  -0.0002781   0.0000811
    3   0.0000280   0.0000957   0.0002180  -0.0000490  -0.0000774  -0.0000299
            7           8           9          10          11          12
    1  -0.0000841   0.0001075  -0.0003648   0.0001126  -0.0000991   0.0000655
    2  -0.0000291  -0.0001776  -0.0001143  -0.0000972  -0.0000522   0.0001663
    3  -0.0001729   0.0001353  -0.0002578   0.0001153   0.0000263   0.0000074
           13          14          15          16          17
    1  -0.0000344   0.0001166  -0.0000789   0.0000080  -0.0000569
    2   0.0001215  -0.0001170   0.0000664   0.0000696   0.0000185
    3  -0.0000624  -0.0000490  -0.0000001   0.0000470   0.0000255
 Max gradient component =       5.389E-04
 RMS gradient           =       1.515E-04
 Gradient time:  CPU 12.10 s  wall 13.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:35:10 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  21

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.389297   -0.724746    1.283351
    2  C           3.383052   -0.372156    0.253672
    3  C           2.299599    0.184513   -0.289962
    4  H           4.308441   -0.488548   -0.304279
    5  C           0.982104    0.387753    0.405711
    6  H           2.346556    0.526055   -1.326571
    7  H           0.736614    1.456995    0.446688
    8  H           1.048731    0.048698    1.446483
    9  C          -0.176467   -0.335071   -0.297607
   10  C          -1.545098   -0.011137    0.294255
   11  H          -0.027571   -1.423829   -0.289958
   12  H          -0.212191   -0.057571   -1.363467
   13  O          -1.704896    0.896876    1.087718
   14  C          -2.702778   -0.884728   -0.161090
   15  H          -3.649481   -0.440902    0.154517
   16  H          -2.609167   -1.881666    0.289359
   17  H          -2.696628   -1.023343   -1.248675
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.861056943

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.001193    0.002300    0.002680    0.004398    0.019993    0.029808
     0.035734    0.039916    0.042163    0.043663    0.045817    0.048166
     0.055390    0.057767    0.077201    0.080979    0.104881    0.118082
     0.123244    0.127988    0.129493    0.132349    0.146727    0.152126
     0.172877    0.196245    0.199126    0.208443    0.232806    0.260280
     0.264617    0.295674    0.300443    0.301487    0.301917    0.302020
     0.302788    0.304435    0.306558    0.308739    0.313353    0.332494
     0.332923    0.647738    0.826860

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00003551
 Step Taken.  Stepsize is  0.092215

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.001124      0.000300      NO
         Displacement       0.038695      0.001200      NO
         Energy change     -0.000035      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.149458
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.374265    -0.729894     1.285383
    2      C       3.376556    -0.377027     0.255710
    3      C       2.299767     0.185954    -0.294193
    4      H       4.303597    -0.502128    -0.297648
    5      C       0.982288     0.402026     0.397942
    6      H       2.352949     0.523219    -1.331856
    7      H       0.738281     1.472013     0.423373
    8      H       1.048106     0.079515     1.443799
    9      C      -0.174305    -0.334074    -0.293125
   10      C      -1.542096    -0.019819     0.304862
   11      H      -0.017044    -1.421890    -0.276247
   12      H      -0.218253    -0.069932    -1.362021
   13      O      -1.700795     0.871848     1.116728
   14      C      -2.701158    -0.883951    -0.165543
   15      H      -3.646592    -0.447618     0.163782
   16      H      -2.606148    -1.889782     0.264746
   17      H      -2.699300    -1.001267    -1.255546
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.5613728411 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:35:10 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000826 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:35:10 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    984 shell pairs
 There are   6958 function pairs
 Smallest overlap matrix eigenvalue = 3.06E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:35:10 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8604528044      7.03E-04
    2    -309.8610728745      4.25E-05
    3    -309.8610805673      2.33E-05
    4    -309.8610813655      1.05E-05
    5    -309.8610815123      6.70E-06
    6    -309.8610816093      1.80E-06
    7    -309.8610816205      3.70E-07
    8    -309.8610816134      2.32E-07
    9    -309.8610816396      6.09E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 29.34 s  wall 30.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:35:40 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.135958
      2 C                    -0.341308
      3 C                    -0.047368
      4 H                     0.138364
      5 C                    -0.294913
      6 H                     0.121920
      7 H                     0.167291
      8 H                     0.150136
      9 C                    -0.360509
     10 C                     0.456036
     11 H                     0.160698
     12 H                     0.160781
     13 O                    -0.435565
     14 C                    -0.528843
     15 H                     0.180642
     16 H                     0.173554
     17 H                     0.163127
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0440      Y      -1.8709      Z      -1.7875
       Tot       2.5879
    Quadrupole Moments (Debye-Ang)
        XX     -43.1748     XY       3.2057     YY     -44.4118
        XZ       2.9145     YZ      -3.0370     ZZ     -43.7564
    Octapole Moments (Debye-Ang^2)
       XXX     -15.8057    XXY      -6.4557    XYY      -6.5416
       YYY       9.2780    XXZ     -12.7093    XYZ       1.7336
       YYZ      -7.2711    XZZ       0.6685    YZZ       0.7926
       ZZZ     -21.6836
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1214.2669   XXXY     -31.2930   XXYY    -247.5384
      XYYY     -15.8776   YYYY    -146.0544   XXXZ       8.0765
      XXYZ     -19.6346   XYYZ       6.2263   YYYZ     -23.6752
      XXZZ    -233.3581   XYZZ      -3.7159   YYZZ     -50.4716
      XZZZ      19.0499   YZZZ     -24.9763   ZZZZ    -136.7844
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:35:40 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0000421   0.0001712  -0.0000169   0.0000188  -0.0001820  -0.0000557
    2  -0.0000700   0.0000054   0.0002086   0.0000134  -0.0000078   0.0000148
    3  -0.0000158   0.0001223   0.0000516  -0.0000177  -0.0001639  -0.0000571
            7           8           9          10          11          12
    1   0.0000011   0.0000282   0.0000385   0.0002222  -0.0001620   0.0000228
    2  -0.0000493  -0.0000947   0.0001889  -0.0000951  -0.0001156  -0.0000531
    3   0.0000049   0.0000677   0.0001210   0.0002509  -0.0000905  -0.0000760
           13          14          15          16          17
    1  -0.0000792   0.0000574  -0.0000378  -0.0000320  -0.0000366
    2  -0.0000558   0.0001834  -0.0000357   0.0000481  -0.0000856
    3  -0.0001363  -0.0003396   0.0001200   0.0001172   0.0000414
 Max gradient component =       3.396E-04
 RMS gradient           =       1.117E-04
 Gradient time:  CPU 11.98 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:35:52 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  22

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.374265   -0.729894    1.285383
    2  C           3.376556   -0.377027    0.255710
    3  C           2.299767    0.185954   -0.294193
    4  H           4.303597   -0.502128   -0.297648
    5  C           0.982288    0.402026    0.397942
    6  H           2.352949    0.523219   -1.331856
    7  H           0.738281    1.472013    0.423373
    8  H           1.048106    0.079515    1.443799
    9  C          -0.174305   -0.334074   -0.293125
   10  C          -1.542096   -0.019819    0.304862
   11  H          -0.017044   -1.421890   -0.276247
   12  H          -0.218253   -0.069932   -1.362021
   13  O          -1.700795    0.871848    1.116728
   14  C          -2.701158   -0.883951   -0.165543
   15  H          -3.646592   -0.447618    0.163782
   16  H          -2.606148   -1.889782    0.264746
   17  H          -2.699300   -1.001267   -1.255546
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.861081640

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.001076    0.001909    0.002352    0.003824    0.020052    0.030234
     0.036618    0.040494    0.042188    0.043271    0.045880    0.049118
     0.055507    0.060251    0.078468    0.083039    0.104929    0.118048
     0.123170    0.127791    0.128102    0.132925    0.145929    0.152070
     0.171929    0.196370    0.198483    0.208449    0.229463    0.254635
     0.264953    0.295656    0.300415    0.301341    0.301866    0.302091
     0.302819    0.304972    0.306393    0.308714    0.313348    0.321719
     0.333205    0.642317    0.827686

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00001995
 Step Taken.  Stepsize is  0.099249

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.000677      0.000300      NO
         Displacement       0.034227      0.001200      NO
         Energy change     -0.000025      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.177266
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.363377    -0.724437     1.292077
    2      C       3.371093    -0.380808     0.259295
    3      C       2.299773     0.184452    -0.298406
    4      H       4.298405    -0.518237    -0.290663
    5      C       0.982683     0.415693     0.389740
    6      H       2.357331     0.510879    -1.339201
    7      H       0.740058     1.486345     0.395803
    8      H       1.047644     0.112530     1.441155
    9      C      -0.172872    -0.333969    -0.288174
   10      C      -1.539594    -0.029688     0.317013
   11      H      -0.005551    -1.420192    -0.262196
   12      H      -0.225503    -0.080718    -1.359159
   13      O      -1.696019     0.844292     1.148337
   14      C      -2.700310    -0.882587    -0.170064
   15      H      -3.644070    -0.458291     0.178842
   16      H      -2.600048    -1.900807     0.228845
   17      H      -2.706281    -0.967262    -1.263099
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.5961437088 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:35:53 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000816 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:35:53 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    984 shell pairs
 There are   6960 function pairs
 Smallest overlap matrix eigenvalue = 3.06E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:35:53 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8599233176      7.64E-04
    2    -309.8610833710      4.99E-05
    3    -309.8610930529      3.21E-05
    4    -309.8610944334      1.85E-05
    5    -309.8610949823      8.54E-06
    6    -309.8610951138      2.65E-06
    7    -309.8610951247      9.74E-07
    8    -309.8610951176      2.16E-07
    9    -309.8610951185      5.35E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 29.20 s  wall 30.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:36:23 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.136076
      2 C                    -0.341012
      3 C                    -0.047625
      4 H                     0.138363
      5 C                    -0.294864
      6 H                     0.122007
      7 H                     0.165865
      8 H                     0.151122
      9 C                    -0.359952
     10 C                     0.455608
     11 H                     0.161405
     12 H                     0.159927
     13 O                    -0.435390
     14 C                    -0.528591
     15 H                     0.180652
     16 H                     0.173200
     17 H                     0.163210
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0459      Y      -1.8390      Z      -1.8301
       Tot       2.5949
    Quadrupole Moments (Debye-Ang)
        XX     -43.1586     XY       3.1029     YY     -44.3074
        XZ       2.9936     YZ      -3.0149     ZZ     -43.8855
    Octapole Moments (Debye-Ang^2)
       XXX     -15.9274    XXY      -6.2742    XYY      -6.7197
       YYY       9.7553    XXZ     -12.9582    XYZ       1.7585
       YYZ      -7.3803    XZZ       0.9059    YZZ       0.8885
       ZZZ     -22.3924
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1212.2241   XXXY     -32.7481   XXYY    -246.5684
      XYYY     -16.8499   YYYY    -144.6616   XXXZ       9.0112
      XXYZ     -19.3565   XYYZ       6.3574   YYYZ     -23.5557
      XXZZ    -233.5802   XYZZ      -3.9844   YYZZ     -50.8330
      XZZZ      20.3491   YZZZ     -25.1169   ZZZZ    -139.4205
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:36:23 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0000108  -0.0000036   0.0000985   0.0000117  -0.0000693  -0.0000421
    2  -0.0001435   0.0001578  -0.0000412   0.0000451   0.0000806  -0.0000089
    3  -0.0000338   0.0000490   0.0000180  -0.0000047  -0.0001373  -0.0000250
            7           8           9          10          11          12
    1  -0.0000074   0.0000065   0.0001218   0.0001326  -0.0000879  -0.0000253
    2  -0.0000279  -0.0000177   0.0001536  -0.0001264  -0.0000439  -0.0000688
    3   0.0000588  -0.0000097   0.0002270   0.0001606  -0.0000619  -0.0000706
           13          14          15          16          17
    1  -0.0000724  -0.0000272   0.0000113  -0.0000344  -0.0000020
    2  -0.0000776   0.0002884  -0.0000608   0.0000108  -0.0001197
    3  -0.0000642  -0.0003552   0.0000984   0.0001251   0.0000254
 Max gradient component =       3.552E-04
 RMS gradient           =       1.033E-04
 Gradient time:  CPU 11.69 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:36:35 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  23

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.363377   -0.724437    1.292077
    2  C           3.371093   -0.380808    0.259295
    3  C           2.299773    0.184452   -0.298406
    4  H           4.298405   -0.518237   -0.290663
    5  C           0.982683    0.415693    0.389740
    6  H           2.357331    0.510879   -1.339201
    7  H           0.740058    1.486345    0.395803
    8  H           1.047644    0.112530    1.441155
    9  C          -0.172872   -0.333969   -0.288174
   10  C          -1.539594   -0.029688    0.317013
   11  H          -0.005551   -1.420192   -0.262196
   12  H          -0.225503   -0.080718   -1.359159
   13  O          -1.696019    0.844292    1.148337
   14  C          -2.700310   -0.882587   -0.170064
   15  H          -3.644070   -0.458291    0.178842
   16  H          -2.600048   -1.900807    0.228845
   17  H          -2.706281   -0.967262   -1.263099
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.861095119

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000925    0.001472    0.002530    0.003556    0.020055    0.030170
     0.036842    0.040525    0.042150    0.043194    0.045879    0.050020
     0.054984    0.060302    0.078429    0.081224    0.104940    0.117926
     0.122969    0.127322    0.128169    0.132823    0.145673    0.149947
     0.172211    0.196865    0.198547    0.208117    0.229249    0.252376
     0.265477    0.296259    0.300457    0.301375    0.301824    0.302210
     0.302784    0.304975    0.306333    0.308776    0.313327    0.317401
     0.333765    0.645193    0.826182

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00001645
 Step Taken.  Stepsize is  0.115998

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.000237      0.000300     YES
         Displacement       0.044104      0.001200      NO
         Energy change     -0.000013      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.214775
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.347722    -0.716424     1.304800
    2      C       3.363396    -0.387121     0.267534
    3      C       2.299381     0.179787    -0.301865
    4      H       4.291550    -0.541262    -0.276464
    5      C       0.982706     0.429912     0.380170
    6      H       2.362940     0.491067    -1.346829
    7      H       0.745011     1.501713     0.368633
    8      H       1.043598     0.143928     1.436426
    9      C      -0.171861    -0.328712    -0.289116
   10      C      -1.537175    -0.035211     0.324091
   11      H       0.005091    -1.413395    -0.259271
   12      H      -0.231474    -0.080719    -1.360675
   13      O      -1.692325     0.828066     1.166737
   14      C      -2.697560    -0.884829    -0.169657
   15      H      -3.638288    -0.488077     0.217385
   16      H      -2.575096    -1.917517     0.183188
   17      H      -2.727498    -0.924011    -1.264940
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.6681664732 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:36:35 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000809 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:36:35 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    986 shell pairs
 There are   6965 function pairs
 Smallest overlap matrix eigenvalue = 3.06E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:36:35 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8597236192      6.17E-04
    2    -309.8610952309      4.85E-05
    3    -309.8611040729      3.56E-05
    4    -309.8611055642      2.33E-05
    5    -309.8611063685      6.92E-06
    6    -309.8611064423      1.90E-06
    7    -309.8611064644      8.19E-07
    8    -309.8611064723      1.36E-07
    9    -309.8611064601      4.00E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 28.27 s  wall 28.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:37:04 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.136168
      2 C                    -0.340824
      3 C                    -0.047770
      4 H                     0.138343
      5 C                    -0.294863
      6 H                     0.122104
      7 H                     0.164750
      8 H                     0.151918
      9 C                    -0.359373
     10 C                     0.455402
     11 H                     0.161663
     12 H                     0.159428
     13 O                    -0.435187
     14 C                    -0.528557
     15 H                     0.180578
     16 H                     0.172280
     17 H                     0.163941
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0509      Y      -1.8158      Z      -1.8618
       Tot       2.6012
    Quadrupole Moments (Debye-Ang)
        XX     -43.1651     XY       3.0257     YY     -44.2600
        XZ       3.0507     YZ      -2.9784     ZZ     -43.9416
    Octapole Moments (Debye-Ang^2)
       XXX     -15.9866    XXY      -6.2154    XYY      -6.7668
       YYY      10.0521    XXZ     -13.1033    XYZ       1.7954
       YYZ      -7.4796    XZZ       1.0284    YZZ       0.9823
       ZZZ     -22.8110
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1209.5052   XXXY     -33.5627   XXYY    -245.8227
      XYYY     -17.2558   YYYY    -144.2144   XXXZ       9.4368
      XXYZ     -18.9388   XYYZ       6.4343   YYYZ     -23.3254
      XXZZ    -233.1272   XYZZ      -4.1574   YYZZ     -51.2287
      XZZZ      21.0671   YZZZ     -25.1341   ZZZZ    -141.0470
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:37:04 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0000878  -0.0001924  -0.0000005  -0.0000103   0.0000649  -0.0000069
    2  -0.0001481   0.0002921  -0.0002984   0.0000426   0.0000785  -0.0000474
    3  -0.0000942   0.0000169  -0.0001423   0.0000342   0.0000248   0.0000029
            7           8           9          10          11          12
    1   0.0000350  -0.0000381   0.0001955   0.0001266   0.0000241  -0.0000009
    2   0.0000227   0.0000888   0.0002817  -0.0001637  -0.0000271  -0.0001057
    3   0.0001683  -0.0000453   0.0001033   0.0001895  -0.0000399   0.0000288
           13          14          15          16          17
    1  -0.0000343  -0.0000965   0.0000687  -0.0000995   0.0000526
    2  -0.0001085   0.0004541  -0.0001603  -0.0000320  -0.0001693
    3  -0.0001074  -0.0005580   0.0001813   0.0001754   0.0000617
 Max gradient component =       5.580E-04
 RMS gradient           =       1.560E-04
 Gradient time:  CPU 11.70 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:37:16 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  24

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.347722   -0.716424    1.304800
    2  C           3.363396   -0.387121    0.267534
    3  C           2.299381    0.179787   -0.301865
    4  H           4.291550   -0.541262   -0.276464
    5  C           0.982706    0.429912    0.380170
    6  H           2.362940    0.491067   -1.346829
    7  H           0.745011    1.501713    0.368633
    8  H           1.043598    0.143928    1.436426
    9  C          -0.171861   -0.328712   -0.289116
   10  C          -1.537175   -0.035211    0.324091
   11  H           0.005091   -1.413395   -0.259271
   12  H          -0.231474   -0.080719   -1.360675
   13  O          -1.692325    0.828066    1.166737
   14  C          -2.697560   -0.884829   -0.169657
   15  H          -3.638288   -0.488077    0.217385
   16  H          -2.575096   -1.917517    0.183188
   17  H          -2.727498   -0.924011   -1.264940
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.861106460

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000449    0.001450    0.002513    0.003593    0.020071    0.030647
     0.038649    0.040318    0.042272    0.043647    0.045883    0.049703
     0.054949    0.058253    0.077878    0.080426    0.104974    0.118316
     0.123547    0.127898    0.132630    0.133987    0.148382    0.148932
     0.176786    0.195987    0.204499    0.210186    0.231593    0.261173
     0.279651    0.296534    0.300456    0.301378    0.301798    0.302163
     0.302817    0.305443    0.306786    0.308942    0.313482    0.332510
     0.340518    0.657041    0.825307

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00002055
 Step Taken.  Stepsize is  0.171826

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.000539      0.000300      NO
         Displacement       0.070132      0.001200      NO
         Energy change     -0.000011      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.310587
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.340279    -0.691233     1.325553
    2      C       3.359303    -0.389151     0.279928
    3      C       2.300240     0.170907    -0.305541
    4      H       4.287168    -0.562779    -0.258772
    5      C       0.982516     0.443082     0.366416
    6      H       2.368655     0.455960    -1.357611
    7      H       0.749022     1.515223     0.326917
    8      H       1.038807     0.182781     1.429338
    9      C      -0.172155    -0.328869    -0.287755
   10      C      -1.534715    -0.044624     0.336621
   11      H       0.014829    -1.411570    -0.250068
   12      H      -0.242434    -0.090120    -1.360676
   13      O      -1.684706     0.802273     1.196803
   14      C      -2.697173    -0.883317    -0.170481
   15      H      -3.631793    -0.526395     0.266750
   16      H      -2.547017    -1.934723     0.107605
   17      H      -2.760708    -0.850250    -1.264880
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.6745046825 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:37:16 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000798 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:37:16 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    982 shell pairs
 There are   6951 function pairs
 Smallest overlap matrix eigenvalue = 3.06E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:37:16 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8567480603      9.23E-04
    2    -309.8610829091      8.33E-05
    3    -309.8610962196      9.48E-05
    4    -309.8611102729      3.55E-05
    5    -309.8611119770      1.15E-05
    6    -309.8611121862      3.34E-06
    7    -309.8611122222      1.49E-06
    8    -309.8611122299      2.52E-07
    9    -309.8611122204      6.85E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 29.14 s  wall 29.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:37:45 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.136367
      2 C                    -0.340602
      3 C                    -0.048006
      4 H                     0.138313
      5 C                    -0.294784
      6 H                     0.122024
      7 H                     0.163210
      8 H                     0.153108
      9 C                    -0.358644
     10 C                     0.454951
     11 H                     0.162222
     12 H                     0.158503
     13 O                    -0.434914
     14 C                    -0.528318
     15 H                     0.180488
     16 H                     0.171055
     17 H                     0.165025
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0446      Y      -1.7789      Z      -1.9111
       Tot       2.6113
    Quadrupole Moments (Debye-Ang)
        XX     -43.1290     XY       2.9054     YY     -44.2057
        XZ       3.1533     YZ      -2.9169     ZZ     -44.0422
    Octapole Moments (Debye-Ang^2)
       XXX     -16.1732    XXY      -5.9925    XYY      -6.9358
       YYY      10.5719    XXZ     -13.3063    XYZ       1.8727
       YYZ      -7.6817    XZZ       1.2400    YZZ       1.1546
       ZZZ     -23.5265
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1207.7817   XXXY     -34.8117   XXYY    -245.3261
      XYYY     -18.0132   YYYY    -142.6909   XXXZ      10.2262
      XXYZ     -18.3499   XYYZ       6.4456   YYYZ     -22.9583
      XXZZ    -232.9238   XYZZ      -4.4927   YYZZ     -51.7252
      XZZZ      21.9677   YZZZ     -25.2272   ZZZZ    -143.8209
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:37:45 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0000347  -0.0001508  -0.0000059  -0.0000206   0.0000883   0.0000370
    2  -0.0000742   0.0001202  -0.0002030   0.0000113   0.0001099  -0.0000448
    3   0.0000644  -0.0000558  -0.0001310  -0.0000313   0.0000823   0.0000245
            7           8           9          10          11          12
    1   0.0000238  -0.0000483   0.0001551  -0.0001210   0.0001082  -0.0000535
    2   0.0000069   0.0000735   0.0000535  -0.0001804   0.0000681  -0.0000250
    3   0.0000478  -0.0000829   0.0001412  -0.0000436  -0.0000310   0.0000187
           13          14          15          16          17
    1   0.0000084  -0.0001224   0.0000226   0.0000986   0.0000152
    2   0.0000493   0.0002925  -0.0001030  -0.0000417  -0.0001130
    3   0.0001313  -0.0002281   0.0000255   0.0000500   0.0000181
 Max gradient component =       2.925E-04
 RMS gradient           =       9.778E-05
 Gradient time:  CPU 11.61 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:37:57 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  25

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.340279   -0.691233    1.325553
    2  C           3.359303   -0.389151    0.279928
    3  C           2.300240    0.170907   -0.305541
    4  H           4.287168   -0.562779   -0.258772
    5  C           0.982516    0.443082    0.366416
    6  H           2.368655    0.455960   -1.357611
    7  H           0.749022    1.515223    0.326917
    8  H           1.038807    0.182781    1.429338
    9  C          -0.172155   -0.328869   -0.287755
   10  C          -1.534715   -0.044624    0.336621
   11  H           0.014829   -1.411570   -0.250068
   12  H          -0.242434   -0.090120   -1.360676
   13  O          -1.684706    0.802273    1.196803
   14  C          -2.697173   -0.883317   -0.170481
   15  H          -3.631793   -0.526395    0.266750
   16  H          -2.547017   -1.934723    0.107605
   17  H          -2.760708   -0.850250   -1.264880
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.861112220

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000871    0.001455    0.002528    0.003835    0.020135    0.030782
     0.037624    0.040171    0.042278    0.043944    0.045913    0.048008
     0.051238    0.057029    0.077466    0.080406    0.104954    0.118354
     0.123578    0.127859    0.132572    0.133449    0.147198    0.149298
     0.175020    0.195221    0.202847    0.209245    0.234224    0.261495
     0.270240    0.297461    0.300548    0.301587    0.301798    0.302286
     0.302821    0.305262    0.307092    0.308773    0.313544    0.331426
     0.335319    0.650157    0.827792

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00001217
 Step Taken.  Stepsize is  0.069198

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.000840      0.000300      NO
         Displacement       0.023518      0.001200      NO
         Energy change     -0.000006      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.130578
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.351306    -0.692072     1.319200
    2      C       3.364886    -0.384071     0.275346
    3      C       2.300122     0.172238    -0.303450
    4      H       4.292617    -0.547333    -0.266768
    5      C       0.982543     0.432222     0.373391
    6      H       2.363744     0.465127    -1.353717
    7      H       0.746529     1.504238     0.347189
    8      H       1.041322     0.159123     1.433126
    9      C      -0.172978    -0.332398    -0.288280
   10      C      -1.536510    -0.039681     0.330086
   11      H       0.006959    -1.416325    -0.253292
   12      H      -0.237098    -0.088939    -1.360595
   13      O      -1.687541     0.817991     1.179289
   14      C      -2.699182    -0.882337    -0.169757
   15      H      -3.635617    -0.509607     0.250228
   16      H      -2.559113    -1.928118     0.133350
   17      H      -2.751871    -0.872863    -1.265200
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.6429471294 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:37:57 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000805 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:37:57 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    982 shell pairs
 There are   6951 function pairs
 Smallest overlap matrix eigenvalue = 3.06E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:37:58 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8603553358      4.84E-04
    2    -309.8611143102      3.29E-05
    3    -309.8611187403      1.85E-05
    4    -309.8611192711      7.93E-06
    5    -309.8611193678      4.31E-06
    6    -309.8611193798      1.50E-06
    7    -309.8611193919      3.12E-07
    8    -309.8611194046      1.67E-07
    9    -309.8611194341      4.91E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 27.60 s  wall 27.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:38:25 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.136275
      2 C                    -0.340841
      3 C                    -0.047750
      4 H                     0.138329
      5 C                    -0.294753
      6 H                     0.121931
      7 H                     0.164111
      8 H                     0.152411
      9 C                    -0.358997
     10 C                     0.455094
     11 H                     0.161873
     12 H                     0.158968
     13 O                    -0.434925
     14 C                    -0.528376
     15 H                     0.180483
     16 H                     0.171449
     17 H                     0.164718
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0421      Y      -1.7986      Z      -1.8849
       Tot       2.6057
    Quadrupole Moments (Debye-Ang)
        XX     -43.1323     XY       2.9722     YY     -44.2619
        XZ       3.1103     YZ      -2.9372     ZZ     -43.9708
    Octapole Moments (Debye-Ang^2)
       XXX     -16.0763    XXY      -6.0539    XYY      -6.8850
       YYY      10.3119    XXZ     -13.1565    XYZ       1.8615
       YYZ      -7.6052    XZZ       1.1207    YZZ       1.0970
       ZZZ     -23.1316
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1209.7774   XXXY     -34.0182   XXYY    -246.0226
      XYYY     -17.5290   YYYY    -143.0707   XXXZ       9.7480
      XXYZ     -18.5585   XYYZ       6.3534   YYYZ     -23.1813
      XXZZ    -233.0403   XYZZ      -4.3568   YYZZ     -51.4719
      XZZZ      21.2533   YZZZ     -25.2442   ZZZZ    -142.2242
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:38:25 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0000012  -0.0000807  -0.0000235  -0.0000155   0.0000860   0.0000275
    2   0.0000161   0.0000228  -0.0000755  -0.0000048   0.0000101  -0.0000063
    3  -0.0000014  -0.0000366  -0.0000460  -0.0000027   0.0000817   0.0000239
            7           8           9          10          11          12
    1   0.0000065  -0.0000202   0.0000008  -0.0000560   0.0000658  -0.0000293
    2   0.0000289   0.0000263  -0.0000134  -0.0000978   0.0000374   0.0000154
    3   0.0000135  -0.0000372  -0.0000094   0.0000011   0.0000061   0.0000193
           13          14          15          16          17
    1   0.0000089  -0.0000119  -0.0000013   0.0000100   0.0000342
    2   0.0000334   0.0000804  -0.0000367  -0.0000040  -0.0000324
    3   0.0000525  -0.0001143  -0.0000048   0.0000458   0.0000085
 Max gradient component =       1.143E-04
 RMS gradient           =       4.108E-05
 Gradient time:  CPU 11.61 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:38:37 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  26

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.351306   -0.692072    1.319200
    2  C           3.364886   -0.384071    0.275346
    3  C           2.300122    0.172238   -0.303450
    4  H           4.292617   -0.547333   -0.266768
    5  C           0.982543    0.432222    0.373391
    6  H           2.363744    0.465127   -1.353717
    7  H           0.746529    1.504238    0.347189
    8  H           1.041322    0.159123    1.433126
    9  C          -0.172978   -0.332398   -0.288280
   10  C          -1.536510   -0.039681    0.330086
   11  H           0.006959   -1.416325   -0.253292
   12  H          -0.237098   -0.088939   -1.360595
   13  O          -1.687541    0.817991    1.179289
   14  C          -2.699182   -0.882337   -0.169757
   15  H          -3.635617   -0.509607    0.250228
   16  H          -2.559113   -1.928118    0.133350
   17  H          -2.751871   -0.872863   -1.265200
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.861119434

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.001178    0.001261    0.002320    0.003685    0.020113    0.031456
     0.037650    0.040182    0.042294    0.042939    0.045854    0.047673
     0.050740    0.056887    0.077534    0.080383    0.104968    0.118300
     0.123496    0.127868    0.132342    0.133458    0.146968    0.149439
     0.173421    0.193585    0.201501    0.207533    0.222441    0.256163
     0.264852    0.296244    0.300549    0.301118    0.301785    0.301977
     0.302858    0.305503    0.305579    0.308780    0.313467    0.317092
     0.334468    0.646693    0.825404

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00000339
 Step Taken.  Stepsize is  0.040677

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.000397      0.000300      NO
         Displacement       0.023856      0.001200      NO
         Energy change     -0.000007      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.045953
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.354162    -0.688431     1.320549
    2      C       3.366908    -0.381725     0.276357
    3      C       2.300450     0.170974    -0.302870
    4      H       4.295218    -0.542806    -0.265409
    5      C       0.982493     0.428416     0.374086
    6      H       2.362974     0.463228    -1.353402
    7      H       0.746172     1.500420     0.350626
    8      H       1.041301     0.152669     1.433225
    9      C      -0.173290    -0.334232    -0.289499
   10      C      -1.536899    -0.037369     0.326822
   11      H       0.003885    -1.418586    -0.253828
   12      H      -0.234955    -0.090645    -1.361924
   13      O      -1.687785     0.826189     1.170032
   14      C      -2.700152    -0.881951    -0.168381
   15      H      -3.634837    -0.513283     0.259053
   16      H      -2.555556    -1.928904     0.128179
   17      H      -2.759970    -0.866770    -1.263470
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.6368308817 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:38:37 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000807 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:38:37 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    981 shell pairs
 There are   6950 function pairs
 Smallest overlap matrix eigenvalue = 3.06E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:38:37 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8610162579      2.34E-04
    2    -309.8611204014      1.53E-05
    3    -309.8611212898      9.85E-06
    4    -309.8611214420      4.55E-06
    5    -309.8611214664      2.67E-06
    6    -309.8611214726      8.86E-07
    7    -309.8611214654      2.31E-07
    8    -309.8611214361      9.23E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 25.08 s  wall 26.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:39:03 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.136244
      2 C                    -0.340949
      3 C                    -0.047625
      4 H                     0.138333
      5 C                    -0.294756
      6 H                     0.121883
      7 H                     0.164465
      8 H                     0.152153
      9 C                    -0.359025
     10 C                     0.455128
     11 H                     0.161652
     12 H                     0.159143
     13 O                    -0.434847
     14 C                    -0.528440
     15 H                     0.180462
     16 H                     0.171150
     17 H                     0.165029
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0399      Y      -1.8069      Z      -1.8749
       Tot       2.6042
    Quadrupole Moments (Debye-Ang)
        XX     -43.1308     XY       2.9968     YY     -44.3032
        XZ       3.0954     YZ      -2.9354     ZZ     -43.9232
    Octapole Moments (Debye-Ang^2)
       XXX     -16.0485    XXY      -6.0829    XYY      -6.8430
       YYY      10.1951    XXZ     -13.0727    XYZ       1.8623
       YYZ      -7.5921    XZZ       1.0292    YZZ       1.0924
       ZZZ     -22.9250
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1210.5463   XXXY     -33.5814   XXYY    -246.4440
      XYYY     -17.2710   YYYY    -143.2966   XXXZ       9.3961
      XXYZ     -18.5628   XYYZ       6.2925   YYYZ     -23.2105
      XXZZ    -232.8609   XYZZ      -4.3227   YYZZ     -51.4151
      XZZZ      20.7749   YZZZ     -25.2355   ZZZZ    -141.3919
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:39:03 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1  -0.0000019  -0.0000390  -0.0000485  -0.0000066   0.0000607   0.0000123
    2   0.0000487  -0.0000126  -0.0000169  -0.0000129  -0.0000304   0.0000026
    3  -0.0000284  -0.0000101  -0.0000252   0.0000135   0.0000682   0.0000145
            7           8           9          10          11          12
    1   0.0000094  -0.0000066  -0.0000582   0.0000048   0.0000409  -0.0000021
    2   0.0000263   0.0000049   0.0000226  -0.0000550  -0.0000007   0.0000167
    3   0.0000137  -0.0000021  -0.0001099   0.0000680   0.0000211   0.0000313
           13          14          15          16          17
    1   0.0000135   0.0000090  -0.0000001  -0.0000135   0.0000259
    2   0.0000292   0.0000264  -0.0000370   0.0000001  -0.0000118
    3  -0.0000141  -0.0001084   0.0000245   0.0000292   0.0000141
 Max gradient component =       1.099E-04
 RMS gradient           =       3.545E-05
 Gradient time:  CPU 11.67 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:39:15 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  27

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.354162   -0.688431    1.320549
    2  C           3.366908   -0.381725    0.276357
    3  C           2.300450    0.170974   -0.302870
    4  H           4.295218   -0.542806   -0.265409
    5  C           0.982493    0.428416    0.374086
    6  H           2.362974    0.463228   -1.353402
    7  H           0.746172    1.500420    0.350626
    8  H           1.041301    0.152669    1.433225
    9  C          -0.173290   -0.334232   -0.289499
   10  C          -1.536899   -0.037369    0.326822
   11  H           0.003885   -1.418586   -0.253828
   12  H          -0.234955   -0.090645   -1.361924
   13  O          -1.687785    0.826189    1.170032
   14  C          -2.700152   -0.881951   -0.168381
   15  H          -3.634837   -0.513283    0.259053
   16  H          -2.555556   -1.928904    0.128179
   17  H          -2.759970   -0.866770   -1.263470
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.861121436

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.001008    0.001512    0.002357    0.003613    0.020114    0.031303
     0.037521    0.040328    0.041528    0.042315    0.045848    0.047682
     0.050349    0.057296    0.077541    0.080560    0.104774    0.117864
     0.123269    0.127876    0.131535    0.133684    0.146849    0.149757
     0.167401    0.187189    0.197961    0.206094    0.216543    0.250187
     0.264720    0.295412    0.300118    0.300956    0.301744    0.301872
     0.302820    0.304205    0.305610    0.308821    0.311440    0.313703
     0.335149    0.644075    0.824212

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00000103
 Step Taken.  Stepsize is  0.018095

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.000231      0.000300     YES
         Displacement       0.008604      0.001200      NO
         Energy change     -0.000002      0.000001      NO


 New Cartesian Coordinates Obtained by Inverse Iteration

 Displacement from previous Coordinates is:  0.032057
 Writing REM_CC_EA           17
 ----------------------------------------------------
       Standard Nuclear Orientation (Angstroms)
    I     Atom         X            Y            Z
 ----------------------------------------------------
    1      H       3.356695    -0.684996     1.321514
    2      C       3.368532    -0.379535     0.276875
    3      C       2.300943     0.170495    -0.302974
    4      H       4.297000    -0.539395    -0.265032
    5      C       0.982458     0.427003     0.373490
    6      H       2.362943     0.461415    -1.353942
    7      H       0.745036     1.498693     0.348289
    8      H       1.041746     0.152963     1.433058
    9      C      -0.173267    -0.337226    -0.288330
   10      C      -1.536804    -0.038222     0.327373
   11      H       0.003058    -1.421610    -0.249924
   12      H      -0.234803    -0.096477    -1.361456
   13      O      -1.686657     0.825036     1.171096
   14      C      -2.701389    -0.880285    -0.168985
   15      H      -3.634996    -0.513195     0.262180
   16      H      -2.556399    -1.929011     0.120791
   17      H      -2.763979    -0.858459    -1.263878
 ----------------------------------------------------
 Molecular Point Group                 C1    NOp =  1
 Largest Abelian Subgroup              C1    NOp =  1
 Nuclear Repulsion Energy =   281.6212407964 hartrees
 There are       27 alpha and       27 beta electrons

-------------------------------------------------
-  Entering fldman on Wed Oct  3 12:39:15 2007  -
-------------------------------------------------

 Applying Cartesian multipole field
    Component          Value
    ---------          -----
     (2,0,0)        1.00000E-10
     (0,2,0)        2.00000E-10
     (0,0,2)       -3.00000E-10
 Nucleus-field energy     =     0.0000000807 hartrees

-------------------------------------------------
-  Entering gesman on Wed Oct  3 12:39:15 2007  -
-------------------------------------------------

 Requested basis set is 6-31G(d)
 There are 48 shells and 125 basis functions
 A cutoff of  1.0D-09 yielded    981 shell pairs
 There are   6950 function pairs
 Smallest overlap matrix eigenvalue = 3.06E-03
 Multipole matrices computed through 2nd order
 Guess MOs from SCF MO coefficient file

-------------------------------------------------
-  Entering scfman on Wed Oct  3 12:39:15 2007  -
-------------------------------------------------

 A restricted hybrid HF-DFT SCF calculation will be
 performed using Pulay DIIS + Geometric Direct Minimization
 Exchange:     0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 Becke
 Correlation:  0.8100 LYP + 0.1900 VWN1RPA
 Using SG-1 standard quadrature grid
 SCF converges when RMS gradient is below 1.0E-07
 ---------------------------------------
  Cycle       Energy         DIIS Error
 ---------------------------------------
    1    -309.8609578711      8.44E-05
    2    -309.8611218463      7.32E-06
    3    -309.8611219746      7.49E-06
    4    -309.8611220535      3.21E-06
    5    -309.8611220571      1.17E-06
    6    -309.8611220605      2.30E-07
    7    -309.8611220817      4.51E-08 Convergence criterion met
 ---------------------------------------
 SCF time:  CPU 22.14 s  wall 22.00 s

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:39:37 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.136255
      2 C                    -0.340941
      3 C                    -0.047643
      4 H                     0.138334
      5 C                    -0.294742
      6 H                     0.121848
      7 H                     0.164450
      8 H                     0.152193
      9 C                    -0.358975
     10 C                     0.455070
     11 H                     0.161716
     12 H                     0.159030
     13 O                    -0.434793
     14 C                    -0.528418
     15 H                     0.180467
     16 H                     0.171029
     17 H                     0.165120
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0367      Y      -1.8057      Z      -1.8767
       Tot       2.6046
    Quadrupole Moments (Debye-Ang)
        XX     -43.1191     XY       2.9917     YY     -44.3054
        XZ       3.1013     YZ      -2.9314     ZZ     -43.9269
    Octapole Moments (Debye-Ang^2)
       XXX     -16.0785    XXY      -6.0358    XYY      -6.8747
       YYY      10.2263    XXZ     -13.0720    XYZ       1.8587
       YYZ      -7.6048    XZZ       1.0262    YZZ       1.1101
       ZZZ     -22.9555
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1211.0914   XXXY     -33.6386   XXYY    -246.5953
      XYYY     -17.3719   YYYY    -142.9982   XXXZ       9.3811
      XXYZ     -18.5442   XYYZ       6.2699   YYYZ     -23.2004
      XXZZ    -232.9461   XYZZ      -4.3758   YYZZ     -51.4080
      XZZZ      20.7318   YZZZ     -25.2517   ZZZZ    -141.4649
 -----------------------------------------------------------------

-------------------------------------------------
-  Entering drvman on Wed Oct  3 12:39:37 2007  -
-------------------------------------------------

 Calculating analytic gradient of the SCF energy
 Gradient of SCF Energy
            1           2           3           4           5           6
    1   0.0000093   0.0000259  -0.0000126   0.0000035  -0.0000047   0.0000028
    2   0.0000308  -0.0000432   0.0000505  -0.0000047  -0.0000121   0.0000088
    3   0.0000194  -0.0000051   0.0000109  -0.0000087   0.0000112  -0.0000017
            7           8           9          10          11          12
    1  -0.0000006   0.0000022  -0.0000280  -0.0000035   0.0000022  -0.0000107
    2  -0.0000041  -0.0000151  -0.0000182  -0.0000103   0.0000053   0.0000153
    3  -0.0000197   0.0000020  -0.0000245   0.0000005  -0.0000006  -0.0000025
           13          14          15          16          17
    1  -0.0000023   0.0000269  -0.0000191   0.0000066   0.0000021
    2   0.0000301  -0.0000587   0.0000061   0.0000057   0.0000137
    3   0.0000223   0.0000213  -0.0000210  -0.0000064   0.0000027
 Max gradient component =       5.868E-05
 RMS gradient           =       1.845E-05
 Gradient time:  CPU 11.59 s  wall 12.00 s

-------------------------------------------------
-  Entering optman on Wed Oct  3 12:39:49 2007  -
-------------------------------------------------


 Cartesian Hessian Update
 Hessian Updated using BFGS Update


** GEOMETRY OPTIMIZATION IN DELOCALIZED INTERNAL COORDINATES **
   Searching for a Minimum

   Optimization Cycle:  28

                       Coordinates (Angstroms)
     ATOM              X           Y           Z
    1  H           3.356695   -0.684996    1.321514
    2  C           3.368532   -0.379535    0.276875
    3  C           2.300943    0.170495   -0.302974
    4  H           4.297000   -0.539395   -0.265032
    5  C           0.982458    0.427003    0.373490
    6  H           2.362943    0.461415   -1.353942
    7  H           0.745036    1.498693    0.348289
    8  H           1.041746    0.152963    1.433058
    9  C          -0.173267   -0.337226   -0.288330
   10  C          -1.536804   -0.038222    0.327373
   11  H           0.003058   -1.421610   -0.249924
   12  H          -0.234803   -0.096477   -1.361456
   13  O          -1.686657    0.825036    1.171096
   14  C          -2.701389   -0.880285   -0.168985
   15  H          -3.634996   -0.513195    0.262180
   16  H          -2.556399   -1.929011    0.120791
   17  H          -2.763979   -0.858459   -1.263878
   Point Group: c1    Number of degrees of freedom:  45


   Energy is   -309.861122082

 Hessian Updated using BFGS Update
  internal optimization with constraints (0)

 45 Hessian modes will be used to form the next step
  Hessian Eigenvalues:
     0.000848    0.001510    0.002380    0.003168    0.020096    0.030336
     0.038660    0.040270    0.041693    0.042326    0.045859    0.047528
     0.054376    0.057007    0.077493    0.080885    0.104968    0.117115
     0.123137    0.127791    0.131707    0.136181    0.147615    0.150273
     0.172882    0.190025    0.199394    0.205869    0.214780    0.253976
     0.267823    0.293135    0.300161    0.301287    0.301719    0.301936
     0.303156    0.304089    0.305726    0.308697    0.311016    0.316664
     0.335422    0.652357    0.824031

 Minimum Search - Taking Simple RFO Step
 Searching for Lamda that Minimizes Along All modes
 Value Taken    Lamda =  -0.00000025
 Step Taken.  Stepsize is  0.010046

                             Maximum     Tolerance    Cnvgd?
         Gradient           0.000088      0.000300     YES
         Displacement       0.004922      0.001200      NO
         Energy change     -0.000001      0.000001     YES



 ******************************
 **  OPTIMIZATION CONVERGED  **
 ******************************

-------------------------------------------------
-  Entering anlman on Wed Oct  3 12:39:49 2007  -
-------------------------------------------------

 Analysis of SCF Wavefunction
 
         Mulliken Net Atomic Charges

     Atom                 Charge (a.u.)
  ----------------------------------------
      1 H                     0.136255
      2 C                    -0.340941
      3 C                    -0.047643
      4 H                     0.138334
      5 C                    -0.294742
      6 H                     0.121848
      7 H                     0.164450
      8 H                     0.152193
      9 C                    -0.358975
     10 C                     0.455070
     11 H                     0.161716
     12 H                     0.159030
     13 O                    -0.434793
     14 C                    -0.528418
     15 H                     0.180467
     16 H                     0.171029
     17 H                     0.165120
  ----------------------------------------
  Sum of atomic charges =     0.000000

 -----------------------------------------------------------------
                    Cartesian Multipole Moments
 -----------------------------------------------------------------
    Charge (ESU x 10^10)
                 0.0000
    Dipole Moment (Debye)
         X       0.0367      Y      -1.8057      Z      -1.8767
       Tot       2.6046
    Quadrupole Moments (Debye-Ang)
        XX     -43.1191     XY       2.9917     YY     -44.3054
        XZ       3.1013     YZ      -2.9314     ZZ     -43.9269
    Octapole Moments (Debye-Ang^2)
       XXX     -16.0785    XXY      -6.0358    XYY      -6.8747
       YYY      10.2263    XXZ     -13.0720    XYZ       1.8587
       YYZ      -7.6048    XZZ       1.0262    YZZ       1.1101
       ZZZ     -22.9555
    Hexadecapole Moments (Debye-Ang^3)
      XXXX   -1211.0914   XXXY     -33.6386   XXYY    -246.5953
      XYYY     -17.3719   YYYY    -142.9982   XXXZ       9.3811
      XXYZ     -18.5442   XYYZ       6.2699   YYYZ     -23.2004
      XXZZ    -232.9461   XYZZ      -4.3758   YYZZ     -51.4080
      XZZZ      20.7318   YZZZ     -25.2517   ZZZZ    -141.4649
 -----------------------------------------------------------------
 Total job wall time:  1240.00 s
 Total job time:  2480.00s(wall), 2452.72s(cpu) 

ENDVOUTPUT